Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
MSDS Date:03/14/1990
FSC:6810
NIIN:01-210-0149
MSDS Number: BXYXX

Emergency Phone: 800-354-2050/314-539-1600

Info Phone: 800-354-2050(PRESS 3)/314-982-5000

Cage: 62910

Telephone: 908-859-2151

Cage: 62910

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL9495

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ANESTHETIC IF INHALED.INHALATION
OF VERY HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION,CARDIAC
ARRHYTHMIAS.CONTACT MAY CAUSE SKIN IRRITATION/DEFATTING;EYE
IRRITATION/POSSIBLE EYE DAMAGE.NO INFORMAT ION FOUND ON
INGESTION,MAY PRODUCE SIMILAR TO
INHALATION.CHRONIC:PROLONGED/REPEATED EXPOSURE MAY CAUSE
DERMATITIS.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED-INCOORDINATION, CARDIAC ARRHYTHMIAS,
DROWSINESS, EXCITEMENT. EYES-REDNESS, TEARING, DISCOMFORT.
SKIN-DEFATTING, REDNESS, DISCOMFORT. INGESTED-NO INFORMATION FOUND.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR
EYE DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE
SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.

First Aid:IN ALL CASES CALL A PHYSICIAN. EYES-IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH
MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN
OR ARTIFI CIAL RESPIRATION AS NEEDED. INGESTED-IFCONSCIOUS, INDUCE
VOMITING IMMEDIATELY BY GIVING WATER OR MILK & STICK FINGER DOWN
THROAT. NOTE TO DR: DO NOT USE EPINEPHRINE!

Flash Point:NON-FLAMMABLE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN
PRESSURE DEMAND OR POSITIVE PRESSURE MODE AND FULL PROTECTIVE GEAR.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD.

Spill Release Procedures:VENTILATE AND EVACUATE AREA. CLEAN-UP
PERSONNEL REQUIRE CLOTHING AND RESPIRATORY PROTECTION. ELIMINATE
ALL SOURCES OF IGNITION. CONTAIN & RECOVER. ABSORB WITH INERT
MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER.
STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM SOURCES OF
IGNITION. PROTECT AGAINST PHYSICAL DAMAGE.
Other Precautions:ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT WEAR
CONTACT LENSES WHEN USING THIS PRODUCT.

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NITRILE, PVA.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:WEAR CLEAN, BODY COVERING CLOTHING.
DLA-HMIS: EYE WASH.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
ENVIRONMENTAL DATA: SARA 311/312-ACUTE, CHRONIC; SARA
313-1,12-TRICHLORO-1,2,2-TRIFLUOROETHANE, CAS# 70-13-1, 100%; SARA
302-RQ/NO, TPQ/NO; CERCLA 103/NO; RCRA 261.33/NO.

HCC:N1
Boiling Pt:B.P. Text:117F,47C
Melt/Freeze Pt:M.P/F.P Text:-33F,-36C
Vapor Pres:334
Vapor Density:6.5
Spec Gravity:1.57
Evaporation Rate & Reference:0.3 (CCL4=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ETHEREAL ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS (POWDERED ALUMINUM, ZINC, BERYLLIUM,
MAGNESIUM), HEAT AND OPEN FLAME.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC VAPORS AND GASES SUCH AS HALOGEN
ACIDS, HALOGENS AND CARBONYL ALKALIES MAY BE RELEASED IF INVOLVED
IN FIRE.
Conditions to Avoid Polymerization:HTIS PRODUCT DOES NOT POLYMERIZE.

Waste Disposal Methods:WASTE MAY BE CONTAINERIZED AND DISPOSED IN A
RCRA APPROVED FACILITY. DO NOT FLUSH TO SEWER!

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.