Product ID:GASOLINE-REGULAR
MSDS Date:03/23/1989
FSC:9150
NIIN:00F045113
MSDS Number: BYLDM

SUN REFINING & MARKETING CO

TEN PENN CENTER 1801 MARKET ST
PHILADELPHIA, PA 19103-1699
US

Emergency Phone: 215-977-3000/800-964-8861

Info Phone: 215-977-6133/215-977-3000

Preparer: JOANNE HOUCK

Cage: 1K762

SUN REFINING AND MARKETING COMPANY

PHILADELPHIA, PA 19103-1699 US

Telephone: 215-977-6133

Cage: 8X531

LEAD ORGANIC

METHYL TERT BUTYL ETHER (MTBE), 2-METHOXY-2-METHYL PROPANE

CAS: 1634-04-4

RTECS: KN5250000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

ACGIH TLV: 890 MG/CUM

BENZENE (SUSPECTED HUMAN CARC BY ACGIH, IARC, ANIMAL

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.1-4.9%

ACGIH TLV: 0.3 MG/CUM (A2) IC

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ADDITIVES

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION TO EYES, NOSE,
THROAT, RESPIRATORY FAILURE. SKIN: MILD IRRITATION REMOVES NATURAL
OILS & FATS. INGESTION: HARMFUL/FATAL. PULMONARY ASPIRATION HAZARD.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:IRRITATION, LOSS OF BALANCE, COORDINATION,
UNCONSCIOUSNESS, COMA, DEATH, TEMPORARY SMARTING, VOMITING.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. SKIN:
WASH W/SOAP & WATER UNTIL NO ODOR REMAINS. EYES: FLUSH W/WATER FOR
15 MINS. INGESTION: DON'T INDUCE VOMITING. DON'T GIVE LIQUIDS.
SMALL AMOUN TS WHICH ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT
UNTIL TASTE OF IT IS GONE. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:-40F
Lower Limits:1.5
Upper Limits:7.6
Extinguishing Media:WATER FOG, CHEMICAL FOAM, DRY CHEMICAL POWDER, CO2.
Fire Fighting Procedures:WEAR SCBA IN CONFINED SPACES.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 750F. EXTREMELY
FLAMMABLE LIQUID (FLASH POINT <20F).

Spill Release Procedures:ARE TOXIC TO FISH & AQUATIC FLORA. PREVENT
IGNITION, STOP LEAK, VENTILATE AREA. CONTAIN. USE WATER SPRAY TO
DISPERSE VAPORS. KEEP UPWIND OF LEAK. WEAR RESPIRATORY PROTECTION
FOR LARGE LEAK/RELEASE. AB SORB ON INERT MATERIAL.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAMES.
NFPA CLASS IA STORAGE. TRANSFER OPERATIONS MUST BE ELECTRICALLY
GROUNDED & BONDED.
Other Precautions:AVOID BREATHING OF MIST/VAPORS & CONTACT W/SKIN.
NEVER SIPHON BY MOUTH. FOR USE AS A MOTOR FUEL ONLY. DON'T USE FOR
ANY OTHER PURPOSE. PRECAUTIONARY LABELING FOR PUMPS, PORTABLE
CONTAINERS & DRUMS IS REQUIRED.

Respiratory Protection:CONCENTRATION IN AIR DETERMINES PROTECTION
NEEDED. USE ONLY NIOSH CERTIFIED RESPIRATORY PROTECTION.
Ventilation:USE ONLY W/ADEQUATE VENTILATION. VENTILATE AS NEEDED TO
COMPLY W/EXPOSURE LIMIT. MECHANICAL VENTILATION RECOMMENDED.
Protective Gloves:IMPERVIOUS
Eye Protection:RECOMMENDED.
Other Protective Equipment:IMPERVIOUS PROTECTIVE GEAR.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
HAZARDOUS WHEN EMPTY FLAMMABLE LIQUID LABEL ARE REQUIRED FOR DRUMS.
EXCESSIVE EXPOSURES TO BENZENE CAN RESULT IN BLOOD DISORDERS
RANGING FROM ANEMIA TO LEUKEMIA. SUN RECOMMENDS EXPOSURE TO BENZENE
BE KEPT <1 PPM FOR 8-HOURS; 5 PPM FOR 15 MINS. NORMAL SERVICE
STATION OPERATIONS ARE BELOW THESE VALUES.

Boiling Pt:B.P. Text:<100-435F
Vapor Pres:325-525
Vapor Density:4
Spec Gravity:0.74
Evaporation Rate & Reference:(ETHYL ETHER =1): >1
Solubility in Water:INSOLUBLE
Appearance and Odor:BRONZE COLORED W/GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS, FLAME.
Hazardous Decomposition Products:COMBUSTION: CO, ASPHYXIANTS, OXIDES OF
LEAD.

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T FLUSH TO DRAIN/STORM SEWER. RCRA HAZARDOUS
WASTE. CONTRACT TO AUTHORIZED DISPOSAL SERVICE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.