Product ID:F-424 SERIES NON-FLAMING CHLORINATED ALKYD
MSDS Date:07/27/1992
FSC:8010
NIIN:00N043793
MSDS Number: BRZRD

PRO-LINE PAINT CO

2646 MAIN ST
SAN DIEGO, CA 92113-3697
US

Emergency Phone: 619-728-3192; 619-484-8364

Info Phone: 619-231-2313; 619-232-8968

Preparer: E. SOETERIK

Cage: 9D157

PRO-LINE PAINT CO

SAN DIEGO, CA 92113-3697 US

Telephone: 619-231-2313; 619-232-8968

Cage: 9D157

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: <1%

OSHA PEL 50 PPM, S

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 22%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

BARIUM SULFATE

CAS: 7727-43-7

RTECS: CR0600000

Fraction By Weight: 35%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS)

CAS: 64742-47-8

RTECS: OA5504000

Fraction By Weight: 11%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

ZIRCONIUM; (ZIRCONIUM 12%). (MFR CAS# 39049-04-2)

CAS: 7440-67-7

RTECS: ZH7070000

Fraction By Weight: 2%

OSHA PEL 5 MG/M3;10 STEL (ZR)

ACGIH TLV: 5 MG/M3;10 STEL (ZR)

COBALT; (COBALT 12%) (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

ANTITERRAU

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

340 G/L

RTECS: 9999999VO

ALKYD RESIN SOLUTION (CONTAINING INGREDS 2-6)

Fraction By Weight: 29%

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 8%

OSHA PEL 400 PPM (MFR)

ACGIH TLV: 50 PPM (MFR)

BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 7.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

BENZENE, TRIMETHYL-(MIXED ISOMERS); (TRIMETHYL BENZENE)

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: 7.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:MAY CAUSE DIZZINESS, HEADACHES,
LOSS OF APPETITE, WEAKNESS & LOSS OF COORDINATION. SKIN/EYE
CONTACT:BURNING SENSATION FROM VAPOR OR LIQUID. DERMATITIS,
SENSITIZATION OR RASH. NOT ACUTELY TOXIC. SKIN ABSORP:PROLONGED
EXPOSURE CAN CAUSE IRRITATION & DEFATTING OF SKIN W/DISCOMFORT.
INGEST:TOXIC IF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:COBALT: IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 52, PG
363, 1991: GROUP 2B
Effects of Overexposure:HLTH HAZ:SWALLOWED. CAN CAUSE BURNING
SENSATION, VOM, DIARR & DROW. ACUTE: NAUS, DIZZ, HDCH & CONVLS.
CHRONIC: NOT APPLICABLE. RPTS HAVE SHOWN THAT ASSOC RPTD/PRLNGD
OCCUP OVEREXPOS TO SOLVS CAN CAUSE PERM BRAIN & NERV SYS DAM.
INTENTIONALMISUSE BY DELIB CONCENTRATING & INHALING CONTENTS MAY BE
HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:ASTHMA & SKIN ALLERGIES. CAN CAUSE
DISCOMFORT TO PEOPLE W/THESE ALLERGIES, BUT NORMALLY IT IS NOT A
PROBLEM.

First Aid:EYES:FLUSH IMMEDIATELY W/FRESH WATER FOR AT LEAST 15 MINS BY
AN EYE WASH APPARATUS OR BY HAND. SEEK MEDICAL ATTENTION. SKIN:WASH
IMMEDIATELY W/WATER. THEN WASH W/SOAP & WATER. RINSE IMMEDIATELY.
SEEK MEDICAL ATTENTION. INHAL:MOVE PERSON TOFRESH AIR. ARTIFICIAL
RESPIRATION IF NECESSARY. SEEK MEDICAL ATTENTION. INGEST:SEEK
MEDICAL ATTENTION. DO NOT INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:0.77%
Upper Limits:6%
Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. BLANKET FLAME W/ONE OF THE EXTING MEDIAS. VAPS OF COMBUST MAY BE
IRRITATING TO RESP TRACT. MAY (SUP DAT)
Unusual Fire/Explosion Hazard:KEEP MATERIAL AWAY FROM HEAT, SPARKS &
OPEN FLAMES.

Spill Release Procedures:REMOVE ALL TYPES OF IGNITION SOURCES. PROVIDE
SUFFICIENT VENTILATION. PROTECT CLEAN-UP PERSON W/8540 3M CORP
NIOSH/MSHA APPROVED RESPIRATOR & GOGGLES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA
W/ SPRINKLER SYSTEM. KEEP AWAY FROM HEAT. PROTECT AGAINST PHYSICAL
DAMAGE TO CONTAINERS & SPILLAGE.
Other Precautions:POST NO SMOKING SIGNS. USE ONLY W/ADEQUATE
VENTILATION.

Respiratory Protection:USE NIOSH/MSHA APPRVD DUST/MIST RESP (HIGH
EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING/SANDING. USE NIOSH/MSHA
APPRVD ORG VAP CARTRIDGE RESP IF TLV FOR SOLV COMPONENTS MAY BE
EXCEEDED, E.G. NIOSH/MSHA APPRVD 8540 3M CORP RESP. WHEN (SUP DAT)
Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED
AREA. KEEP VAPORS BELOW TLV.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:GOGGLES W/SIDE SHIELDS.
Other Protective Equipment:USE PROT CLTHG & CHANGE CONTAMD CLTHG IMMED.
PROVIDE EMER SHOWERS & EYEWASH AT STATIONARY PAINT APPLICATN
FACILITIES.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES BEFORE THEY WORK W/THIS PRODUCT.
Supplemental Safety and Health
FIRE FIGHT PROC:CAUSE BREATHING DIFFICULTIES. PREVENT HUMAN EXPOSURE TO
FIRE, SMOKE, FUMES, ETC. RESP PROT: USING IN CONFINED AREA, USE
NIOSH/MSHA APPROVED AIR-FED HOOD.

HCC:F4
Boiling Pt:B.P. Text:300F,149C
Vapor Pres:6.9 @ 20C
Vapor Density:3.9
Spec Gravity:1.6 @ 20C
Evaporation Rate & Reference:0.36 (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORED LIQUID; MILD PETROLEUM ODOR.

Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. DO NOT ALLOW
VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:(INCL COMBUST PRODS) FLAMM FUMES MAY
ACCUM IN CONFINED AREAS & SPARKS OR OPEN FLAMES MAY IGNITE IT.

Waste Disposal Methods:(CONTR TYPE, NEUTRALIZATION, ETC) USE METAL
CONTR MARKED "DO NOT REUSE". POUR THE MATL IN THIS CONTR. USE
VERMICULITE OR OTHER INERT ABSORB. KEEP AWAY FROM SEWER. DISPOSE OF
ALL WASTES IN ACCORDANCE W /FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.