Product ID:"B" COMPONENT, PDL X23-92 PART B
MSDS Date:11/08/1990
FSC:8040
NIIN:00N051061
Kit Part:Y
MSDS Number: BVDZP

POLYMER DEVELOPMENT LABS, INC

212 W TAFT AVE
ORANGE, CA 92665
US

Emergency Phone: 714-921-2300

Info Phone: 714-921-2300

Cage: IN060

POLYMER DEVELOPMENT LABS, INC

ORANGE, CA 92665 US

Telephone: 714-921-2300

Cage: IN060

BE PUMPED INTO CLSD BUT NOT SEALED CNTNRS FOR DISP.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

W/1-2% ADDED DETERGENT, LETTING IT STAND OVER

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

USED FOR THIS WITH PLASTIC AND DISPOSE OF PROPERLY

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

POLYVINYL ALCOHOL. COVER AS MUCH EXPOSED SKIN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

AREA COVERED BY THE CREAM TO MINIMUM.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

IF TEMPORARY CTL OF ISOCYANTE VAP IS REQD, BLANKET

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

HYDROXYL TERMINATED POLY (OXYALKYLENE) POLYETHER

CAS: 9049-71-2

Fraction By Weight: 63-92%

OSHA PEL N/K

ACGIH TLV: N/K

TERTIARY AMINE BEARING COMPOUNDS

Fraction By Weight: <2%

OSHA PEL N/K

ACGIH TLV: N/K

METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 5-34%

OSHA PEL 1000 PPM

ACGIH TLV: C 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NO SPECIFIC ANTIDOTE. SUPPORTIVE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

TO REACTIONS OF PATIENT. MANIFESTATIONS OF RESP SYMP,

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DELAYED, MAY CAUSE RESPIRATORY SENSITIZATION.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

SOLN CONSISTING OF MIXT OF WATER & 3-8%

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ABOUT 10 PARTS OF NEUT PER PART OF ISOCYANATE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

CALL PDL IMMED. IF IT IS TRANSPORTATION

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

SPILL AREA. DIKE SPILL TO PVNT ENTRY INTO ENVIRON.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 (ORAL RAT)>20 G/KG (INGESTION)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:MAY CAUSE RESP SENSIT IN
SUSCEPTIBLE INDIVIDUALS AT ROOM TEMP, VAPS ARE MINIMAL DUE TO LOW
VAP PRESS. IF HEATED/SPRAYED AS AN AEROSOL, EXCESSIVE CONC ARE
ATTAINABLE THAT CO*2 BE HAZ ON SINGLE EX POS. EXCESSIVE EXPOS MAY
CAUSE IRRIT TOEYES, UPPER RESP TRACT & LUNGS, EFTS MAY BE DELAYED.
DECREASED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:VENTILATORY CAPACITY HAS BEEN ASSOC
W/EXPOS TO SIMILAR ISOCYANATES; IT IS POSS THAT EXPOS TO MDI MAY
CAUSE IMPAIRMENT OF LUNG FUNCTION. SKIN:MAY CAUSE ALLERGIC SKIN
REACTION IN SUSCEPTIBLE IN DIVIDUALS. PRLNGD/RPTED CONT MAY CAUSE
SKIN IRRIT. MAY STAIN SKIN. INGEST:NOT CONSIDERED RTE OF EXPOSURE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/CLEAN, LUKE WARM WATER @ LOW PRESS FOR 15 MINS,
OCCASNLY LIFTING EYELIDS. CONSULT PHYS IMMED. SKIN:REMOVE CONTAMD
CLTHG. WASH EXPO AREA W/WARM SOAPY WATER THORO. CONTAMD CLTHG
SHOULD BE PR OPERLY LAUNDERED BEFORE REUSING. INHAL:REMOVE VICTIM
FROM AREA OF EXPOS TO SAFE AREA. IF NOT BRTHG, GIVE MOUTH TO MOUTH
RESUSCITATION. IF BRTHG IS DFCLT, GIVE OXYG. CONSULT PHYS IMMED.
(SUPDAT)

Flash Point Method:COC
Flash Point:425F,218C
Extinguishing Media:DRY CHEM EXTING SUCH AS MONOAMMONIA PHOSPHATE,
POTASSIUM SULFATE, POTASSIUM CHLORIDE. ADDITIONALLY, CO*2, (SUPDAT)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . IF
WATER IS USED, USE LG AMTS AS THE REACTION BETWEEN HOT ISOCYANTES &
WATER CAN BE VIGOROUS.
Unusual Fire/Explosion Hazard:WATER CONTAMINATION WILL PRODUCE CO*2. DO
NOT RE-SEAL CONTAMD CNTNRS AS PRESSURE BUILDUP MAY RUPTURE THEM.

Spill Release Procedures:MINOR SPILLS:CONTAIN SPILLED MATL & COVER
W/LOOSE ABSORB MATL SUCH AS OILDRY, VERMICULITE, SAWDUST/FULLER'S
EARTH. SHOVEL WASTE MATL INTO PROPER WASTE CNTNRS. DO NOT MAKE
PRESS TIGHT. TRANSPORT TO WEL L-VENTILATED AREA & TREAT
W/NEUTRALIZING (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROD IS REACTIVE W/WATER. CNTNRS
SHOULD BE TIGHTLY SEALED TO PVNT MOISTURE CONTAM. ALWAYS SLOWLY
VENT CNTNR WHEN OPENING TO RELIVE PRESS ANY BUILDUP.
Other Precautions:NITROGEN BLANKET SHOULD BE USED FOR BUILDING STOR.
STORE AT TEMP OF 65 TO 75/ PROTECT FROM FREEZING. IF CONTAM OF MDI
IS SUSPECTED, DO NOT RE-SEAL CNTNR BECAUSE OF POSS RUPTURE DUE TO
PRESSURE BUILDUP .

Respiratory Protection:PROD HAS DEMONSTRATED NO OBSERVABLE EFTS @ ROOM
TEMP, HOWEVER, ATM LEV SHOULD BE MAINTAINED. IN ADDITION, ANY SPRAY
APPLIC/SITUATION WHERE AIRBORNE PARTICULATES/AEROSOL ARE GENERATED,
NIOSH/MSHA APPRV D SUPPLIED AIR SOURCE MUST BE PROVIDED.
Ventilation:NATRL/MECH. LOC EXHAUST WILL KEEP TLV BELOW MIN IN MOST
CASES. SPILLS/OTHER EMER MAY REQ MORE FORCE VENT MEANS.
Protective Gloves:CHEM RESIST SUCH AS NATL RUBBER (ING 15)
Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES .
Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS WHICH
MEET ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA:HIGH EXPANSION (PROTEINIC) CHEM FOAM, WATER SPRAY FOR LG
FIRES. MATLS TO AVOID:COMBINED EFCT OF CO*2 & HEAT CAN PRDCE ENOUGH
PRESS TO RUPTURE CLSD CNTNR. SOME REACTIONS ARE VIOLENT IN PRE
SENCE OF ABOVE MATLS. FIRST AID PROC:INGEST:NO ADVERSE EFTS ANTIC
BY RTE OF EXPOS INCIDENTAL TO PROPER INDUS (ING 4)

Boiling Pt:B.P. Text:DECOMPOSES
Spec Gravity:1.01
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:CLEAR TO DARK BROWN VISCOUS LIQUID, SLIGHTLY
ETHEREAL

Stability Indicator/Materials to Avoid:YES
WATER, ACID, BASES, METAL CMPDS & SURF ACTIVE MATLS. AVOID WATER AS IT
REACTS TO FORM HEAT, CO*2 INSOLUBLE UREA.(SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:ISOCYANATE VAPOR & MIST. CARBON
DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES & TRACES OF HYDROGEN
CYANIDE.
Conditions to Avoid Polymerization:INCOMPATIBLE REACTANTS, ESP STRONG
BASES, WATER/TEMS OVER 347F (175C). TEMP OVER 120F (49C) ACCELERATE
REACTION W/WATER.

Waste Disposal Methods:WASTE MATL MAY BE INCIN AT PROVIDED
FACILITIES/DISPOSED OF UNDER LOCAL, STATE & FEDERAL REGS
CONTROLLING ENVIRONMENTAL PROTECTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.