Product ID:37-THINNER
MSDS Date:12/15/1992
FSC:8010
NIIN:00N011064
MSDS Number: BXYHV

PRO-LINE PAINT CO

2646 MAIN ST
SAN DIEGO, CA 92113-3697
US

Emergency Phone: 800-535-5053 (INFOTRAC)

Info Phone: 619-231-2313

Preparer: E. SOETERIK

Cage: 9D157

PRO-LINE PAINT CO

SAN DIEGO, CA 92113-3697 US

Telephone: 619-231-2313; 619-232-8968

Cage: 9D157

NO SMOKING SIGNS. USE ONLY W/ADEQ VENT. ODOR IS

RTECS: 9999999ZZ

& USE CARE WHEN HANDLING CHEMICAL & PETROLEUM

RTECS: 9999999ZZ

AREA, WEAR AIR-FED HOOD.

RTECS: 9999999ZZ

ETHANE, 1,1,1-TRICHLORO-; (AEROTHENE) (SARA 313) (CERCLA)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 100%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TERT-BUTYL ALCOHOL (SARA 313)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 1.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

BUTANE, 1,2-EPOXY-; (1,2-BUTYLENE OXIDE) (SARA 313)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: 0.5%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANE, DIMETHOXY-; (DIMETHOXYMETHANE)

CAS: 109-87-5

RTECS: PA8750000

Fraction By Weight: 1.9%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EXEMPT 0 G/L

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY

RTECS: 9999999ZZ

WEAR NIOSH/MSHA APPROVED AIR-FED HOOD.

RTECS: 9999999ZZ

TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH

RTECS: 9999999ZZ

PETROLEUM PRODUCTS & THEIR VAPORS.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . INHAL: MAJOR ROUTE
OF EXPOS, LOW (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: TOX; ACUTE EXPOS IN 1000 PPM RANGE
CAUSES NARCOS. OVEREXP CAN CAUSE DIZZ, DRUNKENNESS & DROW, UNCON &
EVEN DEATH. SKIN/EYES: BURNING SENSATION FROM VAP/LIQ. DERM,
SENSIT, NO CORNEAL INJURY L IKELY. MAY CAUSE CONJ. ABSORBED THRU
SKIN: PRLNG/RPTD SKIN CNTCT CAN CAUSE DEFAT. ABSORPTION IS NOT
SIGNIFICANT (SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA AND SKIN ALLERGIES.

First Aid:EYES: FLUSH IMMED W/FRESH WATER FOR AT LEAST 15 MIN BY EYE
WASH APPARATUS/BY HAND. SEEK MED ATTN. SKIN: WASH IMMED W/WATER.
THEN WASH W/SOAP & WATER. RINSE IMMED. SEEK MED ATTN. INHAL: MOVE
TO FRESH A IR; ARTF RESP IF NEC. SEEK MED ATTN. INGEST: SEEK MED
ATTN. DO NOT INDUCE VOMIT. REC TO MD: IN ACUTE CASES SEEK MED ATTN
IMMED. FOR WORKERS WHO MAY BE EXPOS REGULARLY, PROVIDE DETAILED
PERIODIC EXAMS.

Flash Point:NONE
Lower Limits:7.3% @ 28C
Upper Limits:13.9% @ 28C
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP. BLANKET FLAME W/EXTING MEDIA. VAPS OF COMBUST MAY
BE IRRIT TO RESP TRACT. MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL . KEEP MATL AWAY FROM HEAT, SPARKS & OPEN FLAMES.
EXPOSURE TO EXTREME FIRE CAN CAUSE EMISSION OF PHOSGENE.

Spill Release Procedures:REMOVE ALL TYPES OF IGNITION SOURCES. PROVIDE
SUFFICIENT VENTILATION. PROTECT CLEAN-UP PERSON WITH NIOSH/MSHA
APPROVED 8540 3M CORP RESPIRATOR AND GOGGLES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG TO CNTNRS
& SPILLAGE. STORE IN COOL, WELL VENT AREA W/SPRINKLER SYSTEM. KEEP
AWAY FROM HEAT. POST NO SMOKING SIGNS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:USE NIOSH/MSHA APPRVD DUST/MIST RESP (HIGH
EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING/SANDING. USE NIOSH/MSHA
APPRVD ORG VAP CARTRIDGE RESP IF TLV FOR SOLVS MAY BE EXCEEDED,
E.G. 8540 EM CORP RESP. WH EN USING IN CONFINED AREAS, (ING 7)
Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED
AREAS. KEEP VAPORS BELOW TLV.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:USE PROT CLTHG & CHANGE CONTAMD CLTHG IMMED.
PROVIDE EMER SHOWERS & EYEWASH AT STATIONARY PAINT APPLICATION
FACILITIES.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES BEFORE THEY WORK WITH THIS PRODUCT.
Supplemental Safety and Health
FIRE FIGHT PROC: BRTHG DFCLTY. PVNT HUMAN EXPOS TO FIRE, SMOKE, FUMES,
ETC. EFTS OF OVEREXP: EXPOS ROUTE. INGEST: CAN CAUSE BURNING
SENSATION, VOMIT, DIARR, DROW. INGEST OF SM QTYS IS NOT LIKELY TO
BE TOXIC. REPORTS HAVE SHOWN THAT ASSOC RPTD & PRLNG OCCUP OVEREXP
TO SOLVS CAN CAUSE PERM BRAIN & NERVOUS (ING 6)

Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 @ 20C
Vapor Density:4.55
Spec Gravity:1.298 @ 25C
Evaporation Rate & Reference:0.4 (BUTYL ACETATE=1)
Solubility in Water:0.07G/100G @ 25C
Appearance and Odor:COLORLESS LIQUID; IRRITATING ODOR AT HIGH
CONCENTRATIONS.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, OXIDIZING MATERIALS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES. DO NOT ALLOW
VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:PHOSGENE. FLAM FUMES MAY ACCUM IN
CONFINED AREA & SPKS/OPEN FLAMES MAY IGNITE IT. DECOMP PRDCES
HYDROGEN CHLORIDE.

Waste Disposal Methods:USE METAL CONTAINER MARKED "DO NOT REUSE." PUT
THE MATERIAL IN THIS CONTAINER. USE VERMICULITE OR OTHER INERT
ABSORBENT. KEEP AWAY FROM SEWER. NOTE: DISPOSE OF ALL WASTES IN
ACCORDANCE WITH FEDERAL, S TATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.