Product ID:DALIC SOLUTION, 3 ETCHING & DESMUTTING,CODE 1023
MSDS Date:11/21/1997
FSC:6850
NIIN:01-067-6669
MSDS Number: BRNRM

Emergency Phone: 216-524-0099; FAX 216-5246331

Info Phone: 216-881-8600

Cage: 11924

Telephone: -6331

Cage: 11924

CITRIC ACID AND DERIVATIVES

CAS: 77-92-9

RTECS: GE7350000

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: SKIN, EYES, RESPIRATORY
SYSTEM. EYES: MAY CAUSE IRRITATION. SKIN CONTACT: MAY CAUSE
IRRITATION. SKIN ABSORPTION: NOT ABSORBED THROUGH SKIN. INHALATION:
MAY CAUSE SNEEZING, WATERING OF E YES, NASAL DISCHARGE, COUGHING.
INGESTION: ACIDIC TASTE. MAY CAUSE GASTROINTESTINAL IRRITATION.
CHRONIC: NONE
Explanation of Carcinogenicity:KNOWN OR POTENTIAL CARCINOGENS: NTP:NO;
I.A.R.C. MONOGRAPHS: NO; OSHA: NO; ACGIH: NO.
Effects of Overexposure:SKIN AND EYES: IRRITATION. INHALATION:
WATERING EYES, SNEEZING, NASAL DISCHARGE, COUGHING. INGESTION:
GASTROINTESTINAL IRRITATION.
Medical Cond Aggravated by Exposure:NONE REPORTED

First Aid:EYES: HOLD EYELIDS APART AND FLUSH EYES WITH WATER FOR AT 15
MINUTES. SKIN: FLUSH WITH WATER FOR 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. DECONTAMINATE, (OR DISCARD),
CLOTHING AND SHOES. INHALATION: MOVE TO FRESH AIR. LAY VICTIM
DOWN, LEGS RAISED. LOOSEN TIGHT CLOTHING, COVER WITH BLANKET. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. I NGESTION: DO NOT INDUCE VOMITING, UNLESS
ADVISED BY EMS. GIVE VICTIM LARGE QUANTITY OF WATER OR MILK. GIVE
MILK OF MAGNESIA OR FRESH EGGS. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:MATERIAL WILL NOT BURN. ALL MEDIA APPROPRIATE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NIOSH/MSHA APPROVED POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS. STRUCTURAL FIRE FIGHTERS
PROTECTIVE CLOTHING MAY NOT PROVIDE ADEQUATE PROTECTION.
Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE AND
BURST IF EXPOSED TO HEAT (FIRE). CONTACT WITH METALS MAY FORM
HYDROGEN GAS. WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE
AREA FOR LATER DISPOSAL.

Spill Release Procedures:DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
ISOLATE AREA. NOTIFY EMERGENCY COORDINATOR. ELIMINATE IGNITION
SOURCES. VENTILATE AREA. DO NOT RELEASE TO SOIL, SEWERS, NATURAL
BODIES OF WATER. WEAR PR OTECTIVE EQUIPMENT. CAREFULLY MOP UP OR
VACUUM SPILL AND TRIPLE RINSE WITH WARM WATER INTO SUITABLE PLASTIC
CONTAINER. RELEASE OF A REPORTABLE QUANTITY REQUIRES NOTIFICATION
OF PROPER AUTHORITIES.
Neutralizing Agent:SODA ASH, CRUSHED LIMESTONE

Handling and Storage Precautions:STORAGE: KEEP CONTAINER TIGHTLY CLOSED
IN UPRIGHT POSITION. STORE AT 60-90F, AWAY FROM INCOMPATIBLE
MATERIALS AND PHYSICAL HAZARDS. DO NOT REMOVE OR DEFACE LABELS.
Other Precautions:HANDLING: USE BUDDY SYSTEM WHEN WORKING WITH
CHEMICALS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT BREATHE
VAPOR, MIST, GAS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY
AFTER HANDLING. DO NOT REUSE CONTAINER; TRIPLE RINSE THEN DISPOSE
PROPERLY.

Respiratory Protection:IF ENGINEERING CONTROLS ARE NOT FEASABLE, THE
RESPIRATORY PROTECTION PROGRAM MUST COMPLY WITH OSHA 29 CFR
1910.134, 30 CFR 11, AND ANSI Z88.2 REQUIREMENTS.
Ventilation:LOCAL EXHAUST VENTILATION IS REQUIRED TO MEET THE
PERMISSABLE EXPOSURE LIMITS (PEL) DURING THE USE OF THIS PRODUCT.
Protective Gloves:WEAR NITRILE, NEOPRENE, VINYL, LATEX GLOVES FOR SKIN
PROTECTION.
Eye Protection:FACESHIELD AND SAFETY GLASSES WITH SIDE SHIELDS OR
SPLASH-PROOF CHEMICAL GOGGLE
Other Protective Equipment:IMPERVIOUS BOOTS, APRON, PROTECTIVE CLOTHING
REQUIRED BY JOB CONDITIONS. EYE WASH STATION, SAFETY SHOWER AND
WASHING FACILITIES NEAR WORK AREA.
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
PART NUMBERS: 30102304 (1 LITER BOTTLE); 30102306 (4 LITER BOTTLE).

HCC:C3
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:<0.C, 32.F
Vapor Pres:N/A.
Vapor Density:N/A.
Spec Gravity:1.125-1.135
pH:4.3-4.7
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID - ODORLESS

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH REACTIVE METALS, STRONG BASES, OXIDIZERS, CYANIDES
SULFIDES.
Stability Condition to Avoid:STABLE UNDER NORMAL AMBIENT CONDITIONS.
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:SHIP TO APPROVED TREATMENT/DISPOSAL FACILITY.
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. EPA
WASTE I.D. NUMBER: NONE. FOLLOW APPLICABLE REGULATIONS FOR DISPOSAL
OF EMPTY CONTAINERS AND RINSATE. THE RESPONSIBILITY FOR PROPER
WASTE DISPOSAL IS WITH THE GENERATOR OF THE WASTE.

Toxicological Information:NOT AVAILABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT AVAILABLE.

Transport Information:DOT, IATA,K ICAO, IMO DESCRIPTION: PROPER
SHIPPING NAME: NO. 3 ETCHING AND DESMUTTING SOLUTION CODE 1O23.
HAZARD CLASS: NOT RESTRICTED, NOT REGULATED BY DOT. IDENTIFICATION
NUMBER: NONE. PACKING GROUP (PG): NONE. LABEL REQUIREMENTS: NONE.
UNIT CONTAINER: 1 LITER, 4 LITER POLYETHYLENE BOTTLE.
PACKABING:MEETS PERFORMANCE ORIENTED PACKING REQUIREMENTS.
REPORTABLE QUANTITY (RQ): NOT APPLICABLE. 1996 NA ERG GUIDE#: NOT
APPLICABLE.

SARA Title III Information:SUPPLIER NOTIFICATION ABOUT TOXIC CHEMICALS:
SIFCO SELECTIVE PLATING IS REQUIRED TO INFORM YOU, THAT THIS
PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTIO N 313 OF TITLE I I I OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR
PART 372, IF SPECIFIED ANNUAL THRESHOLDS ARE MET OR EXCEEDED. TOXIC
CHEMICAL: NONE. YOUR OTHER SUPPLIERS OF TRADE NAME PRODUCTS OF
MIXTURES CONTAINING SECTION 313 CHEMICALS MUST ALSO NOTIFY YOU. IF
YOU REPACKAGE OR OTHERWISE REDISTRIBUTE THIS PRODUCT TO INDUSTRIAL
CUSTOMERS YOU ARE REQUIRED TO FURNISH NOTIF ICATION TO THEM.
Federal Regulatory Information:CERCLA AND EPCRA: THRESHOLD PLANNING
QUANTITY: NONE. (RELEASE) REPORTABLE QUANTITY: NOT APPLICABLE.
EXTREMELY HAZARDOUS SUBSTANCE: NONE. EPCRA HAZARD CATEGORIES:
IMMEDIATE (ACUTE) HEALTH: YES; DELAYED (CHRONIC) HEALTH: NO; FIRE:
NO; SUDDENRELEASE OF PRESSURE: NO;REACTIVITY: NO. TSCA STATEMENT:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED UNDER THE TOXIC
SUBSTANCES CONTROL ACT (TSCA). ODS, VOC, AND P CB CERTIFICATIONS:
THIS PRODUCT DOES NOT CONTAIN AND IS NOT MANUFACTURED WITH OZONE
DEPLETING SUBSTA NCES (ODS) NOR CONTAIN ANY VOLATILE ORGANIC
COMPOUNDS (VOC) NOR CONTAIN ANY POLYCHLORINATED BIPHENYLS (PCB).
State Regulatory Information:CALIFORNIA PROP. 65: NOT APPLICABLE.