Product ID:N,N-DIMETHYLANILINE
MSDS Date:05/01/1989
FSC:6810
NIIN:00N047828
MSDS Number: BSWTT

DU PONT E I DE NEMOURS & CO INC

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637/800-424-9300(CHEMTREC)

Info Phone: 800-441-7515/MSDS 302-992-3511

Cage: 18873

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

OF BREATH BY FORMATION OF METHEMOGLOBIN.

RTECS: 9999999ZZ

FORMING SYSTEM FUNTION WITH ANEMIA; OR RED BLOOD

RTECS: 9999999ZZ

AMOUNTS CAPABLE OF PRODUCING THE EFTS OF SYSTEMIC

RTECS: 9999999ZZ

CYANOSIS. IN CASE OF SKIN ABSORPTION SYMPS

RTECS: 9999999ZZ

HEMOGLOBIN OCCURS SPONTANEOUSLY AFTER TERMINATION OF

RTECS: 9999999ZZ

TREATED ONLY BY SUPPORTIVE MEASURES SUCH AS BED REST

RTECS: 9999999ZZ

CONTAM AREA OF THE BODY INCLUDING SCALP & NAILS IS

RTECS: 9999999ZZ

INTRAVENOUS INJECTION OF METHYLENE BLUE, 1 MG/KG OF

RTECS: 9999999ZZ

B-12), 1 MG INTRAMUSCULARLY, WILL SPEED RECOVERY.

RTECS: 9999999ZZ

INDICATED IN VERY SEVERE EXPOSURES.

RTECS: 9999999ZZ

REGULATIONS ON REPORTING RELEASES.

RTECS: 9999999ZZ

5.4 (WATER EXTRACT)

RTECS: 9999999ZZ

ANILINE, N,N-DIMETHYL-; (N,N-DIMETHYLANILINE) (SARA III)

CAS: 121-69-7

RTECS: BX4725000

Fraction By Weight: 99.0%

OSHA PEL 5 PPM;10 STEL, S

ACGIH TLV: 5 PPM;10 STEL, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1350 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES EYE BURNES & SKIN IRRIT.
HARMFUL IF INHALED OR ABSORBED THROUGH SKIN; REDUCES BLOOD OXYGEN
CARRYING CAPACITY. SYMPTOMS MAY BE DELAYED. THE COMPOUND IS A SEV
EYE IRRIT & IS A SKIN IRRIT. TOX EFT S DESCRIBED IN ANIMALS FROM
SHORT EXPOSURES INCL METHEMOGLOBINEMIA, LIVER EFTS, ANEMIA, & BONE
MARROW (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EFTS. TESTS IN BACTERIAL OR MAMMALIAN
CELL CULTURES DEMONSTRATE NO MUTAGENIC ACTIVITY. HUMAN HLTH EFTS OF
OVEREXP MAY INITIALLY INCL: NONSPECIFIC DISCOMFORT, SUCH AS NAUS,
HDCH, OR WEAKNESS; OR REDUCTION OF BLOOD'S OXYGEN CARRYING
CAPACITY W/CYANOSIS (BLUISH DISCOLORATION), WEAKNESS, OR SHORTNESS
(ING 2)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE CARDIOVASCULAR SYSTEM OR BONE MARROW MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE.

First Aid:EYE/SKIN: IMMED FLUSH EYE OR SKIN W/PLENTY OF WATER FOR AT
LEAST 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. CALL MD. WASH
CLTHG BEFORE REUSE & DESTROY CONTAM SHOES. INHAL: REMOVE TO FRESH
AIR. IF NOT BRTHG, GIVE ARTF RESP.IF BRTHG IS DIFFICULT, GIVE
OXYGEN. CALL MD. NOTE TO MD: ABSORPTION OF THIS PROD INTO THE BODY
LEADS TO THE FORMATION OF METHEMOGLOBIN WHICH, IN SUFFICIENT CONC,
CAUSES (ING 5)

Flash Point Method:SCC
Flash Point:145F,63C
Lower Limits:1.0%
Upper Limits:7.0%
Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CARBON DIOXIDE (CO*2).
LARGE FIRES: WATER SPRAY, FOG, OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. ISOLATE HAZ & EVAC CONFINED AREAS. STAY UPWIND; AVOID SMOKE &
FUMES. USE WATER SPRAY TO COOL (SUPP DATA)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVAC AREA & KEEP UPWIND OF SPILL. CONTAIN
SPILL W/SAND OR EARTH DAM, SOAK UP WITH SAND OR OTHER
NONCOMBUSTIBLE MATL & TRANSFER TO A COVERED METAL CNTNR FOR
DISPOSAL. FLUSH AREA W/PLENTY OF DETERGENT A ND WATER. COMPLY
W/FEDERAL, STATE & LOC(ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN OR
CLOTHING. AVOID BREATHING VAPOR.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:GOOD GENERAL VENT SHOULD BE PROVIDED TO KEEP CONCENTRATIONS
BELOW THE EXPOSURE LIMIT.
Protective Gloves:BUTYL RUBBER GAUNTLET GLOVES.
Eye Protection:CHEM SPLASH GOGG & FULL-LENGTH FSHLD.
Other Protective Equipment:FOOT WEAR, APRON, WEAR A CHEMICAL-PROOF SUIT
W/HOOD. EMERGENCY EYE BATH AND DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE FIGHT PROC: TANKS AND REDUCE VAPORS. IF SMOKE FUMES CANNOT BE
AVOIDED, WEAR CHEMICAL-PROOF SUIT W/HOOD & BRTHG AIR SUPPLY. FIGHT
FIRE FROM MAXIMUM DISTANCE. RUN-OFF FROM FIRE CONTROL MAY CAUSE PO
LLUTION. DECOMP PRODS: THIS EXOTHERMIC DECOMPOSITION TEMPERATURE.

HCC:V4
Boiling Pt:B.P. Text:379F,193C
Melt/Freeze Pt:M.P/F.P Text:36.0F,2.2C
Vapor Pres:0.75 @ 25C
Vapor Density:4.2
Spec Gravity:0.956 @ 20C
pH:ING 13
Evaporation Rate & Reference:< 1 (BUTYL ACETATE=1)
Solubility in Water:0.18% @ 20C (68F)
Appearance and Odor:LIGHT YELLOW (STRAW COLOR) OILY LIQUID; DARKENS IN
STORAGE. AROMATIC ODOR.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG OXIDIZERS AND STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WILL OCCUR >400C RELEASING HAZ OXIDES
OF NITROGEN GASES. CONTAM BY FOREIGN MATLS OR ACIDIC CNDTNS MAY
LOWER (SUPP DATA)

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. IF APPROVED, MAY BE INCINERATED OR SENT TO AN APPROVED
HAZARDOUS WASTE MATERIAL DISPOSAL AREA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.