Product ID:101 3176 LIQUID DEVELOPER SYSTEM CLEANER, CONCENTRATE
MSDS Date:12/17/1997
FSC:6750
NIIN:01-026-9410
MSDS Number: BXXLG

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM DICHROMATE (NA2(CR2O7))

CAS: 10588-01-9

RTECS: HX7700000

OSHA PEL SEE TABLE Z-2

ACGIH TLV: 0.05 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

SULFURIC ACID

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
HARMFUL IF INHALED. EYES: CAUSES SEVERE BURNS. SKIN: CAUSES SEVERE
BURNS. HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: HARMFUL IF SWA LLOWED. MAY CAUSE BURNS OF THE
GASTROINTESTINAL TRACT IF SWALLOWED. CAN CAUSE KIDNEY DAMAGE.
Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC): GROUP 1, STRONG INORGANIC MISTS OR VAPORS CONTAINING
SULFURIC ACID, HEXAVALENT CHROMIUM COMPOUNDS - AMERICAN CONFERENCE
OF GOVERNMENTAL INDUSTRIAL H YGIENISTS (ACGIH): GROUP A1 CONFIRMED
HUMAN CARCINOGEN, HEXAVALENT CHROMIUM COMPOUNDS - NATIONAL
TOXICOLOGY PROGRAM: HEXAVALENT CHROMIUM COMPOUNDS OSHA: NONE
Effects of Overexposure:EYES: CAUSES SEVERE BURNS. SKIN: CAUSES SEVERE
BURNS. INGESTION: MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF
SWALLOWED.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION
IMMEDIATELY. SKIN : IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED CLOTHING
BEFORE REUSE. DESTR OY OR THOROUGHLY CLEAN CONTAMINATED SHOES.
INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE
ANYTHING BY MOUTH TO AN UN CONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG OXIDIZER.
DRIED PRODUCT RESIDUE CAN ACT AS AN OXIDIZER.

Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.
Other Precautions:DO NOT BREATHE MIST OR VAPOR. MINIMIZE THE POTENTIAL
FOR THE PRODUCTION OF AEROSOLS. DO NOT GET IN EYES, ON SKIN, ON
CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE CARTRIDGE
RESPIRATOR ACID GAS WITH DU ST/MIST PREFILTER. IF RESPIRATORS ARE
USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA
STANDARD 29 CFR 1910.134.
Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A
FACE SHIELD.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
THE FOLLOWING GLOVES HAVE BEEN SHOWN TO BE IMPERVIOUS UNDER THE
INDICATED CONDITIONS: NEOPRENE RUBBER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED.

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.262
pH:<1.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:ORANGE LIQUID. ODOR: SLIGHT ACRID.
Percent Volatiles by Volume:65-70 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS BASES, COMBUSTIBLE MATERIAL.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:SUFLUR DIOXIDE.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. CONTRACT WITH A LICENSED
CHEMICAL DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUE, FOLLOW LABEL WA RNINGS EVEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:GENERAL: INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC) HAS DETERMINED THAT OCCUPATIONAL EXPOSURE TO
HEXAVALENT CHROMIUM COMPOUNDS AND STRONG INORGANIC MISTS OR
VAPORS CONTAINING SULFURIC AC ID ARE CARCINOGENIC TO HUMANS.
BECAUSE THIS PRODUCT CONTAINS CHROMIUM IN A WATER-BASED SOLUTION,
IT IS VERY UNLIKELY TO BE AN INHALATION EXPOSURE HAZARD. THIS
PRODUCT IS NOT EXPECTED TO GENER ATE MISTS OR VAPORS WHEN
PRODUCT INSTRUCTIONS FOR MIXING AND USE ARE FOLLOWED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: NO
BIOCHEMICAL OXYGEN DEMAND AND NO POTENTIAL TO CAUSE OXYGEN
DEPLETION IN AQUEOUS SYSTEMS, A HIGH POTENTIAL TO AFFECT SOME
AQUATIC ORGANISMS, A HIGH POTENTIAL TO AFFECT SECONDARY WASTE
TREATMENT MICROBIAL METABOLISM, A HIGH POTENTIAL TO AFFECT THE
GERMINATION AND/OR EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL TO
BIOCONCENTRATE. AFTER DILUTION WITH A LARGE AMOUNT OF WATER,
FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT
EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: CHROMIUM (VI) COMPOUNDS
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: HEXAVALENT CHROMIUM COMPOUNDS -
MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE
REPRODUCTIVE EFFECTS: NONE