Product ID:FORE FUNGICIDE, 62440
MSDS Date:07/24/1991
FSC:6840
NIIN:00N010725
MSDS Number: BZZSC

ROHM AND HAAS CO

100 INDEPENDENCE MALL WEST
PHILADELPHIA, PA 19105
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 215-592-3000

Cage: 77902

ROHM AND HAAS CO

PHILADELPHIA, PA 19106-2399 US

Telephone: 215-592-2521/215-592-3000

Cage: 77902

PROD CONTAINS COMPONENT/COMPONENTS KNOW TO STATE OF

RTECS: 9999999ZZ

EXPOS. THORO LAUNDER CLTHG BEFORE REUSE. DO NOT

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MATL TO SUITABLE CONTRS FOR RECOVERY/DISP. KEEP

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OUT OF MUNICIPAL SEWERS AND OPEN BODIES OF WATER.

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DENSE PACKING OF UNVENTED STACKS OF BAGS MAY

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FOUL ODOR. CHECK FOR HOT CONTRS & IMMED REMOVE TO

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FEED/DRINKING WATER. TRIPLE RINSE (OR EQUIVALENT) &

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FOR AIRBORNE CONCS UP TO 100 TIMES TWA/TLV WEAR

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PURIFYING RESP. AIR-PURIFYING RESP SHOULD BE

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A MANUAL OF

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OF GOVERNMENTAL INDUSTRIAL HYGIENISTS FOR INFO ON

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AT THE END OF THE SHIFT AND LAUNDERED BY THE

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ANTICIPATED TO BE

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VONDOZEB; (MANCOZEB)

CAS: 8018-01-7

RTECS: ZB3200000

Fraction By Weight: 68-70%

OSHA PEL N/K

ACGIH TLV: N/K

CALCIUM LIGNOSULFONATE; (CALCIUM LIGNOSULFONATE)

CAS: 8061-52-7

Fraction By Weight: 3-4%

OSHA PEL N/K

ACGIH TLV: N/K

1) (SARA 313) (CERCLA)

CAS: 7733-02-0

RTECS: ZH5260000

Fraction By Weight: 5-6%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

COPPER, (PHTHALOCYANINATO(2-))-; (C.I. PIGMENT BLUE 15)

CAS: 147-14-8

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

RELATED REACTION PRODUCTS

Fraction By Weight: 14-16%

OSHA PEL N/K

ACGIH TLV: N/K

2-IMIDAZOLIDINETHIONE; (ETHYLENE THIOUREA) (SARA 313)

CAS: 96-45-7

RTECS: NI9625000

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HIGH DOSE LEVEL OF 5000 PPM, WHICH ALSO CAUSED

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FEEDING STUDY IN RATS INDICATED INCR INCIDENCE OF

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A 2-YR FEEDING STUDY INDICATED THYROID TUMORS IN

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POS W/OUT METABOLIC

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LEVELS OF COMPONENT/COMPONENTS KNOWN TO STATE OF

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LD50 LC50 Mixture:LD50 (ORAL RAT): > 5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: DUST CAN CAUSE IRRIT OF
NOSE & THROAT. EYE: DIRECT CONT W/MATL CAN CAUSE MOD IRRIT. SKIN:
PRLNG/RPTD CONT CAN CAUSE POSS IRRIT, DERM. CHRONIC: AT HIGH LEVELS
PROD HAS CAUSED BIRTH DEFECT S IN TEST ANIMALS (3000 TIMES TWA),
HIND LEG PARALYSIS & INCR INCIDENCE IN OLD AGE-RELATED RETINAL
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:2-IMIDAZOLIDINETHIONE: IARC MONOGRAPHS,
SUPPLEMENT, VOL 7, PG 207, 1987: GROUP 2B. NTP 7TH ANNUAL REPORT ON
(ING 24)
Effects of Overexposure:HLTH HAZ: ATROPHY. IT HAS CAUSED THYROID TUMORS
IN TEST ANIMALS, RSLT FROM ETHYLENETHIOUREA (ETU) FORM. ETU, A
TRACE CONTAM & BREAKDOWN PROD OF FORE FUNGICIDE, HAS CAUSED THYROID
EFTS, TUMORS & BIRTH DEFECTS IN TEST ANIMALS. SENSIT DATA:
AMANCOZEB PROD HAS BEEN REPORTED POS IN MAXIMIZATION METH IN GUINEA
(SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: MOVE TO FRESH AIR. EYE: FLUSH WITH A LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT MD IF IRRITATION
PERSISTS. SKIN: WASH AFFECTED SKIN AREAS THOROUGHLY WITH SOAP AND
WATER. CONSU LT MD IF IRRITATION PERSISTS. INGESTION: IF SWALLOWED,
GIVE 2 GLASSES OF WATER TO DRINK. CONSULT MD. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point Method:TOC
Flash Point:295F,146C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. CONTAIN RUN-OFF. REMAIN UPWIND. AVOID BRTHG SMOKE. USE WATER
SPRAY TO COOL SURFACES & PREVENT REIGNITION.
Unusual Fire/Explosion Hazard:PESTICIDE PARTICULATES CAN BECOME
AIRBORNE. COMBUST GENERATES TOX FUMES OF HYDROGEN SULFIDE, CARBON
DISULFIDE, SULFUR OXIDES, NITROGEN OXIDES, CARBON (SUP DAT)

Spill Release Procedures:APPROP PROT EQUIP MUST BE WORN WHEN HDNLG
SPILL OF THIS MATL. IF EXPOSED TO MATL DURING CLEAN-UP OPERATIONS,
SEE FIRST AID PROC FOR ACTIONS TO FOLLOW. REMOVE ALL CONTAM CLTHG
PROMPTLY. WASH ALL EXPOSE D SKIN AREAS W/SOAP & WATER IMMED
AFTER(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE NEAR FOOD, FEED/DRINKING
WATER. STORE IN WELL-VENT AREA. STORE IN DRY AREA. DO NOT ALLOW
PROD TO BECOME WET/OVERHEATED IN STORAGE.
Other Precautions:DECOMP, IMPAIRED ACTIVITY/FIRE MAY RSLT. MATL IS
COMBUST. DO NOT IGNITE. STORE BAGGED MATL ONLY ON PALLETS NO MORE
THAN 3 HIGH. PROVIDE ACCESS AISLES FOR EACH 2 ROWS. LOOSE BAGS
SHOULD NOT BE STACKED MORE THAN 2X2X2 METERS. (ING 16)

Respiratory Protection:RESP PROT PROGRAM MEETING OSHA 1910.134 & ANSI
Z88.2 REQ MUST BE FOLLOWED WHENEVER WORKPLACE CNDTNS WARRANT RESP
USE. FOR AIRBORNE CONCS UP TO 10 TIMES TWA/TLV WEAR NIOSH/MSHA
APPRVD (OR EQUIVALENT) H ALF-MASK, AIR PURIFYING RESP. (ING 19)
Ventilation:USE LOC EXHAUST VENT W/MIN CAPTURE VELOCITY OF 100 FT/MIN
(30 M/MIN) AT POINT OF VAP EVOLUTION. REFER TO CURRENT(ING 21)
Protective Gloves:CHEMICALLY RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:CHEM-RESIST APRON/OTHER IMPERVIOUS CLTHG TO
AVOID PRLNG/RPTD SKIN CONT. ANSI APPRVD EMER EYEWASH & DELUGE
SHOWER .
Work Hygienic Practices:RINSE AND REMOVE GLOVES IMMEDIATELY AFTER USE.
WASH HANDS WITH SOAP AND WATER. WORK CLOTHING SHOULD BE REMOVED
(ING 23)
Supplemental Safety and Health
SPEC GRAV: 0.35-0.50 (H*2O=1). EXPLO HAZ: OXIDES. DUSTS AT SUFFICIENT
CONCS CAN FORM EXPLO MIX W/AIR. EFTS OF OVEREXP: PIGS. THESE RSLT
INDICATE THAT FORE FUNGICIDE MAY HAVE A WEAK POTENTIAL FOR SKIN
SENSIT IN HUMANS. TOX DATA: A 3-MONTH FEEDING STUDY IN RATS
INDICATED HIND LEG PARALYSIS AFTER 2-WEEK EXPOS, AT (ING 7)

Melt/Freeze Pt:M.P/F.P Text:>378F,>192C
Spec Gravity:SUP DAT
Solubility in Water:DISPERSIBLE
Appearance and Odor:BLUE TO GREEN POWDERED SOLID, WITH MUSTY ODOR
Percent Volatiles by Volume:1

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH OXIDIZING AGENTS AND ACIDS.
Stability Condition to Avoid:KEEP AWAY FROM MOISTURE, HEAT OR FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON
DISULFIDE AND HYDROGEN SULFIDE.

Waste Disposal Methods:FOR DISPOSAL, INCINERATE THIS MATERIAL AT A
FACILITY THAT COMPLIES W/LOCAL, STATE, & FEDERAL REGULATIONS.
DISPOSE EMPTY CONTAINER IN SANITARY LANDFILL/BY INCINERATION AS
ALLOWED BY STATE & LOCAL AUTHO RITIES. AVOID INHALATION OF SMOKE IF
INCINERATED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.