Product ID:MSA 458480 TUBE VENTILATION SMOKE, PKG 12
MSDS Date:06/17/1993
FSC:6635
NIIN:01-375-7977
MSDS Number: BSDDC

MINE SAFETY APPLIANCES CO

PITTSBURG, PA 15230
US

Emergency Phone: 412-967-3000

Info Phone: 412-967-3000

Cage: 3J685

MINE SAFETY APPLIANCES CO

PITTSBURG, PA 15230 US

Telephone: 412-967-3000

Cage: 3J685

AMPOULE 1 (CONTAINING INGREDIENTS 2 & 3)

OSHA PEL N/K

ACGIH TLV: N/K

3310 MG/KG

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 50%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 15 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICA GEL

CAS: 63231-67-4

RTECS: VV7340000

Fraction By Weight: 50%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

AMPOULE 2 (CONTAINING INGREDIENTS 5 & 6)

OSHA PEL N/K

ACGIH TLV: N/K

1,2-ETHANEDIAMINE; (1,2 DIAMINOETHANE); (ETHYLENEDIAMINE)

CAS: 107-15-3

RTECS: KH8575000

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: 10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PUMICE

CAS: 1332-09-8

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: 10 MG/M3

14.4%

RTECS: 9999999ZZ

AS SMOKE PUFF

RTECS: 9999999ZZ

BULB, OVEREXP IS UNLIKELY UNDER INTENDED CONDITIONS

RTECS: 9999999ZZ

BOTH AMPOULES W/IN TUBE ARE CRUSHED. IF BOTH

RTECS: 9999999ZZ

IMMERSED. IF TUBE CONTAINS UNBROKEN AMPOULE, CRUSH

RTECS: 9999999ZZ

UNBROKEN AMPOULE HAS BEEN RELS FROM TUBE, REPLACE IT

RTECS: 9999999ZZ

CONTENTS IN BUCKET. IN ALL CASES LET TUBE SOAK

RTECS: 9999999ZZ

SOLIDS FROM WATER & DISPOSE TO TRASH. FILTERED WATER

RTECS: 9999999ZZ

EQUIP NOT INDICATED UNDER ANTIC CNDTN OF

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACETIC ACID: IRRITATION OF EYES,
MUCOUS MEMBRANES, SKIN. SPLASHES PRODUCE EYE AND SKIN BURNS.
INGESTION OF 1 CM3 GLACIAL ACETIC ACID PRODUCED PERFORATION OF THE
ESOPHAGUS. TARGET ORGANS:EYES, NOSE, TH ROAT, SKIN.
ETHYLENEDIAMINE: IRRITATIONOF EYE, MUCOUS MEMBRANES, SKIN. TARGET
ORGANS:EYES, NOSE, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:THROAT, SKIN, LIVER, KIDNEYS.
Medical Cond Aggravated by Exposure:NO INFORMATION.

First Aid:SKIN:FLUSH W/COPIOUS AMTS WATER. CALL MD . INHAL:REMOVE FROM
EXPOS. IF BRTHG DFCLT, ADMIN O*2. GET MED ATTN IMMED. IF BRTHG
STOPPED, GIVE ARTF RESP. GET MED ATTN IMMED. EYES:REMOVE FROM
EXPOS. F LUSH W/WATER FOR @ LEAST 15 MIN HOLDINGEYES OPEN & RAISING
LIDS TO FLUSH UNDERLID AREAS. SEE MD IMMED. INGEST:IF TUBE CONTENTS
INGEST & IF CONSCIOUS, GIVE 2 GLASSES WATER TO DILUTE CHEM. GET
(ING 8)

Flash Point:SUPDAT
Lower Limits:SUPDAT
Upper Limits:ING 7
Extinguishing Media:AS NEEDED FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:AMPOULES MAY RUPTURE & EMIT TOX FUMES
UNDER FIRE CNDTNS. COMPONENTS ARE SORBED ON INERT SOLID. TOTAL AMT
COMBUST/FLAM MATL <1G/TUBE. AMPOULES SEALED UNTIL USED.

Spill Release Procedures:IF CONTENTS RELS, AVOID CNTCT W/SPILLED MATL.
LEAVE IMMED AREA IF SMOKE GENERATED UNTIL SMOKE SUBSIDES. FILL
BUCKET 3/4 FULL OF WATER. PUT ON RUB GLOVES & SPLASHPROOF GOGG.
SWEEP UP SPILLED MATL & PLA CE IN BUCKET. EXAMINE TUBE TO BE SURE
(ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE TUBES IN A COOL, DRY LOCATION
PROTECTED FROM CURSHING AND IMPACT FORCES.
Other Precautions:THE USER IS CAUTIONED TO AVOID BREATHING THE TUBE
EMISSIONS WHICH ARE IRRITANT.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPR CHEM SFTY GOG W/FULL FCSHLD.
Other Protective Equipment:EMER EYEWASH & DELUGE SHOWER . DUE TO LTD
AMT OF CHEM IN EACH TUBE & SLOW RELS RATE, USE OF PERSONAL PROT
(ING 15)
Work Hygienic Practices:WASH HANDS AFTER USING PRODUCT.
Supplemental Safety and Health
BP:ING 2: 224F,118C; ING 5: 243F,117C. SPEC GRAV:ING 2: 1.05; ING 5:
0.90 (H*2O=1). VP:ING 2: 14.8 @ 25C; ING 5: 10 @ 20C. SOL IN
H*2O:ING 2:SOLUBLE; ING 5:SOLUBLE. APPEAR/ODOR:
ETHYLENEDIAMINE/PUMICE AMPOULE:GRAY TO BLACK GRANULES, AMMONIA
ODOR. FL PT:ING 2: 103F,39C; ING 5: 93F,33.9C. LEL:ING 2: 4%; ING
5: 19.9%.

HCC:T6
Boiling Pt:B.P. Text:SUPDAT
Vapor Pres:SUPDAT
Spec Gravity:SUPDAT
Solubility in Water:SUPDAT
Appearance and Odor:ACETIC ACID/SILICA GEL AMPOULE:WHITE GRANULES,
VINEGAR ODOR. (SUPDAT)
Percent Volatiles by Volume:50

Stability Indicator/Materials to Avoid:YES
AVOID ACIDS, BASES, OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:TAPE OVER ENDS OF EXHAUSTED TUBES AND DISPOSE IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.