Product ID:PGR
MSDS Date:01/01/1994
FSC:8010
NIIN:00N010570
MSDS Number: BYHFQ

STATE CHEMICAL MFG CO

3100 HAMILTON AVE
CLEVELAND, OH 44114-3763
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

IDENTIFIED AS A SUSPECT CARCINOGEN BY NTP.

RTECS: 9999999ZZ

CARBOXYHEMOGLOBIN LEVELS. MAY INCR

RTECS: 9999999ZZ

IF AT ALL POSSIBLE.

RTECS: 9999999ZZ

WINDY DAY WHEN OVERSPRAY CAN BLOW BACK ONTO

RTECS: 9999999ZZ

EXCEEDING 120F. DO NOT STORE NEAR SPKS/OPEN FLAMES.

RTECS: 9999999ZZ

USE PROD OUTDOORS IF POSS. IF YOU MUST USE IT

RTECS: 9999999ZZ

INSURE FRESH AIR MOVEMENT DURING APPLIC & DRYING. IF

RTECS: 9999999ZZ

ADDNTL PROT. NIOSH/MSHA APPRVD DUST MASK DOES NOT

RTECS: 9999999ZZ

OTHER UNVENT AREAS. CLEAN UP RAGS. PAPERS, & WASTE

RTECS: 9999999ZZ

CNTNRS. DO NOT USE ON RUBB, PLASTIC, LINOLEUM/ANY

RTECS: 9999999ZZ

DOWN & SPRAY SHORT JET OF GAS AFTER EACH JOB. FOLLOW

RTECS: 9999999ZZ

PRODS ARE INTENDED FOR INDUST & INSTITUTIONAL USE

RTECS: 9999999ZZ

OF CHILDREN.

RTECS: 9999999ZZ

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: >60%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <10%

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: <20%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: 1000 PPM (MFR)

BUTANE; (N-BUTANE)

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: <20%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

LOSS OF SENSE OF BALANCE & VISUAL DISTURB. ALSO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAIN ING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS . ACUTE:MAY BE FATAL/CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONO SUPP, VOL
7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC
TO BE (SUPDAT)
Effects of Overexposure:HLTH HAZ:BLINDNESS IF SWALLOWED. CNTNS
METHANOL. VAP HARMFUL. CNTNS METHYLENE CHLORIDE. OVEREXP TO VAPS
MAY RSLT IN HDCH, NAUS, DROW, DIZZ, NASAL & RESP IRRIT. DELIBERATE
INHAL OF CONTENTS CAN BE HARM FUL/FATAL. EYE IRRITANT. DIRECT CONT
W/SKIN WILL RSLT IN IRRIT. CHRONIC:CAN CAUSE MENTAL CONFUSN,
DEPRESS, (SUPDAT)
Medical Cond Aggravated by Exposure:HEART DISEASE, RESPIRATORY
DISORDERS.

First Aid:INGEST:DO NOT INDUCE VOMIT. CALL PHYS IMMED. INHAL:REMOVE
PERSON TO FRESH AIR. IF DFCLTY IN BRTHG OR OTHER SYMPS PERSIST,
CALL PHYS. EYES:FLUSH IMMED W/PLENTY OF COOL WATER FOR @ LEAST 15
MINS. CONT P HYS IMMED. DO NOT WEAR CONT LENSES WHILE WORKING
W/THIS PROD. SKIN:WASH PROMPTLY W/PLENTY OF WATER. IF IRRIT
PERSISTS CONT PHYS. NOTE TO PHYS:OVEREXP TO METHYLENE CHLORIDE MAY
PRDCE ELEVATED (ING 8)

Flash Point Method:TCC
Flash Point:-142F,-97C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . WATER MAY BE INEFTIVE, BUT MAY BE USED TO KEEP CANS
COOL. USE SHIELDING TO PROTECT PERS (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . FLAMMABLE. EXPOSURE TO TEMPERATURES ABOVE
120F MAY CAUSE CAN TO VENT, RUPTURE OR BURST.

Spill Release Procedures:REMOVE ALL SOURCES OF HEAT, SPARKS OR OPEN
FLAMES. VENTILATE AREA OF SPILL. ABSORB SPILL ON OIL ABSORBENT,
SAND OR VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER:POISON. MAY BE HARMFUL/FATAL IF
SWALLOWED. VAP HARMFUL. DIRECT CONT W/EYES OR SKIN WILL RSLT IN
IRRIT. AVOID USING PROD OUTDOORS ON (ING 10)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:VAPOR HARMFUL. AVOID BRTHG OF VAPORS/SPRAY MIST
OF THIS PROD. WEAR NIOSH/MSHA APPRVD SCBA IF PROD MUST BE USED IN
CONFINED AREA. WEAR NIOSH/MSHA APPRVD CARTRIDGE RESP IF TLV IS
EXCEEDED OR WHEN SPRAYI NG MORE THAN ON-HALF CAN CONTINUOUSLY.
Ventilation:USE WITH ONLY ADEQUATE LOCAL MECHANICAL VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG .
Other Protective Equipment:HAVE A SOURCE OF COOL, CLEAN WATER NEARBY IN
CASE OF ACCIDENTAL EYE OR SKIN CONT. WEAR LONG PANTS & LONG
SLEEVES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:FROM VENTING, RUPTURING OR BURSTING CANS. MATLS TO
AVOID:ON RUBBER, PLASTIC, LINOLEUM OR ANY ORGANIC MATL. HAZ DECOMP
PROD:OF PHOSGENE GASES. EXPLAN OF CARCIN:CARCIN. ANIMAL:LUNG, LIV,
SALIVARY, MAMMARY GLAND (TUMORS). EFTSOF OVEREXP:FATG, LOSS OF
APPETITE, NAUS, VOMIT, COUGH, (ING 6)

Boiling Pt:B.P. Text:>-40F,>-40C
Vapor Density:4.0
Spec Gravity:0.9 (WATER =1)
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NIL
Appearance and Odor:A CLEAR AEROSOL GEL WITH A STRONG SOLVENT ODOR.
Percent Volatiles by Volume:>90

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CAUSTICS OR CHEMICALLY ACTIVE LIGHT METALS. MAY
ADVERSELY AFFECT SOME PLASTICS. DO NOT USE (SUPDAT)
Stability Condition to Avoid:FLAMMABLE. DO NOT EXPOSE TO TEMPERATURES
ABOVE 120F, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING THIS PROD MAY RSLT IN
FORMATION OF CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE OR
TRACES (SUPDAT)

Waste Disposal Methods:DO NOT INCIN CANS. CONTENTS UNDER PRESS. DISP OF
LIQ AS AN EPA RCRA HAZARDOUS WASTE. FOLLOW ALL FEDERAL, STATE AND
LOCAL REGULATIONS REGARDING WASTE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.