Product ID:D-CROWNS
MSDS Date:10/07/1993
FSC:9650
NIIN:00N049081
MSDS Number: BTZBY

FALCONBRIDGE LIMITED

COMMERCE COURT WEST
TORONTO, ONTARIO CANADA

Emergency Phone: 705-693-2761

Info Phone: 705-693-2761

Cage: IO743

INDUSMIN DIVISION FALCONBRIDGE LTD.

TORONTO, ON CA

Telephone: (705) 877-2210

Cage: 38385

ONLY RELIABLE, SCIENTIFIC

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

BEEN DEMONSTRATED TO RSLT FROM CERTAIN STEPS IN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

OF WORKERS EXPOSED TO VARIOUS FORMS OF NICKEL & ITS

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

OSHA CFR 1910.134 ARE RECOMMENDED.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

BY USE OF APPROPRIATE VENTILATION.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

AVOID SOLUTION CONTACT BY USE OF ANSI APPROVED

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ANTICPATED TO BE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

NICKEL (SARA III); (99.9% NI METAL)

CAS: 7440-02-0

RTECS: QR5950000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

I.A.R.C.(JUNE 1989) HAS RECLASSIFIED NICKEL AS

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

GROUP 1 CARCIN. GROUP 1 CARCIN -

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

TO HUMANS. THIS CLASSIFICATION IS USED WHEN THERE IS

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ANIMALS. FINALLY, ACGIH STATES THAT ONLY DUST & FUMES

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50:(ORAL,RAT)>5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORMAL HNDLG & USE, EXPOS TO
MASSIVE FORMS OF NICKEL PRESENTS FEW HLTH HAZ. IF, HOWEVER, MASSIVE
FORMS ARE CONVERTED TO PARTICULATES THEN BOTH ACUTE & CHRONIC HLTH
HAZ ARE POSS. ACUTE:EYE:PARTIC ULATES MAY CAUSE SLIGHT EYE IRRIT.
SKIN:BOTH MASSIVE FORMS & PARTICULATES MAY CAUSE EITHER CONT DERM
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL:IARC MONO ON EVAL OF CARCIN RISK
OF CHEMS TO MAN, VOL 49, PG 257, 1990:GRP 2B. NTP 6TH ANNUAL REPORT
ON (ING 12)
Effects of Overexposure:HLTH HAZ:OR SKIN SENSIT IN SENSITIVE
INDIVIDUALS W/RPTD SKIN EXPOS. INGEST:NOT A NORMAL ROUTE OF ENTRY.
INHAL:RARE CASES OF ASTHMA HAVE BEEN REPORTED TO HAVE OCCURRED IN
INDIVIDUALS EXPOSED TO SOME FO RMS OF PARTICULATES CONTAINING
NICKEL, PARTICULARLY NICKEL SULPHATE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IRRIGATE WITH WATER FOR AT LEAST 15 MINS. SKIN:WASH OFF
CONT AREAS W/WATER/REMOVE CONTAMD CLTHG & SHOWER. CONTAMD CLTHG
SHOULD BE WASHED BEFORE REUSE. AVOID PRLNGD/RPTD CONT W/SKIN.
INGEST:INDUCE VOMIT IF LG AMTS INGESTED. CONSULT PHYS.
INHAL:REMOVE TO FRESH AIR IF ACUTE RESP EFFECT. CONSULT PHYS.

Extinguishing Media:MASSIVE FORMS OF NICKEL DO NOT PRESENT A FIRE OR
EXPLOSIVE HAZARD.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .

Spill Release Procedures:UNDER NORMAL HNDLG AND USE MATL IS NOT DUSTY
AND DOES NOT PRESENT SPILLAGE & LEAKAGE PROBLEMS. NO PROT REQD,
EXCEPT AVOID PRLNGD/RPTD DIRECT SKIN CONTACT IF SENSITIVE TO
NICKEL. IN SUCH CIRCUMSTANCES, GLOVES ARE RECOMMENDED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE NEAR MINERAL ACIDS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:IF SOLID NICKEL FORMS ARE CONVERTED IN MFR
PROCESSES TO PARTICUALTES & VENT IS NOT ADEQ TO MAINTAIN NICKEL
CONCS BELOW RECOMMENDED EXPOS LIMS, THEN RESP PROT SHOULD BE USED.
NIOSH/MSHA APPRVD RESPS W/ H.E.P.A. FILTER ACCORDING TO (ING 9)
Ventilation:IF SOLID FORMS OF NICKEL ARE CONVERTED TO PARTICULATES
MAINTAIN WORKING ENVIRONMENT BELOW RECOMMENDED EXPOS LIMS(ING 10)
Protective Gloves:LEATHER OR RUBBER GLOVES.
Eye Protection:IF NICKEL METAL IS DISSOLVED, (ING 11)
Other Protective Equipment:PROT COVERALLS AND SAFETY FOOTWEAR ARE
RECOMMENDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS (STAB):WILL PRODUCE NICKEL CARBONYL-A HIGHLY TOXIC GAS. EFTS OF
OVEREXPOS:FORM. ACUTE INHAL DOSE L.C. 50 IN RATES IS >10 MG/L.
CHRONIC:ACCORDING TO OSHA CFR 1910.1200(D)(4)(1), NICKEL METAL IS
CONSIDERED A POSS CANCER HAZ BECAUSE NTP HAS CONCLUDED IT MAY BE
REASONABLY ANTICIPATED TO BE A HUMAN CARCIN.(ING 2)

Boiling Pt:B.P. Text:4946F,2730C
Melt/Freeze Pt:M.P/F.P Text:2647F,1453C
Spec Gravity:8.9 (H*20=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID, METALLIC - NO ODOR

Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:CONT W/MINERAL ACIDS WILL RELEASE
HYDROGEN-A DANGEROUS GAS. UNDER SPECIFIC CNDTNS, EXPOS TO CARBON
MONOXIDE (SUPDAT)
Hazardous Decomposition Products:NONE.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.