Product ID:SEMIVOLATILE BASE-NEUTRALS MATRIX SPIKE MIX A, 48100
MSDS Date:01/14/1994
FSC:6630
NIIN:00N066608
MSDS Number: CBDSS

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ACENAPHTHENE; (ACENAPHTHYLENE, 1,2-DIHYDRO-ACENAPHTHENE

CAS: 83-32-9

RTECS: AB1000000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, 1,2,4-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA

CAS: 120-82-1

RTECS: DC2100000

Fraction By Weight: 0.1%

OSHA PEL C, 5 PPM

ACGIH TLV: C, 5 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.1%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

500 MG/KG

RTECS: 9999999ZZ

TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313)

CAS: 121-14-2

RTECS: XT1575000

Fraction By Weight: 0.1%

OSHA PEL S, 1.5 MG/M3

ACGIH TLV: 0.15 MG/M3, A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DIPROPYLAMINE, N-NITROSO-; (1-PROPANAMINE,

CAS: 621-64-7

RTECS: JL9700000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

480 MG/KG

RTECS: 9999999ZZ

2700 MG/KG

CAS: 129-00-0

RTECS: UR2450000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANOL (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES,
BLINDNESS.
Explanation of Carcinogenicity:BENZENE, P-DICHLORO:IARC MONOGRAPHS,
SUPP, VOL 7, PG 192. 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS,
1994:(SUPP DATA)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. CONT MD. SKIN:FLUSH W/LG
VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS, GIVE
ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PER SON. NEVER TRY TO MAKE AN UNCON PERSON VOMIT. GIVE 2 TBSP OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
INDUCE VOMIT. IMMED CONT MD.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION. HYDROGEN CHLORIDE,
OXIDES OF NITROGEN.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ANTICIPATED TO BE CARCINOGEN. ANIMAL:KIDNEY, BLADDER,
URETER, LIVER. DIPROPYLAMINE, N-NITROSO-:IARC MONOGRAPHS,
SUPPLEMENT. VOL 7, PG 56, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON
CARCI NOGENS, 1994:ANTICIPATED TO BE CARCINOGEN. ANIMAL:LUNG.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:1

Stability Indicator/Materials to Avoid:YES
OXDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC ACIDS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, OXIDES OF NITROGEN.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.