Product ID:PURGEABLE B, 48852
MSDS Date:12/14/1992
FSC:6850
NIIN:00N019167
MSDS Number: CBBDF

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ETHANE, 1,2-DICHLORO-; (SARA 313) (CERCLA); LD50 (ORAL,

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.02%

OSHA PEL 50 PPM; Z-2

ACGIH TLV: 10 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,1,1-TRICHLORO-; (SARA 313) (CERCLA) (ING 3) LD50

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.02%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2,2-TETRACHLORO-; (2 PPM) (SARA 313) (CERCLA)

CAS: 79-34-5

RTECS: KI8575000

Fraction By Weight: 0.02%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 1 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,2-DICHLORO-; (ETHENE, 1,2-DICHLORO(E)-) (SARA

CAS: 156-60-5

RTECS: KV9400000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPENE, 1,3-DICHLORO-; (1,3-DICHLOROPROPENE, MIXTURE OF

CAS: 542-75-6

RTECS: UC8310000

Fraction By Weight: 0.04%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

3500 MG/KG.

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, TRIBROMO-; (SARA 313) (CERCLA). LD50 (ORAL, RAT)

CAS: 75-25-2

RTECS: PB5600000

Fraction By Weight: 0.02%

OSHA PEL S, 0.5 PPM

ACGIH TLV: S, 0.5 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANE, BROMODICHLORO-; (SARA 313) (CERCLA) LD50 (ORAL,

CAS: 75-27-4

RTECS: PA5310000

Fraction By Weight: 0.02%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA). LD50 (ORAL,

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.78%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 95

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

4894 MG/KG

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.02%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE; (BENZENE, METHYL-) (SARA 313) (CERCLA). LD50

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0.02%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS LOW CONCENTRATION(S) OF MATERIAL(S) KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER. SUCH CONCENTRATION(S)
IS/ARE SUBSTANTIALLY BELOW OSHA-HCS THRESHOLDS WHICH WOULD REQUIRE
LISTING HEREIN AS A COMPONENT OF THIS MIXT. HEADACHE, NAUSEA, GI
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DISTURBANCES, BLINDNESS. TOLUENE
APPEARS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD L IST INFORMATION AND SAFE HANDLING AND
EXPOSURE INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/H*2O FOR AT LEAST 15 MIN, CONTACT A MD. SKIN:
FLUSH W/LARGE VOLUMES OF H*2O. INHAL: MOVE TO FRESH AIR. IF
BREATHING STOPS, GIVE ARTF RESP. CONTACT A MD. INGEST: NEVER GIVE
ANYTHING BY MO UTH TO AN UNCONSCIOUS PERSON. NEVER TRYTO MAKE AN
UNCONSCIOUS PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN A
GLASS OF H*2O. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMIT.
IMMED CONTACT A MD.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATED
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINERS. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR A NIOSH APPROVED FACE MASK WITH ORGANIC
CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:NOT APPLICABLE.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.