Product ID:T&T SPRAY JOHN DEERE GREEN, 1680WZ
MSDS Date:06/27/1995
FSC:8010
NIIN:00N065009
MSDS Number: BZKXQ

ZYNOLYTE PRODUCTS INC

2320 E DOMINGUEZ ST
CARSON, CA 90749
US

Emergency Phone: 303-623-5716;800-424-9300(CHEMTREC)

Info Phone: 310-513-0700

Preparer: JOHN R KORDOSH

Cage: 25461

ZYNOLYTE PRODUCTS CO

6244 CARSON, CA 90749 US

Telephone: 310-513-0700

Cage: 25461

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 41.87%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

200 @ 100F

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

37 @ 100F

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 10%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

LACOLENE; (LIGHT ALIPHATIC PETROLEUM DISTILLATE BP

CAS: 64742-89-8

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

5.1 @ 68F

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 6%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

72 @ 100F

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

22 @ 68F

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 25%

OSHA PEL 200 PPM

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:MAY CAUSE NOSE & THROAT IRRIT.
MAY CAUSE NERV SYS DEPRESS CHARACT BY FOLLOWING PROGRESSIVE
STEPS:HDCH, DIZZ, NAUS, STAG GAIT, LASSITUDE, LOSS OF COORD,
CONFUSN, UNCON. SKIN/EYE CONT:MAY CAUSE IR RIT/BURNING OF EYES.
RPTD/PRLNGD LIQ CONT MAY CAUSE SKIN IRRIT W/DISCOMFORT & DERM. EYE
WATERING, HDCHS NAUS, DIZZ, ETC, ARE SIGNS THAT SOLV LEVELS ARE TOO
HIGH. SKIN ABSORP:SEE INHAL. ORG SOLVS ARE E ASILY ABSORBED. DRY
SKIN, REDNESS/DERM DUE TO DEFAT ACTION OF SOLVS ARE SIGNS OF EXPOS.
INGEST:SEE INHAL. MAY ALSO RSLT IN GI DISTRESS. THERE IS DANGER OF
PETROL DISTILLS ENTERING LUNGS IF SWALLOWED/V OMIT & CAUSING
INFLAM, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS SUPP,
VOL 7, PH 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:
ANTIC TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMRY GLAND
(TUMORS).
Effects of Overexposure:HLTH HAZS: DMG/EVEN DEATH. TOLUENE APPEARS ON
NAVY LISTING OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM
APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE
HNDLG & EXPOS INFO . CHLOROCARB MATLS HAVE PRODCED SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT
IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE- SUSTAINI NG USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBS . RPTS HAVE ASSOC RPTD &
PRLNGD OVEREXP TO SOLV W/PERM BRAIN & NERV SYS DMG. LAB STUDIES
W/RATS HAVE SHOWN THAT PETROL DISTILLS CAUSE KIDNEY DMG &
KIDNEY/LIVER (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.

First Aid:INHALATION:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREF MOUTH-TO-MOUTH. CALL MD. EYE:IMMED FLUSH W/PLENTY OF WATER FOR
@ LST 15 MIN. CALL MD. SKIN:WASH W/SOAP & WATER. IF IRRIT OCCURS,
CONT MD. INGEST:CALL MD IMMED, HAVE NAMES OF HAZ INGS READY, DO
NOT INDUCE VOMIT, KEEP HEAD LOWER THAN WAIST. ASPIR OF VOMIT MAY
RSLT IN CHEM PNEUM &/OR PULM EDEMA.

Flash Point Method:TCC
Flash Point:-256F,-160C
Lower Limits:1%
Upper Limits:25%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . AVOID CONFINED SPACES. WATER MAY BE
UNSUITABLE AS AN EXTINGUISHING MEDIUM.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY ACCUM IN LOW AREAS
OF POOR VENT/TRAVEL ALONG GROUND TO ROMOTE IGNIT SITES. THERMAL
DECOMP PRODS MAY INCLUDE HCL & PHOSGENE .

Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION,
INCLUDING HOT METAL SURFACES. WEAR APPROPRIATE CLOTHING AND GEAR.
PREVENT SKIN CONTACT AND AVOID BREATHING OF VAPOR. CONFINE
IMMEDIATELY AND REMOVE WITH INE RT ABSORBENT SUCH AS CLAY OR SAND.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE ALL LBL PRECS. KEEP AWAY FROM
HEAT, SPKS, OPEN FLAME (I.E. ALL IGNIT SOURCES). CAP CNTNR AFTER
EACH USE.DO NOT STORE ABOVE 120F.
Other Precautions:WASH HANDS THORO AFTER HNDLG & BEFORE EATING/SMKING.
STORE IN DRY, WELL VENT PLACE. DO NOT EXPOSE TO DIRECT SUNLIGHT TO
AVOID BURSTING. DO NOT SPRAY NEAR FIRE/FLAME. AVOID UNNEC CONT. DO
NOT TAKE INTE RNALLY. DO NOT PUNCTURE CNTNRS. USE W/ADEQ VENT-DO
NOT INHAL VAPS. DO NOT SAND, FLAME CUT, BRAZE/WEL D DRY (OTHER
INFO)

Respiratory Protection:DO NOT BRTHE VAPS/MISTS. IF TLV, PEL/OTHER LIMS
ARE EXCEEDED THEN WEAR PROPERLY FITTED VAP & PARTICULATE/POS PRESS
AIR SUPPLIED RESP APPRVD BY NIOSH/MSHA FOR USE W/PAINTS DURING
APPLICATN & UNTIL ALL VAPS & SPRAY MISTS ARE EXHSTED. FOLOW RESP
MFR'S DIRECTIONS FOR PROPER USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP CONTAMS
BELOW APPLIC OSHA REQS/OTHER SUGGESTED EXPOS LIMS. USE ONLY EXPLO
PROOF EQUIP W/FLAM MATLS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
APRON, COVERALLS/WORK CLOTHES. CHANGE CLOTHES & SHOES IN CASE OF
SPILL, SPLASH/EXCESS OVERSPRAY. DO NOT REUSE CLTHG/SHOES WHILE SOLV
ODOR IS (SUPDAT)
Work Hygienic Practices:AS WITH ALL CHEMICAL PRODUCTS, USE CARE IN
HANDLING. DO NOT SMOKE OR EAT WITHOUT FIRST WASHING YOUR HANDS.
Supplemental Safety and Health
OTHER PROT EQUIP: RETAINED IN THEM. PROTECTIVE CREAMS ARE NOT RECOM FOR
PROT BUT MAY BY USED FOR EASE OF CLEANUP. EFTS OF OVEREXP: TUMORS.
THESE EFTS WERE NOT SEEN IN SIMILAR STUDIES W/GUINEA PIGS, DO
GS/MONKEYS. SEVERAL STUDIES EVALUATING PETROL WORKERS HAVE NOT
SHOWN SIGNIFICANT INCREASE OF KIDNEY DMG/ AN (OTHER INFO)

Boiling Pt:B.P. Text:>-43F,>-42C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.85 (H*2O=1)
VOC Grams/Liter:3.32
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:AEROSOL CAN

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS AND BASES, SELECTED AMINES.
Stability Condition to Avoid:NONE REASONABLY FORESEEABLE.
Hazardous Decomposition Products:MAY EMIT FUMES WHEN HEATED TO DECOMP,
CARBON MONOXIDE, CARBON DIOXIDE, UNIDENTIFIED ORG CMPDS. HCL,
PHOSGENE .

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. DISPOSE OF ABSORBED MATERIAL IN ACCORDANCE WITH ALL
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.