Product ID:MODEL-CAST A SIDE, 6008
MSDS Date:10/01/1993
FSC:8030
NIIN:00N054968
MSDS Number: BVYBJ

VAGABOND CORP

36374 MONTEZUMA VALLEY RD
RANCHITA, CA 92066
US

Emergency Phone: 800-255-3924

Info Phone: 619-782-3136

Cage: 5X169

VAGABOND CORP

RANCHITA, CA 92066 US

Telephone: 619-782-3136

Cage: 5X169

POLYMETHYLENEPOLYPHENYL ISOCYANATE;(POLYMETHYLENE

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE

CAS: 101-68-8

RTECS: NQ9350000

OSHA PEL C 0.02 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

AS 'PRACTICALLY NONTOX' BY INGEST. IRRIT &

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AS A RESULT OF

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INDIVIDUALS DEVELOP ISOCYANATE SENSIT WHICH WILL

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LEVELS WELL BELOW TLV. SIMILAR TO MANY NON-SPECIFIC

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AN INDIVIDUAL CAN EXPER THESE SYMPS UPON EXPOS TO

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HAS ALSO BEEN RPTD TO CAUSE LUNG DMG WHICH MAY BE

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IRRIT ARE LIKELY TO DEVELOP AFTER RPTD &/OR RPTD CONT

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BY MOUTH TO AN UNCON PERSON. GET MED ATTN.

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ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS

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PUMPED INTO CLSD, BUT NOT SEALED CNTNR FOR DISP.

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SHOVEL INTO SUITABLE UNSEALED CNTNRS, TRANSPORT TO

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0.2-0.5% LIQ DETERGENT & 3-8% CONC AMMONIUM

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FOR AMMONIUM HYDROXIDE). FOLLOW PREC ON SUPPLIER'S

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PERFORMED BY TRAINED PERS TRAINED W/HAZS OF CHEMS

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SOLN TO EACH PART OF SPILL, & ALLOW IT TO REACT FOR

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LEAVING INSOLUBLE POLYUREAS. WASH RESIDUE TO A SEWER

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DECONTAMINATE FLOOR WITH DECONTAMINATING

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UNDER RCRA, 40 CFR 261.SPRAY/POUR 5-15

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WELL RINSED. LEAVE DRUM SOAKING UNSEALED FOR 48 HRS.

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PUNCTURE OR OTHERWISE DESTROY THE RINSED CONTAINER

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AN AIR SUPPLIED HOOD. AIR PURIFYING (CARTRIDGE

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PROT MAY BE REQD SUCH AS APRON, ARM

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BUTYL RUB, NITRILE RUB & SOME NEOPRENE GARMENTS HAVE

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LD50 LC50 Mixture:LD50(ORAL,RAT):<5,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:ALTHOUGH MDI IS LOW IN
VOLATILITY, AN INHAL HAZ CAN EXIST FROM MDI AEROSOLS/VAPS FORMED
DURING HEATING FOAMING OR SPRAYING. VAPS & AEROSOLS CAN IRRIT EYES,
NOSE & RESP PASSAGES. SEV OVEREXP MAY LEAD TO PULM EDEMA. MDI CAN
INDUCE RESPSENSIT W/ ASTHMA-LIKE SYMPS. SYMPS INCLUDE CHRONIC
COUGH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TIGHTNESS OF CHEST W/DFCLTY IN BRTHG.
THESE SYMPS MAY BE IMMED/DELAYED UP TO SEVERAL HOURS AFTER EXPOS.
SKIN:NO IRRIT IS LIKELY TO DEVELOP FOLLOWING SHORT CONT PERIODS
W/HUMAN SKIN. EYE:THIS MATL WILL PROBABLY IRRIT HUMAN EYES
FOLLOWING CONT. INGEST: RELATIVE TO OTHER MATLS, THIS MATL IS
CLASSIFIED (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:WASH MATL OFF SKIN W/PLENTY OF SOAP & WATER. FOR SEV
EXPOS, GET UNDER SFTY SHOWER AFTER REMOVING CLTHG, THEN GET MED
ATTN. FOR LESSER EXPOS, SEEK MED ATTN IF IRRIT DEVELOPS/PERSISTS
AFTER AREA IS WASHED. EYES:FLUSH W/COPIOUS AMTS OF WATER FOR AT
LST 15 MIN HOLDING EYELIDS OPEN. GET MED ATTN IMMED. INGEST: DO NOT
INDUCE VOMIT, GIVE 1 TO 2 CUPS OF WATER TO DRINK. DO NOT GIVE
ANYTHING (ING 10)

Flash Point Method:COC
Flash Point:400F,204C
Extinguishing Media:DRY CHEM, CARBON DIOXIDE, FOAM, HALOGENATED AGENTS.
IF WATER IS USED, USE VERY LG QTYS. REACTION BETWEEN WATER (SUP
DAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER CONTAMINATION WILL PRODUCE CARBON
DIOXIDE. DO NOT RESEAL CONTAMINATED CONTAINERS AS PRESSURE BUILDUP
MAY RUPTURE THEM.

Spill Release Procedures:EVACUATE & VENT SPILL AREA:DIKE SPILL TO PVNT
ENTRY INTO WATER SYS;WEAR FULL PROT EQUIP DURING CLEANUP. MAJOR
SPILL: IF TEMPORARY CONTROL OF ISOCRYANATE VAP IS REQUIRED, A
BLANKET OR PROTEIN FOAM MAY BE PLACED OVER THE SPILL. LG QTYS MAY
BE (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN TIGHTLY SEALED CONTAINERS TO
PROTECT FROM ATMOSPHERIC MOISTURE. MATL QUALITY WILL DETERIORATE IF
STORED AT TEMPS OVER 100F (3-6 MONTHS).
Other Precautions:EDUCATE AND TRAIN EMPLOYEES IN SAFE USE OF PRODUCT.
KEEP AWAY FROM FOOD. DRUMS MUST BE DECONTAMINATED IN PROPERLY
VENTILATED AREAS BY PERSONNEL PROTECTED FROM THE INHALATION OF
ISOCYANATE VAPORS.

Respiratory Protection:BECAUSE OF LOW VAP PRESS, VENT IS USUALLY
SUFFICIENT TO KEEP VAPS BELOW TLV AT ROOM TEMPS. EXCEPTIONS ARE
WHEN MATL IS HEATED, SPRAYED/USED IN A POORLY VENT AREA. USE
MSHA/NIOSH APPRVD POS PRESS SUPPL IED AIR RESP W/FULL
FACEPIECE/(ING 23)
Ventilation:LOC EXHST SHOULD BE USED TO KEEP AIRBORNE CONC BELOW TLV
WHENEVER MDI IS PROCESSED, HEATED OR SPRAYED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH
MEET ANSI DESIGN CRITERIA . DEPENDING ON CNDTNS OF USE, ADDNL (ING
24)
Work Hygienic Practices:WASH W/SOAP AND WATER. DO NOT REUSE CLOTHING
UNTIL CLEANED.
Supplemental Safety and Health
VP:<0.0001 MM HG AT 20C. EXTING MEDIA:AND HOT ISOCYANATE MAY BE
VIGOROUS. MATLS TO AVOID:THE REACTION W/WATER IS VERY SLOW UNDER
50C, BUT IS ACCELD AT HIGHER TEMPS & IN PRESENCE OF ALKALIES,
TERTIARY AMINES, & METAL CMPDS. SOME REACTIONS CAN BE VIOLENT.
CNDTNS (POLYM):OF CARBON DIOXIDE GAS MAY RUPTURE CLSD CNTNRS.

HCC:T6
Boiling Pt:B.P. Text:646F,341C
Vapor Pres:SUPP DATA
Spec Gravity:1.217 @ 20C
Solubility in Water:REACTS
Appearance and Odor:PALE YELLOW ODORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
THIS PROD WILL REACT W/ANY MATLS CNTNG ACTIVE HYDROGENS, SUCH AS WATER,
ALCOHOL, AMMONIA, ALKALIES & ACIDS. (SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES, AMMONIA AND TRACE AMOUNTS OF
HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:HIGH TEMPS IN PRESENSE OF ALKALIES,
TERTIARY AMINES, & METAL CMPDS WILL ACCEL POLYMERIZATION. POSS
EVOLUTION (SUP DAT)

Waste Disposal Methods:SLOWLY STIR ISOCYANATE WASTE INTO DECONTAM
SOLUTION USING 10 PARTS OF SOLUTION FOR EACH PART OF ISOCYANATE.
LET STAND FOR 48 HRS, ALLOWING EVOLVED CARBON DIOXIDE TO VENT AWAY.
NEUTRALIZE WASTE. NEITHE R SOLID NOR LIQ PORTION IS A HAZ WASTE
(ING 20)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.