Product ID:FUNGINEX
MSDS Date:10/07/1993
FSC:6840
NIIN:00N064577
MSDS Number: BZQCX

CIBA-GEIGY CORP

GREENSBORO, NC 27419

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-888-8372

Cage: 0267X

CIBA-GEIGY CORP, AGRICULTURAL DIV.

18300 GREENSBORO, NC 27419 US

Telephone: 800-888-8372 OR 800-334-9481

Cage: 8K340

CYCLOHEXANONE (CERCLA)

CAS: 108-94-1

RTECS: GW1050000

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

EMULSIFIER BLEND; (EMULSIFIER)

OSHA PEL N/K

ACGIH TLV: N/K

TRIETHYLAMINE (CERCLA)

CAS: 121-44-8

RTECS: YE0175000

OSHA PEL 25 PPM

ACGIH TLV: 1 PPM/5 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PIPERAZINE, 1,4-BIS(1-FORMAMIDO-2,2,2-TRICHLOROETHYL)-;

CAS: 26644-46-2

RTECS: TK9200000

OSHA PEL N/K

ACGIH TLV: N/K

WASH W/PLENTY OF SOAP & WATER,

RTECS: 9999999ZZ

MEDICATING AGENTS EXCEPT ON MD ADVICE. REMOVE CONTAM

RTECS: 9999999ZZ

CONTAM AREA TO FRESH AIR. APPLY ARTF RESP IF NEC.

RTECS: 9999999ZZ

INGS OF THIS PROD ARE CORR/SEV IRRIT. CONSIDERATION

RTECS: 9999999ZZ

STOM EMPTYING. CHECK FOR POSS MUCOSAL DMG BEFORE

RTECS: 9999999ZZ

SUSPENSION (50G/400ML WATER) CAN BE GIVEN TO ABSORB

RTECS: 9999999ZZ

REC IN CASE OF EYE CONTAM. BASED ON ACUTE ORAL LD50

RTECS: 9999999ZZ

(PET LITTER). SWEEP UP MATL & PLACE IN APPROP

RTECS: 9999999ZZ

DETERGENT, ABSORB W/PET LITTER/OTHER ABSORB MATL,

RTECS: 9999999ZZ

IN APPRVD MANNER. FLUSH SPILL AREA W/WATER TO

RTECS: 9999999ZZ

GOGGLES AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): > 2000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN CAUSE IRREVERSIBLE EYE
INJURY & SUBSTANTIAL SKIN IRRIT. IF SWALLOWED, NAUS, VOMIT, BRTHG
DFCLT, & CONVLS CAN OCCUR. INHAL MAY IRRIT NOSE & THROAT. INHAL OF
HIGH CONCS OF ING 1 MAY CAUSE CNS EFTS SUCH AS LABORED BRTHG,
TREMORS & DECR HEART RATE. VERY HIGH EXPOS MAY CAUSE FATAL RESP
DEPRESS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INGEST/ABSORPTION OF ING 1 THRU SKIN
MAY CAUSE EFTS SIMILAR TO INHAL. PRLNG EXPOS TO LGE AMTS OF ING 1
HAS CAUSED LIVER & KIDNEY DMG, & BLOOD & BONE MARROW EFTS IN
EXPERIMENTAL ANIMALS. EXPO S TO ING 3 VAPS MAY CAUSE SEV EYE & RESP
TRACT IRRIT/BURNS, CHEM PNEUMIT & PULM EDEMA. CHANGES IN LUNGS,
LIVER,(SUP DAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:IF POIS SUSPECTED, IMMED CONT MD, NEAREST HOSPITAL/NEAREST
POIS CTL CTR. TELL PERS CONT COMPLETE PROD NAME, & TYPE & AMT OF
EXPOS. DESCRIBE ANY SYMP & FOLLOW ADVICE GIVEN. INGEST: DO NOT
INDUCE VOMIT. IMMED GIVE LGE QTYS OF WATER TO DRINK & GET MED
ATTN. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. APPLY ARTF RESP
IF NEC. EYE: IMMED RINSE W/LGE AMT OF RUNNING WATER FOR AT LEAST 15
MIN. (SUP DAT)

Flash Point:122F,50C
Extinguishing Media:USE DRY CHEMICAL, FOAM, OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. EVACUATE NON-ESSENTIAL PERS FROM AREA TO PREVENT HUMAN EXPOSURE
TO FIRE, SMOKE, FUMES/PRODS OF COMBUSTION.
Unusual Fire/Explosion Hazard:FUNGINEX IS AN NFPA CLASS IIIA
COMBUSTIBLE LIQUID AND A DOT COMBUSTIBLE LIQUID. PREVENT USE OF
CONTAMINATED BUILDINGS, AREA, AND EQUIPMENT UNTIL DECONTAMINATED.

Spill Release Procedures:WEAR CHEM GOG W/SIDE SHIELDS/FSHLD, RUB
GLOVES, RUB BOOTS, LONG-SLEEVED SHIRT, LONG PANTS, HAT & NIOSH/MSHA
APPRVD CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE & PESTICIDE
PREFILTER. FOR SML SPILLS, COVER SPILL W/ABSORB MATL SUCH AS
SWEEPING CMPD (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE MATL IN WELL-VENT, SECURE AREA,
OUT OF REACH OF CHILDREN & DOMESTIC ANIMALS. DO NOT STORE FOOD,
BEVERAGES/TOBACCO PRODS IN STORAGE AREA.
Other Precautions:PREVENT EATING, DRINKING, TOBACCO USAGE, AND COSMETIC
APPLICATION IN AREAS WHERE THERE IS A POTENTIAL FOR EXPOSURE TO THE
MATERIAL.

Respiratory Protection:TO AVOID BREATHING SPRAY OR MIST, WEAR
NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE AND PESTICIDE PREFILTER.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:NEOPRENE RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS (ING 15)
Other Protective Equipment:RUB BOOTS, LONG-SLEEVED SHIRT, LONG PANTS, &
HAT. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA
.
Work Hygienic Practices:ALWAYS WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH: 4.5-5.5 (10% SOLN). EFTS OF OVEREXP: KIDNEY, & HEART HAVE BEEN
OBSERVED IN TEST ANIMALS EXPOS TO HIGH AMTS OF ING 3. PROD CONTAINS
EMULSIFIER REPORTED BY ITS MFR TO BE EYE, SKIN, & RESP IRRIT. FIR
ST AID PROC: HOLD EYELIDS APART TO RINSE ENTIRE SURF OF EYE & LIDS.
DO NOT APPLY ANY MEDICATING AGENTS EXCEPT (ING 5)

Spec Gravity:1.0756
pH:SUPDAT
Solubility in Water:MISCIBLE
Appearance and Odor:AMBER LIQUID, WITH AMMONIA-LIKE ODOR

Stability Indicator/Materials to Avoid:YES
ACIDS, ALKALIES, AND OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT AND FIRE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROGEN CHLORIDE, DIMETHYLAMINE, AND OXIDES OF NITROGEN.

Waste Disposal Methods:DO NOT REUSE PRODUCT CONTAINERS. DISPOSE OF
PRODUCT CONTAINERS, WASTE CONTAINERS, AND RESIDUES ACCORDING TO
LOCAL, STATE, AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.