BZQTY - TCLP VOA MIX, 30024
- MSDS: BZQTY
- Manufacturer: RESTEK CORP
- Product Name: TCLP VOA MIX, 30024
- National Stock Number: 6850-00N069900
Product Identification
Product ID:TCLP VOA MIX, 30024
MSDS Date:08/13/1995
FSC:6850
NIIN:00N069900
MSDS Number: BZQTY
Responsible Party
BELLEFONTE, PA 16823-8812
US
Emergency Phone: 814-353-1300
Info Phone: 814-353-1300
Cage: 0JL17
Contractor
Telephone: 814-353-1300
Cage: 0JL17
Ingredients
METHANOL (SARA 313) (CERCLA)
CAS: 67-56-1
RTECS: PC1400000
Fraction By Weight: 97.8%
OSHA PEL 200 PPM, S
ACGIH TLV: 200PPM/250STEL, S
EPA Report Quantity: 5000 LBS
DOT Report Quantity: 5000 LBS
BENZENE (SARA 313) (CERCLA)
CAS: 71-43-2
RTECS: CY1400000
Fraction By Weight: 0.2%
OSHA PEL 10 PPM (MFR)
ACGIH TLV: 10 PPM; A2
EPA Report Quantity: 10 LBS
DOT Report Quantity: 10 LBS
ETHANE, 1,2-DICHLORO-; (1,2-DICHLOROETHANE) (SARA 313)
CAS: 107-06-2
RTECS: KI0525000
Fraction By Weight: 0.2%
OSHA PEL 50 PPM
ACGIH TLV: 10 PPM
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
ETHYLENE, TRICHLORO-; (TRICHLOROETHYLENE) (SARA 313)
CAS: 79-01-6
RTECS: KX4550000
Fraction By Weight: 0.2%
OSHA PEL 100 PPM
ACGIH TLV: 50 PPM/100STEL, A5
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
BENZENE, CHLORO-; (CHLOROBENZENE) (SARA 313) (CERCLA)
CAS: 108-90-7
RTECS: CZ0175000
Fraction By Weight: 0.2%
OSHA PEL 75 PPM
ACGIH TLV: 10 PPM
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
ETHYLENE, 1,1-DICHLORO-; (1,1-DICHLOROETHYLENE) (CERCLA)
CAS: 75-35-4
RTECS: KV9275000
Fraction By Weight: 0.2%
OSHA PEL 1 PPM
ACGIH TLV: 5 PPM/20 STEL
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
CARBON TETRACHLORIDE (SARA 313) (CERCLA)
CAS: 56-23-5
RTECS: FG4900000
Fraction By Weight: 0.2%
OSHA PEL 10 PPM
ACGIH TLV: 5PPM/10 STEL, A3, S
EPA Report Quantity: 10 LBS
DOT Report Quantity: 10 LBS
2-BUTANONE (SARA 313) (CERCLA)
CAS: 78-93-3
RTECS: EL6475000
Fraction By Weight: 0.2%
OSHA PEL 200 PPM
ACGIH TLV: 200 PPM/300STEL
EPA Report Quantity: 5000 LBS
DOT Report Quantity: 5000 LBS
BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)
CAS: 106-46-7
RTECS: CZ4550000
Fraction By Weight: 0.2%
OSHA PEL 75 PPM
ACGIH TLV: 10 PPM, A3
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
CHLOROFORM (SARA 302/313) (CERCLA)
CAS: 67-66-3
RTECS: FS9100000
Fraction By Weight: 0.2%
OSHA PEL C 50 PPM
ACGIH TLV: 10 PPM; A2
EPA Report Quantity: 10 LBS
DOT Report Quantity: 10 LBS
ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE) (SARA 313)
CAS: 127-18-4
RTECS: KX3850000
Fraction By Weight: 0.2%
OSHA PEL 100 PPM
ACGIH TLV: 25PPM/100STEL, A3
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
ETHYLENE, CHLORO-; (VINYL CHLORIDE) (SARA 313) (CERCLA)
CAS: 75-01-4
RTECS: KU9625000
Fraction By Weight: 0.2%
OSHA PEL SEE 1910.1017
ACGIH TLV: 5 PPM, A1
EPA Report Quantity: 1 LB
DOT Report Quantity: 1 LB
CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF
RTECS: 9999999ZZ
SIMILAR EFT IN HUMANS. ADRENOMINETICS (E.G.,
RTECS: 9999999ZZ
SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY
RTECS: 9999999ZZ
OSHA REGULATED CFR 29 1910.1028. CARBON
RTECS: 9999999ZZ
GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994
RTECS: 9999999ZZ
GROUP 1. NTP
RTECS: 9999999ZZ
IARC MONO, SUPP, VOL 7, PG
RTECS: 9999999ZZ
KIDNEY. CHLOROFORM
RTECS: 9999999ZZ
ANTICIPATED TO BE
RTECS: 9999999ZZ
GROUP 2B.
RTECS: 9999999ZZ
IARC MONO,
RTECS: 9999999ZZ
ANTIC TO BE CARCIN. ANIMAL
RTECS: 9999999ZZ
ASSISTANCE. CONTACT MD IMMED. NEVER GIVE
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INHAL: EXPOS CAN CAUSE DROW &
INTOXICATION, HDCH, VISUAL DISTURB LEADING TO BLINDNESS, COUGHING &
SHORTNESS OF BREATH, COLLAPSE & DEATH AT HIGH CONCS. EYES: LIQ CAN
CAUSE MOD BURNING, WATERING, SWELL & REDNESS. SKIN: EXTENSIVE,
RPTD&/PRLNG SKIN CONT CAN CAUSE BURNING, ITCH, REDNESS/BLISTERS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120,
1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE
CARCIN.(ING 16)
Effects of Overexposure:HLTH HAZ: INGEST: CAUSES BURNING OF GI TRACT &
TOX EFTS. SWALLOWING > 2 OZ OF METHANOL CAN CAUSE DEATH. MILD
POISONING IS CHARACT BY FATG, NAUS, HDCH & DELEAYED VISUAL
BLURRING. MOD INTOX RSLT IN SEV DEPRESS. TEMPORARY/PERM BLINDNESS
MAY FOLLOW 2-6 DAYS. IN SEV POISONING, SYMPS PROGRESS TO RAPID,
SHALLOW RESP,(SUP DAT)
Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES,
LIVER, KIDNEYS, LUNGS, AND CARDIOVASCULAR SYSTEM.
First Aid
First Aid:EYES: REMOVE CONT LENSES IF PRESENT. HOLD EYELIDS OPEN &
IRRIGATE W/LGE VOL OF WATER FOR AT LEAST 15 MIN. SEEK MED
TREATMENT. SKIN: IMMED WASH W/SOAP & WATER. CONTINUE RINSING W/LGE
VOL OF WATER FOR 1 5 MIN. REMOVE CONTAM CLTHG. SEEK MED TREATMENT.
INHAL: REMOVE TO FRESH AIR. HAVE TRAINED PERS ADMIN OXYGEN & CPR IF
NEEDED. CONT MD IMMED. INGEST: MAY CAUSE BLINDNESS. CONT POIS CTL
CTR FOR (ING 25)
Fire Fighting
Flash Point Method:CC
Flash Point:53.6F,12.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM,
WATER MIST OR FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . HEAT MAY BUILD PRESS & RUPTURE CLSD STOR CONTRS.
KEEP FIRE-EXPOSED CONTRS COOL W/ (SUP DAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .
Accidental Release
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. PROTECT
FROM IGNITION. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER
ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:AVOID ALL INHALATION & CONTACT. KEEP
IN TIGHTLY CLOSED CONTAINER AT ALL TIMES. PROTECT FROM TEMP EXTREME
& DIRECT SUNLIGHT. HANDLE W/UTMOST CARE.
Other Precautions:STORE IN AN EXPLOSION-PROOF FREEZER AT -18C. NO
SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES, OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY
CAUSE THE FORMATIO N OF HCL AND/OR PHOSGENE .
Exposure Controls
Respiratory Protection:FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR. USE NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE, NITRILE, OR RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:PROTECTIVE CLOTHING MEETING LAB SAFETY REQS.
EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:WATER SPRAY. MAY BURN W/INVISIBLE FLAME. MIX W/WATER AS
LOW AS 21% BY VOL ARE STILL FLAMM. UNDER SOME CIRCUMSTANCES CAN
CORRODE METALS, INCL ALUMINUM & ZINC, & GENERATE HYDROGEN GAS. E
FTS OF OVEREXP:CYANOSIS, COMA, HYPERTENSION, DILATED PUPILS &
VISUAL DISTURB. DEATH MAY RSLT FROM RESP FAILURE. (ING 13)
Chemical Properties
Boiling Pt:B.P. Text:149F,65C
Vapor Pres:97
Spec Gravity:0.791
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS, WITH ALCOHOL ODOR
Stability
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND REACTIVE METALS WHICH WILL DISPLACE
HYDROGEN.
Stability Condition to Avoid:HEAT, SPARKS, AND CONTACT WITH IGNITION
SOURCES.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION CAN GENERATE
CARBON MONOXIDE AND OTHER TOXIC VAPORS SUCH AS FORMALDEHYDE. HCL,
PHOSGENE .
Disposal
Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE
WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.