BXPVQ - AMMONIUM HYDROXIDE SOLUTION

Product Identification

Product ID:AMMONIUM HYDROXIDE SOLUTION
MSDS Date:01/12/1987
FSC:6810
NIIN:01-031-5513
MSDS Number: BXPVQ

Responsible Party
SCIENCE KIT & BOREAL LABORATORIES
777 EAST PARK DRIVE
TONAWANDA, NY 14150-6784
US

Emergency Phone: 800-828-7777

Info Phone: 716-874-9572

Preparer: ALEXANDER PICCIRILLI

Cage: 57020

Contractor
SCIENCE KIT INC
TONAWANDA, NY 14150-6708 US

Telephone: 716-874-6020

Cage: 57020

Ingredients

AMMONIA (SARA 302/313) (CERCLA) (DISSOLVED IN WATER TO FORM

CAS: 7664-41-7

RTECS: BO0875000

Fraction By Weight: 29%

OSHA PEL 50 PPM

ACGIH TLV: 25 PPM/35 STEL; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS


WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 71%

Hazards

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 350 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES SEVERE IRRITATION OR BURNS TO
EYES, SKIN AND MUCOUS MEMBRANES; HIGHLY TOXIC BY ORAL AND
INHALATION ROUTES. INHALATION OF AMMONIA GAS CAUSES EDEMA, SPASM,
AND ASPHYXIA. CHRONIC: NONE SPECIFIED B Y MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED-EDEMA, SPASM, ASPHIXIA. EYES-PAIN,
BURNING, TEARS. SKIN-BURNS, REDNESS, PAIN. INGESTED-PAIN, BURNS TO
MOUTH & THROAT, STOAMCH PAIN, NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid

First Aid:SKIN-FLOOD WITH WATER, THEN WASH WITH VINEGAR. EYES-FLUSH
WITH LOTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL
ATTENTION. INHALED-REMOVE TO FRESH AIR. RESTORE BRETAHING IF
REQUIRED. GET M EDICAL ATTENTION. INGESTED-IF CONSCIOUS,GIVE LOTS
OF WATER. FOLLOW WITH FRUIT JUICE AND VEGATABLE OIL. GET PROMPT
MEDICAL ATTENION.

Fire Fighting

Flash Point:NON-FLAMMABLE
Lower Limits:16
Upper Limits:25
Extinguishing Media:USE ANY MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:WHEN HEATED,EMITS TOXIC FUMES.AMMONIUM
HYDROXIDE IS NON-COMBUSTIBLE & NON-EXPLOSIVE;BUT AMMONIA VAPORS
RELEASED FROM SOLUTION CAN FORM AN EXPLOSIVE MIXTURE.

Accidental Release

Spill Release Procedures:WEARING PROTECTIVE EQUIPENT, CAREFULLY
NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS
AMOUNTS OF WATER. NOTE: DISCHARGE, TREATMENT OR DISPOSAL MAY BE
SUBJECT TO LOCAL, STATE AND/OR F EDERAL REGULATIONS.
Neutralizing Agent:SODIUM BISULFATE.

Handling

Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM
ACIDS AND ACID FUMES OR OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE.
Other Precautions:READ LABEL ON CONTAINER BEFORE USING. FOR LABORATORY
USE ONLY. NOT FOR FOOD, DRUG OR HOUSEHOLD USE. KEEP OUT OF REACH OF
CHILDREN.

Exposure Controls

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RUBBER.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:GOGGLES, FACESHIELD, LAB COAT, APRON,
VENTILATION HOOD, EYE WASH STATION.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
PER DLSC-TIR NSN CANCELLED WITHOUT REPLACEMENT 91274; HOWEVER,
SAMMS-CTDF DOES NOT!!?? HAVE SUCH A STATEMENT-CTDF HAS FULL DATA ON
NSN.

Chemical Properties

HCC:B1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:-107F,-77C
Vapor Pres:584 MM HG
Vapor Density:<1
Spec Gravity:0.896-0.902
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:WATER, WHITE LIQUID; STRONG PUNGENT AMMONIA ODOR.
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
ACIDS, ACROLEIN, DIMETHYL SULFATE, HALOGENS, SILVER NITRATE, SILVER
PERMANGANATE.
Stability Condition to Avoid:WHEN HEATED, EMITS TOXIC FUMES.
Hazardous Decomposition Products:AMMONIA FUMES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Disposal

Waste Disposal Methods:WEARING PROPER PROTECTIVE CLOTHING, CAREFULLY
NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS
AMOUNTS OF WATER. DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO LOCAL, STAE AND/OR F EDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.