Product ID:R1604T
MSDS Date:05/05/1988
FSC:8305
NIIN:01-246-4175
MSDS Number: BTVSH

CIBA GEIGY CORP/PLASTICS & ADDITIVES

THREE SKYLINE DRIVE
HAWTHORNE, NY 10532-2119
US

Emergency Phone: 800-888-8372/914-785-2000

Info Phone: 914-785-2000/800-888-8372

Preparer: JANOS SCHULZE

Cage: EO487

CIBA-GEIGY CORP ADDITIVES DIV.

HAWTHORNE, NY 10532-2119 US

Telephone: 800-888-8372

Cage: 07566

GLYCIDYL BENZENAMINE

4,4,'-DIAMINODIPHENYLMETHANE, 4,4-METHYLENE DIANILINE

CAS: 101-77-9

RTECS: BY5425000

ACGIH TLV: 0.1 PPM (SKIN)

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

2-BUTANONE (METHYL ETHYL KETONE) (MEK)

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES/INHALATION:
IRRITANT/SENSITIZER. ACUTE OVEREXPOSURE:
IRRITATION/SENSITIZATION/DERMATITIS. FOR METHYLENE DIANILINE:
FEVER/CHILL/ANOREXIA/VOMITING. CHRONIC OVEREXPOSURE: HUMAN LIVER
TOXIN/FEVE R/CHILLS/ANOREXIA/VOMITING/TOXIC
HEPATITIS/JAUNDICE/HEPATOTOXIC EFFECTS.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:SKIN/EYES/INHALATION: IRRITANT/SENSITIZER.
ACUTE OVEREXPOSURE: IRRITATION/SENSITIZATION/DERMATITIS. FOR
METHYLENE DIANILINE: FEVER/CHILL/ANOREXIA/VOMITING. CHRONIC
OVEREXPOSURE: HUMAN LIVER TOXIN/FEVE
R/CHILLS/ANOREXIA/VOMITING/TOXIC HEPATITIS/JAUNDICE/HEPATOTOXIC
EFFECTS.
Medical Cond Aggravated by Exposure:LIVER DISEASE, JAUNDICE, SKIN/EYE
CONDITIONS.

First Aid:EYES: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. SKIN: WASH
W/SOAP & WATER. ANY MATERIAL ADHERING SHOULD BE REMOVED W/RESIN
REMOVING CREAMS. DON'T USE SOLVENTS. INGESTION: IF CONSCIOUS GIVE
LARGE QUANTIT IES OF WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN
MEDICAL ATTENTION IN ALL CASES.

Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. COOL
FIRE EXPOSED CONTAINERS W/WATER. COOL SURROUNDING
EQUIPMENT/STRUCTURES W/WATER IN CASE OF LARGE FIRES.
Unusual Fire/Explosion Hazard:DECOMPOSITION/COMBUSTION PRODUCTS MAY BE
TOXIC.

Spill Release Procedures:COLLECT & PLACE INTO A CLOSABLE CONTAINER FOR
DISPOSAL. WEAR PROTECTIVE EQUIPMENT.

Handling and Storage Precautions:STORE IN DRY CHEMICAL STORAGE FACILITY
IN TIGHTLY CLOSED CONTAINERS. STORE AWAY FROM FOOD, FOOD CONTAINERS
& CLOTHNG.
Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING. DON'T BREATHE
DUST/VAPOR/MIST/SPRAY. USE ONLY W/GOOD VENTILATION.

Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE
RESPIRATOR WHEN VAPOR/MIST EXPOSURE IS LIKELY.
Ventilation:REQUIRED.
Protective Gloves:RECOMMENDED.
Eye Protection:SAFETY GLASSES/GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING, BARRIER CREAM
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING/BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health

Melt/Freeze Pt:M.P/F.P Text:140F
Decomp Temp:Decomp Text:392F
Spec Gravity:1.2
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT YELLOW RESIN ON WHITE FABRIC W/NO ODOR
Percent Volatiles by Volume:<1

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS & BASES.
Stability Condition to Avoid:TEMPS >200F.
Hazardous Decomposition Products:CO, CO2, NITROGEN OXIDES/OTHER TOXIC
ORGANIC SPECIES.
Conditions to Avoid Polymerization:DON'T HEAT IN BULK. DANGEROUS
EXOTHERMIC REACTION MAY OCCUR.

Waste Disposal Methods:BURY/INCINERATE IN APPROVED SITE/FACILITY
IAW/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.