Product ID:KILLEM
MSDS Date:08/20/1990
FSC:6840
NIIN:00N041263
MSDS Number: BSHBN

FPPF CHEMICAL CO INC

117 W TUPPER ST
BUFFALO, NY 14201
US

Emergency Phone: 800-735-3773

Info Phone: 201-226-6316

Preparer: ROBERT MILLER JR.

Cage: FPPFC

FPPF CHEMICAL CO.

BUFFALO, NY 14201 US

Telephone: 201-226-6316

Cage: FPPFC

CARBAMIC ACID, ETHYLENE BIS (DITHIO-, DISODIUM SALT);

CAS: 142-59-6

RTECS: FA6825000

Fraction By Weight: 15%

2-IMIDAZOLIDINETHIONE; (ETHYLENE THIOUREA) (SARA III)

CAS: 96-45-7

RTECS: NI9625000

Fraction By Weight: <1%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,2-ETHANEDIAMINE; (ETHYLENE DIAMINE) (SARA III)

CAS: 107-15-3

RTECS: KH8575000

Fraction By Weight: <1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIMETHYL AMINE (SARA III)

CAS: 124-40-3

RTECS: IP8750000

Fraction By Weight: <1%

OSHA PEL 10 PPM

ACGIH TLV: 5 PPM;15 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SLIGHTLY IRRITATING TO SKIN/EYES.
VAPORS CAN BE IRRITATING TO NOSE, THROAT & RESPIRATORY TRACT. MAY
CAUSE NAUSEA & VOMITING, IF INGESTED.
Explanation of Carcinogenicity:ETHLYENE THIOUREA:GROUP 2B (IARC SUPP7,
P207,'87), ANTIC TO BE A CARCINOGEN (NTP 6TH ANN RPT, '91).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:FLUSH
W/WATER FOR AT LEAST 15 MINUTES; USE SOAP ON SKIN. INGEST:DRINK
LARGE QUANTITIES OF WATER. INHAL:MOVE TO FRESH AIR. GIVE OXYGEN IF
BREATHING IS D IFFICULT, ARTIFICIAL RESPIRATION IF BREATHING STOPS.
SEEK MEDICAL ATTENTION FOR ANY EMERGENCY.

Extinguishing Media:NON-FLAMMABLE. USE WATER, FOAM, CO*2 OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:SHUT-OFF ALL IGNITION SOURCES. CONTAIN SPILL,
THEN ABSORB W/SAND OR OTHER INERT MATERIAL. PLACE IN DRUMS FOR
DISPOSAL. DO NOT GET MATERIAL IN SEWERS. REPORT ANY RELEASES TO
AUTHORITIES. REPORTABLE QUA NTITY FOR ETHYLENE THIOUREA IS 1 LB.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MAINTAIN AT ROOM TEMPERATURE, AWAY
FROM HEAT & OTHER IGNITION SOURCES. USE ADEQUATE VENTILATION &
SAFETY PROCEDURES AT ALL TIMES.
Other Precautions:DISPOSE OF DRUMS PROPERLY. AVOID CONTACT OR
INHALATION.

Respiratory Protection:USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS, IF NECESSARY.
Ventilation:NOT APPLCIABLE FOR INTENDED USE; MECHANICAL FOR DRUM
STORAGE.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:ANSI APRV CHEMICAL WORKERS GOGGLES (FP N
Other Protective Equipment:LAB COAT, BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Boiling Pt:B.P. Text:>212F,>100C
Spec Gravity:1.2 (H*2O=1)
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR YELLOW; SULFUR ODOR.
Percent Volatiles by Volume:70

Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS SUCH AS SULFURIC, NITRIC & HYDROCHLORIC.
Stability Condition to Avoid:ACID, HEAT.
Hazardous Decomposition Products:CARBON DISULFIDE, AMINES.

Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE & FEDERAL
LAW.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.