Product ID:A-286
MSDS Date:03/01/1989
FSC:3439
NIIN:00N052617
MSDS Number: BVMQD

SAMUEL G. KEYWELL CO INC

FREWSBURG, NY 14738
US

Emergency Phone: 716-569-0700

Info Phone: 716-569-0700

Cage: IO848

SAMUEL G. KEYWELL CO INC

650 FREWSBURG, NY 14738 US

Telephone: 716-569-0700

Cage: IO848

ALUMINUM (SARA III)

CAS: 7429-90-5

RTECS: BD0330000

OSHA PEL 15MG/M3 DUST/5 FUME

ACGIH TLV: 10MG/M3 DUST

BORON

CAS: 7440-42-8

RTECS: ED7350000

OSHA PEL N/K

ACGIH TLV: N/K

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.05 MG/M3;DUST

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

IRON

CAS: 7439-89-6

RTECS: NO4565500

OSHA PEL N/K

ACGIH TLV: N/K

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

OSHA PEL 5 MG/M3, C

ACGIH TLV: 5 MG/M3, DUST

MOLYBDENUM (SARA III)

CAS: 7439-98-7

RTECS: QA4680000

OSHA PEL 5 MG (MO)/M3

ACGIH TLV: 5 MG (MO)/M3

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

COLUMBIUM; (NIOBIUM)

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORUS(RED); (PHOSPHORUS)

CAS: 7723-14-0

RTECS: TH3495000

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TUNGSTEN; (W)

CAS: 7440-33-7

RTECS: YO7175000

OSHA PEL 5 MG/M3;10 STEL (W)

ACGIH TLV: 5 MG/M3;10 STEL (W)

TITANIUM

CAS: 7440-32-6

RTECS: XR1700000

OSHA PEL N/K

ACGIH TLV: N/K

VANADIUM (SARA III)

CAS: 7440-62-2

RTECS: YW1355000

OSHA PEL N/K

ACGIH TLV: N/K

LUNGS,

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: METALLIC TASTE; NAUSEA;
TIGHTNESS OF CHEST; FEVER; IRRITATION OF EYES, NOSE, THROAT AND
SKIN; LOSS OF CONSCIOUSNESS/DEATH DUE TO MELTING/WELDING GASES OR
LACK OF OXYGEN. CHRONIC: ADVERSE EFFECT S MAY RESULT FROM LONG TIME
EXPOSURE TOMELTING/WELDING FUMES, GASES, OR DUSTS. THESE EFFECTS
MAY INCL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM: IARC MONOGRAPHS, VOL 49, PG
49, 1990:GRP 1. NTP 6TH ANNUAL REPORT ON CARCINS, 1991:KNOWN TO BE
CARCIN.(SUPDAT)
Effects of Overexposure:HEALTH HAZARDS: SKIN SENSITIZATION,
NEUROLOGICAL DAMAGE, AND RESPIRATORY DISEASE SUCH AS BRONCHIAL
ASTHMA, LUNG FIBROSIS OR PNEUMOCONIOSIS.
Medical Cond Aggravated by Exposure:AGGRAVATION OF PREEXISTING
RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS.

First Aid:INHALATION: REMOVE VICTIM FROM EXPOSURE AND OBTAIN PROMPT
MEDICAL ATTENTION. IF VICTIM IS UNCONSCIOUS, ADMINISTER OXYGEN. IF
NOT BREATHING, RESUSCITATE IMMEDIATELY. SKIN: FLUSH WITH COPIOUS
AMOUNTS OF WATER . EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES .
INGESTION: CALL MD IMMEDIATELY .

Flash Point:NONFLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:RESIDUE FROM CUTTING OR GRINDING SHOULD BE
SWEPT OR VACUUMED AND PLACED IN SUITABLE CONTAINERS FOR DISPOSAL BY
LOCAL, STATE, OR FEDERAL WASTE DISPOSAL REGULATIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:METAL PRODUCTS THEMSELVES ARE NOT
REACTIVE, HOWEVER, CAUTION MUST BE TAKEN WHEN MELTING/WELDING DUE
TO FUMES AND GASES.
Other Precautions:PEL/TLV EXPOSURES SHOULD BE KEPT BELOW
RECOMMENDATIONS BY OSHA AND ACGIH TO INSURE PROPER HEALTH
PROTECTION OF WORKER.

Respiratory Protection:WHEN EXPOSURE LIMITS ARE EXCEEDED, USE PROPER,
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE LOCAL EXHAUST WHEN CUTTING, GRINDING, MELTING, OR
WELDING.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGG .
Other Protective Equipment:OSHA APPROVED PROTECTIVE CLOTHING SHOULD BE
USED WHEN CUTTING, GRINDING, MELTING, OR WELDING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: HUMAN/ANIMAL: LUNG CANCER, SKIN. COBALT: IARC
MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 52, PG 363,
1991: GRP 2B. ANIMAL: PULM FIBROSIS (BLOOD EFTS). NICKEL: IARC
MONOGR APHS ON EVAL OF CARCIN RISK OF CHEMS TOMAN: VOL 49, PG 257,
1990: GRP 2B.NTP 6TH ANNUAL REPORT ON CARCINS,1991:(ING 15)

Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.