Product ID:EMPIRE 20 MICROENCAPSULATED INSECTICIDE
MSDS Date:06/02/1992
FSC:6840
NIIN:01-338-6003
MSDS Number: BSFWW

VAN WATERS AND ROGERS INC/SUB OF UNIVAR

6100 CARILLON PT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3712

Info Phone: 206-889-3712

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

CHLORPYRIFOS (SARA III)

CAS: 2921-88-2

RTECS: TF6300000

Fraction By Weight: 20% %

OSHA PEL S, 0.2 MG/M3

ACGIH TLV: S, 0.2 MG/M3; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

PETROLEUM SOLVENTS

Fraction By Weight: 10% %

NON HAZARDOUS INGREDIENTS AND WATER

Fraction By Weight: 70% %

LD50 LC50 Mixture:LD50 0RAL (RATS) > 25000 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLORPYRIFOS IS A CHOLINESTERASE
INHIBITOR. EXCESSIVE EXPOOSURE MAY CAUSE RESPIRATORY IRRITATION AND
CENTRAL NERVOUS SYSTEM EFFECTS. ESSENTIALLY NONIRRIATING TO EYES.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM
EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION. INGESTION: INDUCE VOMITING IF LARGE AMOUNTS
ARE INGESTED. CONSULT MEDICAL PERSONNEL. ATROPINE IS PREFERRED
ANTIDOTE.

Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:SWEEP UP INTO PLASTIC BAGS USING SWEEPING
COMPOUND.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVVVOID HEATING ABOVE 50C FOR EXTENDED
PERIODS OF TIME.
Other Precautions:DO NOT CONTAMINATE FOOD, FEED OR WATER BY STORAGE OR
CLEANING OF EQUIPMENT. OPEN BURING IS PROHIBITED.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER
CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH RESPIRATOR
SELECTION.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO
MAINTAIN EXPOSURE LEVELS.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES
Other Protective Equipment:CLEAN BODY-COVERING CLOTHING
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
PESTICIDE, SPRAY MIXTURE OR RINSE WATER THAT CANNOT BE USED ACCORDING
TO LABEL INSTRUCTIONS MUST BE DISPOSED OF ACCORDING TO APPLICABLE
FEDERAL, STATE AND LOCAL PROCEDURES.

HCC:T5
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:17.5
Vapor Density:< 1
Spec Gravity:1.03
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:DISPERSES IN WATER
Appearance and Odor:LIQUID, SHITE SUSPENSION, SLIGHT SOLVENT ODOR

Stability Indicator/Materials to Avoid:YES
BASES
Stability Condition to Avoid:AVOID HEATING ABOVE 50C FOR EXTENDED
PERIODS, LOSS OF ACTIVE INGREDIENT MAY RESULT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, ETHYL SULFIDE,
DIETHYL SULFIDES, NITROGEN OXIDES.

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.