Product ID:24160U
MSDS Date:05/08/1995
FSC:8010
NIIN:00N062432
MSDS Number: BYGSV

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-441-3637

Preparer: T R LOUER

Cage: B0589

E I DU PONT DE NEMOURS & CO

BRUSSEL, DE 19898 BE

Telephone: 32-(0)15-401.505

Cage: B0589

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: <4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

COPPER, (PHTHALOCYANINATO (2-))-; (PHTHALOCYANINE BLUE

CAS: 147-14-8

RTECS: GL8510000

Fraction By Weight: <3%

OSHA PEL N/K

ACGIH TLV: N/K

QUINACRIDONE PIGMENT

CAS: 1047-16-1

Fraction By Weight: <2%

OSHA PEL N/K

ACGIH TLV: N/K

ACRYLIC POLYMER

CAS: 25068-63-7

Fraction By Weight: <60%

OSHA PEL N/K

ACGIH TLV: N/K

2-PROPENOIC ACID 2-METHYL-METHYL ESTER, POLYMER

CAS: 80010-53-3

Fraction By Weight: <26%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 3-7%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-HEPTANONE; (METHYL N-AMYL KETONE)

CAS: 110-43-0

RTECS: MJ5075000

Fraction By Weight: <2%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (CERCLA)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: <8%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: <46%

OSHA PEL N/K

ACGIH TLV: N/K

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 20-30%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE NOSE & THROAT
IRRIT. MAY CAUSE CNS DEPRESS CHARACT BY THESE PROGRESSIVE STEPS:
HDCH, DIZZ, NAUS, STAG GAIT, CONFUSN, UNCON. REPORTS HAVE ASSOC
RPTD/PRLNG OVEREXP TO SOLV W/PERM BRAIN & CNS DMG. INGEST: MAY
RSLT IN GI DISTRESS. EYES: MAY CAUSE IRRIT/BURNING. SKIN:
RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT W/DISCOMFORT & DERM. TITANIUM
DIOXIDE: IN LIFETIME INHAL TEST, LUNG CANCERS WERE FOUND IN SOME
RATS EXPOS TO 250 MG/M3 RESP TITANIUM DUST. ANALYSIS OF TITANIUM
DIOXIDE CONCS IN RAT'S LUNGS SHOWED LUNG CLEARANCE MECHANISM WAS
OVERWHELMED & RSLTS AT MASSIVE 250 MG/M3 LEVEL ARE NOT RELEVANT TO
(EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: WORKPLACE. TOLUENE: RECURRENT
OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS
HAVE PRODUCED IRREGULAR HEARTBEAT IN ANIMALS & OCCAS PALPITATIONS
IN HUMANS. RATS EXPOS TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBITED
HIGH FREQUENCY HEARING DEFICITS. SIGNIFICANCE OF THIS TO MAN IS
UNKNOWN. METHYL AMYL KETONE: INGEST STUDIES ON LAB ANIMALS SHOWED
VERY HIGH ORAL DOSES CAUSED INCR LIVER & KIDNEY WTS. ETHYL
ACETATE: PRLNG/RPTD HIGH EXPOS OF LAB ANIMALS RSLTD IN SECONDARY
ANEMIA W/INCR IN WHITE BLOOD CELLS, FATTY DEGENERATION, CLOUDY
SWELLING & EXCESS OF BLOOD IN VARIOUS ORGANS. PROPYLENE GLYCOL
MONOMETHYL (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY
PERSISTS OR OCCURS LATER, CONSULT MD. INGESTION: CALL MD
IMMEDIATELY AND HAVE THE NAMES OF THE INGREDIENTS AVAILABLE. SKIN:
WASH WITH SOAP AND WATER. IF IRRITATION OCCURS, CONTACT MD. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
CALL MD.

Flash Point Method:CC
Flash Point:>20F,>-7C
Lower Limits:1.0%
Upper Limits:13.1%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMMABLE VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPS BELOW FLASH POINT.

Spill Release Procedures:AVOID PROLONGED CONTACT WITH SKIN AND
BREATHING OF VAPOR. REMOVE SOURCES OF IGNITION. REMOVE WITH INERT
ABSORBENT. VENTILATE AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING.
Other Precautions:DO NOT SAND, FLAME-CUT, BRAZE OR WELD DRY COATING
WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE
VENTILATION.

Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR APPROP, PROPERLY
FITTED RESP (NIOSH/MSHA APPRVD) DURING & AFTER APPLICATION UNLESS
AIR MONITORING DEMONSTRATES VAP/MIST LEVELS ARE < APPLIC LIM.
FOLLOW RESP MFR'S DIREC TIONS FOR RESP USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOLUME & PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA AND OTHER SUGGESTED EXPOS LIMS.
Protective Gloves:NEOPRENE OR "VITON" GLOVES ARE REC.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THORO AFTER HNDLG & BEFORE EATING & SMKNG.
USE APPROPRIATE INDUSTRIAL HYGIENE PRACTICES.
Supplemental Safety and Health
EFTS OF OVEREXP: ETHER: MAY CAUSE MOD EYE BURNING. RECURRENT OVEREXP
MAY RSLT IN LIVER & KIDNEY INJURY. XYLENE: HIGH CONCS HAVE CAUSED
EMBRYOTOXIC EFTS IN LAB ANIMALS. RECURRENT OVEREXP MAY RSLT IN LI
VER & KIDNEY INJURY. CAN BE ABSORBED THRU SKIN IN HARMFUL AMTS.
TOLUENE APPEARS ON THE NAVY LIST OF OCCUP (OTHER INFO)

Boiling Pt:B.P. Text:>169F,>76C
Vapor Pres:76.00
Vapor Density:3.00
Spec Gravity:1.04 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT SOLUBLE
Appearance and Odor:SEMI-VISCOUS LIQUID, WITH CHARACTERISTIC ODOR

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:CARBON MONOXIDE (CO), CARBON DIOXIDE
(CO*2), SMOKE.

Waste Disposal Methods:DO NOT ALLOW MATL TO CONTAM GROUND WATER SYS.
BURN/DISP OF ABSORBED MATL IN HAZ WASTE LANDFILL WHICH COMPLIES
W/FED, STATE & LOC REQS. DO NOT INCIN IN CLSD CONTRS. IF RCRA HAZ
WASTE, RQ=1LB, WASTE FRO M PROD IS CLASSED D001 IGNITABLE. IF
LEAD/CHROMIUM IS REPORTED IN INGREDS, WASTE IS THEN CLASSIFIED
EPITOXIC D008 (LEAD) OR EPITOXIC D007 (CHROMIUM).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.