Product ID:N,N-DIMETHYLANILINE
MSDS Date:08/29/1990
FSC:6810
NIIN:00N047919
MSDS Number: BTYJB

DU PONT

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Cage: 25827

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

CONTAM AREA OF BODY INCL SCALP & NAILS IS OF UTMOST

RTECS: 9999999ZZ

METHYLENE BLUE, 1 MG/KG OF BODY WT, MAY BE OF VALUE.

RTECS: 9999999ZZ

WILL SPEED RECOVERY. IV FLUIDS & BLOOD TRANSFUSIONS

RTECS: 9999999ZZ

METAL CNTNR FOR DISPOSAL. FLUSH AREA W/PLENTY OF

RTECS: 9999999ZZ

REGULATIONS ON REPORTING RELEASES. AQUATIC TOXICITY

RTECS: 9999999ZZ

RESISTANT WORK CLTHG IF HNDLG MATL ABOVE

RTECS: 9999999ZZ

WEAR A CHEMICAL-PROOF SUIT W/HOOD.

RTECS: 9999999ZZ

FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

ANILINE, N,N-DIMETHYL-; (N,N-DIMETHYL-ANILINE) (SARA III)

CAS: 121-69-7

RTECS: BX4725000

Fraction By Weight: 99%

OSHA PEL 5 PPM;10 PPM STEL, S

ACGIH TLV: 5 PPM;10 PPM STEL, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NERV SYS DEPRESS W/ANESTH EFTS SUCH AS DIZZ, HDCH,

RTECS: 9999999ZZ

MAY CAUSE RED BLOOD CELL DESTRUCT/ABNORM BLOOD

RTECS: 9999999ZZ

1900 MG/M3 WAS FATAL TO 2 OF 10 ANIMALS; SURVIVORS

RTECS: 9999999ZZ

EFTS IN ANIMALS FROM RPTD DOSES INCL

RTECS: 9999999ZZ

ORGANS. LONG-TERM INGEST EXPOS CAUSED MICROSCOPIC

RTECS: 9999999ZZ

SPLEEN TUMORS IN MALE RATS & STOM TUMORS IN FEMALE

RTECS: 9999999ZZ

OF CARCIN IN MALE RATS & "EQUIVOCAL EVID" OF CARCIN

RTECS: 9999999ZZ

CELL CULTURES, BUT HAS NOT BEEN TESTED IN ANIMALS.

RTECS: 9999999ZZ

ABSORP OF

RTECS: 9999999ZZ

WHICH, IN SUFFICIENT CONC, CAUSES CYANOSIS. IN CASE

RTECS: 9999999ZZ

REVERSION OF METHEMOGLOBIN TO HEMOGLOBIN OCCURS

RTECS: 9999999ZZ

NEED TO BE TREATED ONLY BY SUPPORTIVE MEASURES SUCH

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1,350 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES EYE BURNS & SKIN IRRIT. HARMFUL
IF INHALED/ABSORBED THRU SKIN; REDUCES BLOOD'S OXYGEN CARRYING
CAPACITY. SYMPS MAY BE DELAYED. HUMAN HLTH EFTS OF OVEREXP BY EYE
CONT MAY INITIALLY INCL IRRIT W/ DISCOMFORT, TEARING/BLURRING OF
VISION.HIGHER EXPOS MAY CAUSE CORR W/CORNEAL/CONJ ULCERATION. BY
SKIN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONT, EFTS MAY INCL IRRIT
W/DISCOMFORT/RASH. EVID SUGGESTS THAT PERMEATION CAN OCCUR IN AMTS
CAPABLE OF PRDCG SYSTEMIC TOX. BY INHAL, INGEST/SKIN CONT, EFTS MAY
INCL METHEMOGLOBINEMIA (REDUCT ION OF BLOOD'S OXYGEN CARRYING
CAPACITY) W/HDCH, WEAK/CYANOSIS (BLUISH DISCOLORATION OF SKIN),
POSS PROGRESSING (SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
OF BONE MARROW OR BLOOD FORMING SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. CALL
MD. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE
REMOVING CONTAM CLTHG & SHOES. CALL MD. WASH CLTHG BEFORE REUSE &
DESTROY CO NTAM SHOES. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG,
GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD.
INGEST:GIVE 2 GLASSES OF WATER & INDUCE VOMIT. NEVER GIVE ANYTHING
BY MOUTH TO AN (ING 10)

Flash Point Method:SCC
Flash Point:145F,63C
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:SMALL FIRES:DRY CHEMICAL, CARBON DIOXIDE (CO*2).
LARGE FIRES:WATER SPRAY, FOG OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
ISOLATE HAZ & EVACUATE CONFINED AREAS. STAY UPWIND & AVOID SMOKE &
FUMES. USE WATER SPRAY TO COOL (SUPDAT)
Unusual Fire/Explosion Hazard:OSHA CLASS III A COMBUSTIBLE LIQUID.
FOLLOW APPROPRIATE NFPA CODES.

Spill Release Procedures:REVIEW FIRE & EXPLO HAZS & SFTY PRECS BEFORE
PROCEEDING W/CLEAN UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN
UP. EVACUATE AREA & KEEP UPWIND OF SPILL. CNTN SPILL W/SAND/EARTH
DAM, SOAK UP W/SAND/OT HER NONCOMBUST MATL & TRANSFER TO COVERED
(ING 17)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED AREA
AWAY FROM HEAT, SPKS & FLAME. DO NOT STORE W/OXIDIZERS OR STRONG
ACIDS. KEEP CNTNR TIGHTLY CLSD.
Other Precautions:HANDLE IN A MANNER TO PVNT HUMAN CONT. DO NOT GET IN
EYES, ON SKIN/ON CLTHG. AVOID BRTHG VAP. COMBUSTIBLE LIQUID! CAUSES
EYE BURNS! CAUSE SKIN IRRITATION. HARMFUL IF INHALED/ABSORBED THRU
SKIN.

Respiratory Protection:IF CONTACT W/LIQUID OR VAPOR CANNOT BE AVOIDED,
WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE PROVIDED TO KEEP VAPOR
CONCENTRATIONS BELOW THE RECOMMENDED EXPOSURE LIMIT.
Protective Gloves:BUTYL RUBBER GAUNTLET GLOVES.
Eye Protection:ANSI APPVD CHEM SPLASH GOGGS (ING 21)
Other Protective Equipment:ANSI APVD EMER EYEWSH & DELUGE SHWR . HV
AVAIL & WEAR AS APPROP TO PVNT LIQ/VAP EXPOS:FTWEAR &
APRON,FLAME-(ING 19
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:5.4(WATER EXTRACT). FIRE FIGHT PROC:CNTNRS & REDUCE VAPS. FIGHT FIRE
FROM MAX DIST. RUN-OFF FROM FIRE CONTROL MAY CAUSE POLLUTION. HAZ
DECOMP PROD:LOWER THIS EXOTHERMIC DECOMP TEMP. EFTS OF OVEREXP :TO
DIZZ, INCOORD, SHORTNESS OF BREATH,INCR PULSE RATE & LOSS OF
CONSCIOUSNESS. HIGHER EXPOS MAY CAUSE TEMPORARY(ING 2)

Boiling Pt:B.P. Text:379F,193C
Melt/Freeze Pt:M.P/F.P Text:36.0F,2.2C
Decomp Temp:Decomp Text:752F,400C
Vapor Pres:0.75 @ 25C
Vapor Density:4.2
Spec Gravity:0.956
pH:SUPDAT
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:0.18 WT% @ 20C
Appearance and Odor:LIGHT YELLOW (STRAW COLOR)-DARKENS IN STORAGE, OILY
LIQUID; AROMATIC AMINE ODOR

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZERS & STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WILL OCCUR AT TEMPS >400C (752F)
RELEASING HAZ NITROGEN OXIDE GAS. CONTAM BY FOREIGN MATLS/ACIDIC
CNDTNS MAY (SUPP DATA)

Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS. IF
APPROVED, MAY BE INCINERATED OR SENT TO AN APPROVED HAZARDOUS
MATERIAL DISPOSAL AREA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.