Product ID:1,1,2-TRICHLOROTRIFLUOROETHANE, 0400727
MSDS Date:02/24/1990
FSC:6810
NIIN:00N056261
MSDS Number: BWNBP

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 609-222-0342

Cage: DO242

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM;1250 STEL

LD50 LC50 Mixture:LD50:(ORAL,RAT) 43 G/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LEVELS OF 2600 PPM CAUSE DROWSINESS,
LOSS OF CONCENTRATION, POSSIBLE NARCOSIS, POSSIBLE CARDIAC
ARRHYTHMIA AT HIGHER CONCENTRATIONS. LIQUID & VAPOR IRRITATING TO
SKIN, EYES OR MUCOUS MEMBRANES. CHLORO FLUOROCARBON (CFC) MATERIALS
HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN LAB
ANIMALS & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:COULD HAVE SIMILAR EFFECT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED
TO CFC'S .
Medical Cond Aggravated by Exposure:HEART CONDITIONS.

First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
SKIN:WASH THOROUGHLY W/SOAP & WATER. EYES:IMMEDIATELY FLUSH
THOROUGHLY W/WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH
AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED.
INGEST:DO NOT INDUCE VOMITING; GET IMMEDIATE MEDICAL ATTENTION.

Flash Point:NONCOMBUSTIBLE
Extinguishing Media:USE ANY SUITABLE FOR ADJACENT MATERIAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES, CHLORIDES & PHOSGENE . THERMAL DECOMPOSITION
PRODUCES TOXIC FUMES.

Spill Release Procedures:DIKE SPILL. TAKE UP W/ABSORBENT & CONTAINERIZE
FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN
COOL, DRY AREA, AWAY FROM IGNITION SOURCES & OXIDIZERS. DO NOT
BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN/ON CLTHG.
Other Precautions:DO NOT TAKE INTERNALLY. NO SMOKING IN AREA OF USE. DO
NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT
SURFACES. HEAT &/OR UV RADIATION MAY CAUSE THE FORMATION OF
CHLORIDES, FLUORIDES OR PHOSGENE .

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN IN
THE ABSENCE OF ADEQUATE VENTILATION.
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
HOOD OR W/ADEQUATE VENTILATION.
Protective Gloves:VITON OR EQUIVALENT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH & SAFETY EQUIPMENT SHOULD BE
READILY AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MATLS TO AVOID:LITHIUM, SAMARIUM.

Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:-141F,-96C
Vapor Pres:334 @ 20C
Vapor Density:6.5
Spec Gravity:1.57
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID; SLIGHT ETHER ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CORROSIVES, OXIDIZERS. MAY REACT EXPLOSIVELY ON CONT W/ACTIVE METALS:
NA, K, BA, AL, BE, MO, ZN, TITANIUM, (SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME (TEMPERATURES >200C).
Hazardous Decomposition Products:CHLORIDES, FLUORIDES & PHOSGENE .
HALOGEN ACIDS, HALOGENS, CARBONYL HALIDES.

Waste Disposal Methods:WASTE DISPOSAL TO BE PERFORMED IN COMPLIANCE
W/ALL CURRENT LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.