BWCHJ - NITROGEN

Product Identification

Product ID:NITROGEN
MSDS Date:08/01/1985
FSC:6685
NIIN:01-231-4204
MSDS Number: BWCHJ

Responsible Party
UNION CARBIDE CORP INDUSTRIAL CHEMICALS DIV
39 OLD RIDGEBURY ROAD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357

Info Phone: 800-822-4357

Cage: 61637

Contractor
WEKSLERIGLASS THERMOMETER CORP
FREEPORT, NY 11520 US

Telephone: 516-623-0100

Cage: 64467

Ingredients

NITROGEN

CAS: 7727-37-9

RTECS: QW9700000

Fraction By Weight: 100%

ACGIH TLV: ASPHYXIANT; 9394

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION: PRODUCT IS A GAS AT NORMAL
TEMPERATURE AND PRESSURE. SKIN: NO HARMFUL EFFECT EXPECTED FROM
VAPOR. INHALATION: ASPHYXIANT. EYE: NO HARMFUL EFFECTS EXPECTED
FROM VAPOR.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:INHALATION: MODERATE CONCENTRATIONS MAY CAUSE
HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS SALIVATION,
VOMITING, AND UNCONSCIOUSNESS. LACK OF OXYGEN CAN CAUSE DEATH.
CONTACT WITH LIQUID MAY CAU SE FROSTBITE.
Medical Cond Aggravated by Exposure:OVEREXPOSURE IS NOT LIKELY TO
AGGRAVATE EXISTING MEDICAL CONDITIONS.

First Aid

First Aid:SWALLOWING-THIS PRODUCT IS A GAS AT NORMAL TEMPERATURE &
PRESSURE. SKIN-IMMEDIATELY WARM FROSTBITE AREA WITH AWARM WATER. IF
MASS EXPOSURE, REMOVE CLOTHING WHILE SHOWERING W/WARM WATER. CALL A
PHYSICI AN. INHALATION-REMOVE TO FRESH AIR. GIVE CPR IF NOT
BREATHING. GIVE OXYGEN IF HARD TO BREATH. CALL A PHYSICIAN.
EYE-IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MIN. SEE A
PHYSICIAN IMMEDIATELY.

Fire Fighting

Flash Point:NONE
Extinguishing Media:NITROGEN CANNOT CATCH FIRE. USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:EVACUATE ALL PERSONNEL FORM DANGER AREA.
IMMEDIATELY DELUGE CONTAINERS W/WATER SPRAY FROM MAX DISTANCE UNTIL
COOL, THEN MOVE CONTNR AWAY FROM FIRE AREA W/O RISK
Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE DUE TO HEAT OF
FIRE. NO PART OF CONTAINER SHOULD BE SUBJECTED TO TEMPERATURE
HIGHER THAN 52C (125F). GAS CANNOT CATCH FIRE.

Accidental Release

Spill Release Procedures:USE SCBA WHERE NEEDED. SHUTOFF LEAK IF W/O
RISK. VENTL AREA OF LEAK OR MOVE CONTAINER TO WELL VENTLAREA.
EVACUATE ALL PERSONNEL FROM DANGER AREA. TEST AREA FOR SUFFICIENT
OXYGEN CONTENT PRIOR TO PERMI TTING RE-ENTRY OF PERSONNEL.
Neutralizing Agent:NOT APPLICABLE.

Handling

Handling and Storage Precautions:NEVER WORK ON A PRESSURIZED SYSTEM. IF
THERE IS A LEAK, CLOSE THE CYLINDER VALVE, BLOW DOWN SYSTEM BY
VENTING TO SAFE PLACE, THEN REPAIR THE LEAK.
Other Precautions:HIGH PRESSURE GAS. CAN CAUSE RAPID SUFFOCATION DUE TO
OXYGEN DEFICIENCY. STORE AND USE WITH ADEQUATE VENTILATION. CLOSE
VALVE WHEN NOT IN USE AND WHEN EMPTY.

Exposure Controls

Respiratory Protection:SELECT ACCORDANCE WITH OHSA 29 CFR 1910.134.
RESPIRATORS SHALL BE ACCEPTABLE TO MSHA AND NIOSH.
Ventilation:LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE
Protective Gloves:NOT NEEDED IN NORMAL SERVICE.
Eye Protection:SAFETY GLASSES
Other Protective Equipment:NO SPECIAL REQUIREMENTS
Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS MATERIAL.
Supplemental Safety and Health
NONE

Chemical Properties

HCC:G3
Boiling Pt:B.P. Text:-320F,-196C
Melt/Freeze Pt:M.P/F.P Text:-346F,-210C
Vapor Density:0.967
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS AT NORMAL TEMPERATURE AND
PRESSURE
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
UNDER CERTAIN CONDITIONS, NITROGEN CAN REACT VIOLENTLY WITH LITHIUM,
NEODYMIUM, TITANIUM, OZONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE

Disposal

Waste Disposal Methods:SLOWLY RELEASE INTO ATMOSPHERE. DISCARD ANY
PRODUCT RESIDUE, DISPOSABLE CONTAINER/LINER IN COMPLIANCE WITH
FEDERAL, LOCAL, AND STATE REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.