Product ID:17-5 METHANOL ABSOLUTE
MSDS Date:03/22/1996
FSC:6550
NIIN:00F048832
Kit Part:Y
MSDS Number: BZTYL

SIGMA CHEMICAL COMPANY

3050 SPRUCE ST
SAINT LOUIS, MO 63178-5000
US

Emergency Phone: 314-771-5765/800-325-3010

Info Phone: 314-771-5765/800-325-3010

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *96-2*

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TOXIC BY INHALATION, ABSORPTION &
INGESTION. EYES/SKIN: IRRITATION. MATERIAL MAY BE IRRITATING TO
MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, GI DISTURBANCES, CONVULSIONS.

First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO
FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH
W/WATER PROVIDED PERSON IS CONSCIOUS. OBTAIN MEDICAL ATTENTION IN
ALL CASES.

Flash Point:52F
Lower Limits:6
Upper Limits:36
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS MAY TRAVEL
DISTANCE TO IGNITION SOURCES & FLASH BACK.

Spill Release Procedures:EVACUATE AREA. SHUT OFF IGNITION SOURCES. WEAR
SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/DRY-LIME,
SAND/SODA ASH. PLACE IN COVERED CONTAINERS USING NON-SPARKING TOOLS
& TRANSPORT OUTDOORS. VEN TILATE AREA & WASH SITE AFTER PICKUP
ISCOMPLETE.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. KEEP FROM HEAT,
SPARKS & OPEN FLAME. STORE IN A COOL DRY PLACE.
Other Precautions:DON'T BREATHE VAPOR. AVOID CONTACT W/EYES, SKIN &
CLOTHING. DON'T USE IF SKIN IS CUT/SCRATCHED. TOXIC.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST VENTILATION.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health

Boiling Pt:B.P. Text:148.4F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:97.68
Vapor Density:1.1
Spec Gravity:0.791
Appearance and Odor:LIQUID

Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS, REDUCING
AGENTS, ALKALI METALS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, MOISTURE.
Hazardous Decomposition Products:COMBUSTION: CO, CO2

Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED
W/AFTERBURNER & SCRUBBER, USE CARE MATERIAL IS HIGHLY FLAMMABLE.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.