Product ID:CHLOROBENZENE
MSDS Date:08/21/1989
FSC:6830
NIIN:00N051422
MSDS Number: BVKYJ

SCOTT SPECIALTY GASES INC

ROUTE 611
PLUMSTEADVILLE, PA 18949
US

Emergency Phone: 215-766-8861

Info Phone: 215-766-8861

Cage: 51847

SCOTT SPECIALTY GASES

310 PLUMSTEADVILLE, PA 18934 US

Telephone: 215-766-0416

Cage: 51847

BENZENE, CHLORO-; (CHLOROBENZENE) (SARA III)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 99.9%+

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: VAPOR/MIST IS IRRIT TO EYES,
MUC MEMB & UPPER RESP TRACT. INHALATION CAUSES LUNG, LIVER & KIDNEY
CHANGES. CAUSES CNS DEPRESS, HDCH, DIZZ, DROW, CYANOSIS, LOSS OF
CONSCIOUSNESS, SPASTIC CONTRACT IONS OF EXTREMITIES, RAPID
RESPIRATION,WEAK & IRREGULAR PULSE, BURGUNDY-RED URINE, COMA & RESP
& (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CIRCULATORY COLLAPSE. SKIN CNTCT
W/LIQ CAUSES DEFATTING & REDNESS. EYE CNTCT MAY CAUSE CONJUNCT,
REDNESS & PAIN. CHRONIC: HDCH, DIZZ, DYSPEPTIC DISORDERS,
ACROPARESTHESIA, HYPESTHESIA, SPAST IC CONTRACTIONS OF MUSC, LUNG,
LIVER, KIDNEY DAMAGE, DERMATITIS, ERYTHEMA, BURNS, CONJUNCT.
Medical Cond Aggravated by Exposure:NONE.

First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: IMMEDIATELY REMOVE
VICTIM TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN/EYES:
IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING. SEEK MEDICAL
ATTENTION.

Flash Point:84.0F,28.9C
Lower Limits:1.3%
Upper Limits:7.1%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER SPRAY TO KEEP FIRE EXPOSED
CYLINDERS COOL.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. VAPOR MAY TRAVEL
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK.

Spill Release Procedures:EVACUATE AND VENTILATE AREA. ELIMINATE ALL
SOURCES OF IGNTION. ABSORB SPILL ON SAND OR VERMICULITE AND PLACE
IN CLOSED CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN WELL VENT AREA ONLY. KEEP
VALVE PROT CAP ON CYL WHEN NOT IN USE; SECURE WHEN USING TO PROT
FROM FALLING. USE SUITABLE HAND TRUCK TO MOVE CYL.
Other Precautions:PROTECT CNTNRS FROM PHYSICAL DMG. DO NOT DEFACE
CYL/LABELS. MOVE CYL W/ADEQ HAND TRUCK. CYL SHOULD BE REFILLED BY
QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENT OF COMPRESSED GAS
CYL WHICH HAS NOT BEEN FILLED BY OWNER OR W/HIS/ (SUPDAT)

Respiratory Protection:USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS IN CASE OF EMERGENCY OR NON-ROUTINE USE.
Ventilation:PROVIDE ADEQUATE & LOCAL EXHAUST VENTILATION TO MAINTAIN
CONCENTRATION BELOW EXPOSURE LIMITS.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED SAFETY GOGGLES .
Other Protective Equipment:WEAR SAFETY SHOES. SAFETY SHOWER & EYEWASH
STATION WHICH MEET ANSI DESIGN CRITERIA SHOULD BE READILY AVAILABLE
.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC: HER WRITTEN CONSENT IS VIOLATION OF FED LAW (49 CFR). IN
CASE OF EMER, CNTCT SUPPLIER FOR SPECIAL INSTRUCTIONS.

Boiling Pt:B.P. Text:270F,132C
Vapor Pres:8.8 @ 20C
Vapor Density:3.9
Spec Gravity:1.107 (H*2O=1)
Evaporation Rate & Reference:1.0 (BUAC=1)
Solubility in Water:0.1%
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH MILD ALMOND-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, SILVER PERCHLORATE, DIMETHYL SULFOXIDE, SODIUM.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HCL,
PHOSGENE, SOOT

Waste Disposal Methods:RETURN CYLINDERS TO SUPPLIER FOR PROPER DISPOSAL
W/ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROTECTION CAP IN
PLACE. WASTE MAY BE BURNED IN CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER . OBSERVE ALL FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.