Product ID:FERROUS AMMONIUM SULFATE 0.025-0.250 NORMAL, 3142
MSDS Date:09/10/1992
FSC:6810
NIIN:00N055921
MSDS Number: BWDKW

RICCA CHEMICAL CO

448 W FORK DRIVE
ARLINGTON, TX 76094
US

Emergency Phone: 817-461-5601

Info Phone: 817-461-5601

Cage: 0V553

RICCA CHEMICAL COMPANY

13090 ARLINGTON, TX 76013 US

Telephone: 817-461-5601

Cage: 0V553

1); (FERROUS

CAS: 10045-89-3

RTECS: WS5890000

OSHA PEL 1 MG (FE)/M3

ACGIH TLV: 1 MG (FE)/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50:(ORAL RAT) SULFURIC ACID 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SULFURIC ACID SOLUTIONS ARE CORROSIVE,
FERROUS AMMONIUM SULFATE CAN CAUSE IRON POISONING. TARGET ORGANS
INCLUDE:RESPIRATORY SYSTEM, EYES, SKIN, MUCOUS MEMBRANES, LIVER,
TEETH. IRRITATION OF EYES, NOSE , THROAT, PULMONARY EDEMA, DENTAL
EROSION, BURNS OF SKIN AND EYES, NAUSEA, BLACK STOOL, PINK URINE.
Explanation of Carcinogenicity:SULFURIC ACID MIST: IARC MONOGRAPHS ON
EVAL OF CARCIN RISK OF CHEM TO MAN, VOL 54, PG 41, 1992:GRP 1
ANIMAL:PULM IRRIT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY DISEASE.
PRE-EXISTING EYE PROBLEMS. PRE-EXISTING SKIN DISORDERS. IMPAIRED
LIVER FUNCTION. IMPAIRED KIDNEY FUNCTION.

First Aid:IN ALL CASES SEEK QUALIFIED EVALUATION. EYES:IRRIGATE
IMMEDIATELY WITH LARGE QTYS OF RUNNING WATER FOR AT LEAST 15
MINUTES. SKIN:WATER FLUSH IMMEDIATELY. REMOVE ANY CONTAMINATED
CLOTHING. INHAL:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION
IF NECESSARY. INGEST:DILUTE IMMEDIATELY WITH WATER OR MILK. DO NOT
INDUCE VOMITING. GET MEDICAL HELP.

Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .

Spill Release Procedures:COVER WITH SODA ASH, MIX AND SCOOP INTO
BEAKER. NEUTRALIZE WITH 6-MOLAR HYDROCHLORIC ACID AND WASH DOWN
DRAIN WITH EXCESS WATER.
Neutralizing Agent:6-MOLAR HYDROCHLORIC ACID

Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NORMAL ROOM VENTILATION IS ADEQUATE. NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NORMAL ROOM VENTILATION IS ADEQUATE.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOGG & (SUPP DATA)
Other Protective Equipment:LAB COAT OR LAB APRON. EMER EYEWASH AND
DELUGE SHOWER WHICH MEET ANSI DESIGN STANDARDS .
Work Hygienic Practices:WASH HANDS AFTER HANDLING THIS OR ANY OTHER
CHEMICAL BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
WASTE DISP METH:WASHING TO DRAIN WITH LARGE EXCESS OF WATER. SLUDGE MAY
BE ADDED TO LANDFILL. EYE PROT:FULL LENGTH FACESHIELD .

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.08 (H*2O=1)
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:INFINITE
Appearance and Odor:CLEAR, LIGHT GREEN, ODORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
METALS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DISP OF IN ACCORD W/LOCAL, STATE AND FED REGS .
ADD SLOWLY TO LG CONTAINER OF WATER. STIR IN SLIGHT EXCESS OF SODA
ASH. LET STAND 24 HOURS. DECANT OR SIPHON INTO ANOTHER CONTAINER
AND NEUTRALIZE WITH 6-MOLAR HYDROCHLORIC ACID BEFORE (SUPP DATA)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.