Product ID:11135 LACTOL SPIRITS
MSDS Date:12/08/1993
FSC:6810
NIIN:00-238-8119
MSDS Number: BWSDN

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 800-424-9300(CHEMTREC)/503-641-3222

Info Phone: 213-977-7589 OR 800-967-7601

Cage: 23034

HOC INDUSTRIES, INC

2609 WICHITA, KS 67219 US

Telephone: 316-838-4663

Cage: 0A9L8

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 1-3%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-HEPTANE

CAS: 142-82-5

RTECS: MI7700000

OSHA PEL 500 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9293

METHYLCYCLOHEXANE

CAS: 108-87-2

RTECS: GV6125000

OSHA PEL 500 PPM

ACGIH TLV: 400 PPM; 9293

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-18%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

C6-C8 PARAFFINS AND CYCLOPARAFFINS

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

SOLVENT NAPHTHA, LIGHT ALIPHATIC (VM & P NAPHTHA)

CAS: 64742-89-8

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAUSES SKIN & EYE IRRITATION.
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS & CAUSE DAMAGE. LOW
TO MODERATE DEGREE OF TOXICITY IF INHALED. OR SWALLOWED. CHRONIC:
REPEATED & PROLONGED OCCUPATI ONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUEPECTED CARCINOGEN.
Effects of Overexposure:EYES-IRRITATION, STINGING, WATERING, REDNESS, &
SWEELING. SKIN-REDNESS, BURNING, DRYING & CRACKING OF SKIN.
INHALED-HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION,
FATIGUE, IRRITATION OF NOSE/T HROAT. INGESTED-IRRITATION OF GI
TRACT,NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN
DISORDERS,RESPIRATORY (ASTHMA-LIKE) DISORDERS,KIDNEY DISORDERS,&
LIVER.EXPOSURE MAY CAUSE IRREGULAR HEART BEATS;PERSONS WITH
PRE-EXISTING HEART DISORDERS MAY BE MORE SUSCEPTIBLE.

First Aid:INHALATION-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION
IF NOT BREATHING. GET MEDICAL ATTENTION. EYE-FLUSH WITH WATER FOR
15 MINUTES WHILE HOLDING LID OPEN. GET MEDICAL ATTENTION. SKIN-WASH
WITH S OAP & WATER. REMOVE CONTAMINATED CLOTHING. INGESTION-IF
CONSCIOUS & ALERT, INDUCE VOMITING UNDER DIRECTION OF DOCTOR OR
POISON CONTROL CENTER. GET MEDICAL ATTENTION IMMEDIATELY.

Flash Point Method:TCC
Flash Point:20.0F,-6.7C
Autoignition Temp:Autoignition Temp Text:580F
Lower Limits:1.0
Upper Limits:7.0
Extinguishing Media:DRY CHEMICALS, CARBON DIOXIDE, FOAM, HALON. WATER
MAY BE AN INEFFECTIVE EXTINGUISHING AGENT.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROTECTIVE CLOTHING
AND SELF-CONTAINED BREATHING APPARATUS. ISOLATE DAMAGE AREA, DENY
ENTRY. STOP SPILL IF MINIMAL RISK.
Unusual Fire/Explosion Hazard:MATERIAL IS FLAMMABLE, MAY TRAVEL TO
DISTANT SOURCE OF IGNITION & FLASHBACK. VAPORS ARE HEAVIER THAN AIR
AND MAY COLLECT IN LOW AREAS.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. USE
NON-SPARKING TOOLS. ISOLATE & DENY ENTRY. WEAR PROPER PROTECTIVE
GEAR. PREVENT SPILL FROM ENTERING SEWERS, WATERWAYS. ABSORB ONTO
APPROPRIATE ABSORBANT MATERIAL. NOTIFY USCG AT 800-424-8802 IF
ENTERS WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTIALTED
PLACE AWAY FROM SOURCES OF IGNITION & INCOMPATIBLE MATERIALS. OPEN
CONTAINER SLOWLY.
Other Precautions:BOND & GROUND VESSELS DURING TRANSFERS. DO NOT ENTER
CONFINED SPACES WITHOUT FOLLOWING ENTRY PROCEDURES IN ASTM D-4276 &
29CFR1910.146. "EMPTY" CONTAINERS RETAIN RESIDUES. DO NOT
PRESSURIZE, CUT, WELD , ETC. THEY MAY EXPLODE, CAUSING INJURY.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERVIOUS-NITRILE, BUTYL, VITON.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. IMPERVIOUS
CLOTHING TO PREVENT REPEATED/PROLONGED SKIN CONTACT.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
TARGET ORGANS: CENTRAL NERVOUS SYSTEM, KIDNEY, LIVER, HEARING.
INTENTIONAL MISUSE BY DELIBERATLEY CONCENTRATING & INHALING THIS
MATERIAL MAY BE HARMFUL/FATAL. EPA/CERCLA RQ'S: RQ #1-TOLUENE, 1000
LB E QUAL TO 5556 LBS (890 GALLONS THIS MATERIAL); RQ
#2-CYCLOHEXANE, 1000 LB EQUAL TO 33333 LB (5342 GALLONS THIS
MATERIAL).

HCC:F2
Boiling Pt:B.P. Text:201F,94C
Vapor Pres:25
Vapor Density:3.4
Spec Gravity:0.746
Viscosity:0.68 CST
Evaporation Rate & Reference:3.9 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WATER WHITE LIQUID; LIGHT HYDROCARBON ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REDUCING AGENTS.
Stability Condition to Avoid:ALL POSSIBLE SOURCES OF IGNITION. AVOID
EXPSOURE TO INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:RCRA WASTE NUMBERS D001 AND D018 MAY APPLY IF
UNUSED/UNCONTAMINATED. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. SARA 313-TOLUENE, CAS# 108-88-3, 10-18%;
CYCLOHEXANE, CAS# 110- 82-7, 1-3%.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.