Product ID:ROUNDUP HERBICIDE
MSDS Date:11/01/1992
FSC:6840
NIIN:01-108-9578
MSDS Number: BSYZL

Emergency Phone: 314-694-4000

Info Phone: 314-694-4000

Cage: 76541

Telephone: 202-832-1161

Cage: 0Y285

GLYPHOSATE, N-PHOSPHONOMETHYLGLYCINE, IN THE FORM OF ITS

CAS: 1071-83-6

Fraction By Weight: 41% %

INERT FILLERS

Fraction By Weight: 59% %

LD50 LC50 Mixture:LD 50 ORAL RAT > 5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: TEMPORARY EYE IRRITATION AND
CONJUNCTIVITIS, GASTROINTESTINAL DISCOMFORT. INGESTION OF LARGE
QUANTITIES MAY RESULT IN HYPOTENSION AND PULMONARY EDEMA. CHRONIC:
SKIN IRRITATION.
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT
IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES: TEMPORARY EYE IRRITATION. SKIN:
IRRITATION ON PROLONGED CONTACT. INHALATION: NO SYMPTOMS NOTED.
INGESTION: GASTROINTESTINAL DISCOMFORT, IRRITATION OF THE MOUTH,
NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:NONE NOTED.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. INHALATION: REMOVE VICTIM TO FRESH
AIR. GET MEDICAL ATTENTION IF BREATHING DIFFICULTY DEVELOPS.
INGESTION: DRINK MILK, EGG WHITES OR GELATIN SOLUTION OR WATER. GET
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:ABSORB WITH ABSORBENT CLAY SUCH AS ATTAPULGITE
OR BENTONITE. PLACE IN PLASTIC-LINED METAL DRUM. THOROUGHLY SCRUB
FLOORS WITH STRONG INDUSTRIAL TYPE DETERGENT SOLUTION AND RINSE
WITH WATER.

Handling and Storage Precautions:SPRAY SOLUTIONS OF THIS PRODUCT SHOULD
BE MIXED, STORED OR APPLIED ONLY IN STAINLESS STEEL, ALUMINUM,
FIBERGLASS, PLASTIC AND PLATIC-LINED CONTAINERS.
Other Precautions:TRIPLE RINSE CONTAINERS IF METAL DRUMS. DONOT REUSE
PLASTIC DRUMS.

Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED
RESPIRATOR APPROVED FOR PESTICIDE IN CASE OF HEAVY SPRAY OR MIST.
Ventilation:NO SPECIAL REQUIREMENT.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE
EXPOSURE FROM PROLONGED OR REPEATED CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
DO NOT CONTAMINATE WATER, FOODSTUFFS, FEED OR SEED BY STORAGE OR
DISPOSAL. EMPTIED CONTAINER RETAINS VAPOR AND PRODUCT RESIDUE.
OBSERVE ALL LABELED SAFEGUARDS UNTIL CONTAINER IS CLEANED,
RECONDITIONED OR DESTROYED.

HCC:T5
Spec Gravity:1.17
pH:4.7
Appearance and Odor:CLEAR, VISCOUS AMBER-COLORED SOLUTION. PRACTICALLY
ODORLESS TO SLIGHT AMINE-LIK

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT IN CONTACT WITH GALVANIZED OR UNLINED STEEL MAYA FORM
FLAMMABLE AND EXPLOSIVE HYDROGEN GAS.
Stability Condition to Avoid:STABLE FOR AT LEAST 5 YEARS UNDER NORMAL
CONDITIONS OF WAREHOUSE STORAGE. HEATED FACILITIES ARE NOT
REQUIRED.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
INCOMPLETELY BURNED CARBON PRODUCTS.

Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER RECOMMENDS DISPOSAL IN A LANDFILL
APPROVED FOR PESTICIDES. DO NOT REUSE C ONTAINER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.