Product ID:DIBROM ULV INSECTICIDE
MSDS Date:08/26/1987
FSC:6840
NIIN:00N046717
MSDS Number: BSJVN

SUMMIT CHEMICAL CO

7657 CANTON CENTER DR
BALTIMORE, MD 21224
US

Emergency Phone: 301-282-5200

Info Phone: 301-282-5200

Cage: 6R717

SUMMIT CHEMICAL CO

BALTIMORE, MD 21224-2028 US

Telephone: 410-282-5200

Cage: 6R717

PHOSPHORIC ACID, 1,2-DIBROMO-2, 2-DICHLOROETHYL DIMETHYL

CAS: 300-76-5

RTECS: TB9450000

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEAVY AROMATIC NAPHTHALENES; (HEAVY AROMATIC NAPHTHA)

OSHA PEL N/K

ACGIH TLV: N/K

INCOMPLETE COMBUSTION CAN PRODUCE CARBON

RTECS: 9999999ZZ

LEVELS MAY BE USEFUL IN MONITORING EXPOS. IF

RTECS: 9999999ZZ

SULFATE IS ANTIDOTAL. 2-PAM (PROTOPAM) IS ALSO

RTECS: 9999999ZZ

NOT BE USED ALONE.

RTECS: 9999999ZZ

MORE ABSORBENT & PLACE IN DISPOSABLE CONTAINER.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CORR TO EYES & SKIN, CAUSES EYE IRRIT
& DMG. CAUSES SKIN DMG. SIGNS & SYMPS OF EXPOS:NALED IS MOD TOX ORG
PHOSPHORUS INSECTICIDE WHICH INHIBITS CHOLINERGIC NERVES BY
INHIBITION OF CHOLINESTERASE. SIGN S & SYMPS WHICH MAY INCL, BUT
MAY NOT BE LTD TO, CONSTRICTION OF PUPIL, BLURRED VISION, EXCESSIVE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SALIVATION/NASAL DISCHARGE, PROFUSE
SWEATING, CRAMPS, NAUS, VOMIT, RETCHING, PROD OF TEARS, TWITCHING,
TREMORS/ CONVLS. IN SEV CASES, DEATH MAY RSLT FROM RESP
FAILURE/CARDIAC ARREST. SIGNS & SYMPS MAY BE DELAYED BUT RARELY
BEGIN LATER THAN 12 HRS AFTER EXPOS. ADDNL SLIGHT EXPOS MAY RSLT IN
ACUTE INTOX.
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid:EYES:FLUSH IMMED W/FRESH WATER FOR AT LST 15 MINS & SEE MD.
SKIN:WASH W/SOAP & WATER, REMOVE & LAUNDER CONTAM CLTHG. SEE MD.
DISCARD CONTAM NON-WATERPROOF SHOES & BOOTS. INHAL:REMOVE TO FRESH
AIR IMME D. ASSIST BRTHG IF NEC. CALL MD IMMED. INGEST:DO NOT
INDUCE VOMIT. PROD CONTAINS PETRO DISTILS & INDUCED VOMIT COULD
LEAD TO PROBS OF ASPIR PNEUM. SEE MD IMMED. NOTE TO MD:BLOOD
CHOLINESTERASE (ING 4)

Flash Point Method:TCC
Flash Point:145F,63C
Lower Limits:0.8% (SOLV)
Upper Limits:7% (SOLV)
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
SMOKE FROM FIRES INVOLVING THIS MATL MAY PRESENT UNUSUAL HAZS.
AVOID BRTHG SMOKE & MISTS. AVOID (SUPDAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:AVOID ANY CONT, KEEP PEOPLE AWAY, WEAR PROT
CLTHG & NIOSH/MSHA APPRVD MASK. SPILLS SHOULD BE ABSORBED ON
OIL-DRY, CLAY, SAWDUST/OTHER ABSORB MATL, SWEPT UP & PLACED IN
DISPOSABLE CNTNR. SCRUB CONTAM A REA W/DETERGENT & WATER. PICK UP
LIQ W/(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE NEAR HEAT OR OPEN FLAME.
DO NOT STORE NEAR FOOD & FEED. KEEP OUT OF REACH OF CHILDREN. STORE
IN A COOL, DRY PLACE.
Other Precautions:BE ACUTELY AWARE OF EVIDENCE OF FAULTY OR LEAKING
CONTAINERS. DO NOT REUSE CONTAINER. DISPOSE OF CONTAINER AS
DIRECTED ON LABEL. AVOID CONTACT W/SKIN, EYES & CLOTHING.

Respiratory Protection:NIOSH/MSHA APPROVED INSECTICIDE/ORGANIC VAPOR
MASK.
Ventilation:LOCAL EXHAUST: USE ADEQUATE VENT TO KEEP AIRBORNE
CONCENTRATION BELOW EXPOSURE STANDARD. MECHANICAL: AS REQUIRED.
Protective Gloves:RUBBER GLOVES (NEOPRENE PREFERRED).
Eye Protection:CHEM SPLASH RESIST, FULL FACE MASK.
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . RUBBER
SHOES, PROTECTIVE WORK CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REPLACE
CONTAMINATED CLOTHING IMMEDIATELY.
Supplemental Safety and Health
FIRE FIGHT PROC:CONT W/FALLOUT & RUNOFF. MIN AMT OF WATER USED FOR FIRE
FIGHTING. CONTAIN & ISOLATE RUNOFF & DEBRIS FOR PROPER DISP. USE
WATER SPRAY TO DISPERSE VAPS. CNDTNS (STAB):TO SUNLIGHT. AVOID
CONT W/STRONG OXIDIZING AGENTS. SLOWLY UNDERGOES CHEM CHANGES WHEN
IN CONT W/MILD STEEL.

HCC:V4
Boiling Pt:B.P. Text:>349F,>176C
Vapor Pres:<3 @ 25C
Vapor Density:4.2
Spec Gravity:1.214
Evaporation Rate & Reference:<0.1
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:PALE STRAW COLORED LIQUID; PUNGENT AROMATIC
HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
CORROSIVE TO MILD STEEL, ALUMINUM & MAGNESIUM. MAY CORRODE METAL SPRAY
EQUIPMENT.
Stability Condition to Avoid:ACTIVE CHEM, (NALED) HYDROLYZES SLOWLY IN
PRESENCE OF WATER UNDER NEUTRAL/ACID CNDTNS. WILL DISCOLOR WHEN
EXPOS (SUPDAT)
Hazardous Decomposition Products:NORM COMBUST FORMS CARBON DIOXIDE &
WATER VAP & MAY PRDCE TOX CMPDS OF PHOSPHORUS, CHLORINE & BROMINE;
(ING 3)

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . REFER TO NACA "DISPOSAL METHODS FOR ORGANIC
PHOSPHATES & RELATED MATERIALS".

Disclaimer (provided with this information by the compiling agencies):
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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
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assume responsibility for the suitability of this information to their
particular situation.