Product ID:VALCOOL VAL-U-CLEAN AL
MSDS Date:09/01/1993
FSC:6850
NIIN:00N068439
MSDS Number: CBHTH

VALENITE INC

TROY, MI 48007
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 313-589-1000

Cage: IO973

VALENITE INC

3950 TROY, MI 48007-3950 US

Telephone: 313-589-1000

Cage: IO973

ETHANOL, 2-AMINO-; (ETHANOLAMINE) (MFR CAS # 114-43-5)

CAS: 141-43-5

RTECS: KJ5775000

Fraction By Weight: 20%

OSHA PEL N/K

ACGIH TLV: N/K

NONANOIC ACID; (PELARGONIC ACID)

CAS: 112-05-0

RTECS: RA6650000

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

NEODECANOIC ACID

CAS: 26896-20-8

Fraction By Weight: 10% MAX

OSHA PEL N/K

ACGIH TLV: N/K

SILICIC ACID, (H2SIO3), DISODIUM SALT; (SODIUM

CAS: 6834-92-0

RTECS: VV9275000

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

ACETIC ACID, (ETHYLENEDINITRILO) TETRA-, TETRASODIUM SALT;

CAS: 64-02-8

RTECS: AH5075000

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

ISONANANOIC ACID

CAS: 3302-10-1

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

MAY RSLT FROM CONT W/CONC PROD. SKIN IRRIT CAN RSLT

RTECS: 9999999ZZ

MILK. IMMED CONT MD & OBTAIN TREATMENT.

RTECS: 9999999ZZ

CAUSE INJURY/ILLNESS; BUT AS SHOULD BE EXPECTED WHEN

RTECS: 9999999ZZ

NOT EXPECTED TO BE

RTECS: 9999999ZZ

CAN OCCUR IN APPLICATNS WHERE HIGH MIST LEVELS ARE

RTECS: 9999999ZZ

AIRBORNE PARTICULATE AS NUISANCE LEVEL OF EXPOS.

RTECS: 9999999ZZ

AS DEFINED UNDER 40 CFR 261. VALCOOL

RTECS: 9999999ZZ

HAULERS FOR YOUR AREA. "EMPTY" CNTNRS WILL CNTN

RTECS: 9999999ZZ

REGS. DRUMS CAN BE DRAINED TO "DRIP-DRY" CONDITION

RTECS: 9999999ZZ

CLOSE TOGETHER/VENT IS INADEQ, OPERATORS MAY EXPER

RTECS: 9999999ZZ

OR MIST COLLECTORS IS RECOMMENDED.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PROD CONC:INHAL:N/A. EYE:PRIMARY
IRRIT. SKIN:PRIMARY IRRIT. INGEST:NOT ORALLY TOX. USE
DILUTION:INHAL:EXTENDED EXPOS TO MISTS MAY CAUSE RESP IRRIT.
EYES:WILL CAUSE STINGING SENSATION. SKIN:NOT IRRIT W HEN USED AS
DIRECTED & GOOD PERSONAL HYGIENE IS PRACTICED. INGEST:SM QTYS MAY
CAUSE NAUS/DIARR. WHEN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:USED IN APPLICATNS GENERATING HIGH
LEVELS OF MIST, OPERATOR EXPOS CAN BE MIN BY PROPER VENT, USE OF
MIST COLLECTORS/SPLASH GUARDS, AS APPROP. IF THERE IS DOUBT ABOUT
ACTUAL MIST LEVELS PRESE NT, MONITORING SHOULD BE CONDUCTED. MILD
SKIN IRRIT (REDNESS & DRYNESS OF HANDS) MAY BE EXPER WHEN DILUTED
PROD (SUPDAT)
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN
IRRITATION WHERE FURTHER DEFATTING OR SKIN PENETRATION COULD OCCUR.

First Aid:EYE:IN CASE OF CONT W/CONC PROD/DILUTED MIX, FLUSH IMMED
W/RUNNING WATER FOR @ LST 15 MIN, THEN PROMPTLY GET MED ATTN TO
CHECK FOR POSS IRRIT. SKIN:IN CASE OF CONT W/PROD CONC, WASH
W/WATER AS SOON AS POSS. REMOVE SEVERELY CONTAM CLTHG, INCLUDING
SHOES. LAUNDER BEFORE REUSE. IF IRRIT PERSISTS, GET MED ATTN.
INGEST:IF CONC/MIX IS SWALLOWED, DO NOT INDUCE VOMIT. DILUTE BY
DRINKING WATER OR (ING 8)

Flash Point Method:COC
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE. HAZARDOUS COMBUSTION
PRODUCTS:SMOKE, FUMES AND OXIDES OF CARBON.

Spill Release Procedures:CONTAIN THE SPILL. COLLECT ON ABSORBENT
MATERIAL AND DISCARD AS DICTATED BY FEDERAL, STATE AND LOCAL
REGULATIONS THAT MAY APPLY. FLUSH AREA THOROUGHLY WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE ONLY AS REC BY MFR. AVOID ALL CONT
OF CONC W/EYES/SKIN. DO NOT SWALLOW. IF FROZEN, PROD SEPARATES.
THAW COMPLETELY AT ROOM TEMP & STIR THORO.
Other Precautions:CONTAINS AMINES. DO NOT ADD SODIUM NITRITE OR OTHER
NITROSATING AGENTS TO THIS PRODUCT. SUSPECTED CANCER-CAUSING
NITROSAMINES COULD BE FORMED. HIGHWAY SPILLS IN RAINY WEATHER COULD
RESULT IN SLIPPERY ROAD CONDITIONS.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . PROD IS NOT VOLATILE.
Ventilation:FOR MOST APPLICATNS, NORMAL SHOP VENT IS ADEQ. HOWEVER,
WHEN HIGH MIST LEVELS ARE GENERATED/WHERE MACHINES ARE (ING 16)
Protective Gloves:IMPERVIOUS GLOVES ARE REQ WHEN HNDLG.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . EFFECTIVE METALWORKING PLANT PROT CLTHG AS APPROP.
Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD ALWAYS BE
FOLLOWED.
Supplemental Safety and Health
PH (CONC):11.3-11.7; (5% MIX):10-10.8. EFTS OF OVEREXP:HAS BEEN CONTAM
BY CERTAIN OILS, BY DISSOLVED METALS/WHEN MIX RATIO IS TOO STRONG.
WHEN PROBLEMS OCCUR, USE OF WATER-RESISTANT BARRIER CREAMS MAY BE
TEMPORARY CTL MEASURE. CONT VALCOOLTECHNICAL SERVICES
(313-589-6011) FOR SPECIFIC RECS. SYMPS:EYE INJURY (ING 7)

Boiling Pt:B.P. Text:212F,100C
Vapor Pres:LIKE WATER
Spec Gravity:1.030-1.040
pH:SUPDAT
Evaporation Rate & Reference:LIKE WATER
Solubility in Water:100% MISCIBLE
Appearance and Odor:CLEAR/SWEET.

Stability Indicator/Materials to Avoid:YES
AVOID ADDITION OF STRONG ACIDS TO PRODUCT CONCENTRATE.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:SMOKE, FUMES, OXIDES OF CARBON.

Waste Disposal Methods:USED MIX:DISP PROC MUST COMPLY W/LOC, COUNTY,
STATE & FED REGS. IF PRE-TREATMENT IS NEEDED, CHEM EMULSION
BREAKING/ULTRAFILTRATION MAY BE USED. CONT VALCOOL TECHNICAL
SERVICES (313-689-6011) FOR ASSIS TANCE. UNUSED CONC:CONC IS NOT
HAZ WASTE, (ING 13)

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particular situation.