Product ID:ETHYLAMINE, 02940
MSDS Date:10/01/1994
FSC:6810
NIIN:00N069821
MSDS Number: CBKWT

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 516-467-3535

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

ETHYLAMINE (CERCLA)

CAS: 75-04-7

RTECS: KH2100000

OSHA PEL 10 PPM

ACGIH TLV: S,5 PPM/15 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

CORROSIVE & TOXIC LIQUID & GAS UNDER PRESS. KEEP

RTECS: 9999999ZZ

ACCIDENT OR IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED

RTECS: 9999999ZZ

FULL LENGTH FACESHIELD (8-INCH MINIMUM) .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 400 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN.
INHALATION MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION & EDEMA
OF LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA.
SYMPTOMS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH,
HEADACHE, NAUSEA AND VOMITING. EXPOSURE CAN CAUSE:DAMAGE TO EYES &
LUNGS. TARGET ORGAN(S):LIVER AND KIDNEYS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES/SKIN:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LEAST 15
MINS WHILE REMOVING CONTAMD CLTHG & SHOES. ASSURE ADEQ FLUSHING OF
EYES BY SEPARATING EYELIDS WITH FINGERS. INHAL:REMOVE TO FRESH AIR.
IF N OT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYSICIAN. DISCARD CONTAMINATED CLOTHING AND SHOES.

Flash Point:2F,-17C
Lower Limits:3.5%
Upper Limits:14%
Extinguishing Media:DO NOT EXTING BURNING GAS IF FLOW CANNOT BE SHUT
OFF IMMED. USE WATER SPRAY/FOG NOZZ TO KEEP CYL COOL. MOVE CYL
(SUPDAT)
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DANGER:EXTREMELY FLAMM. VAP MAY TRAVEL
CONSIDERABLE DIST TO SOURCE OF IGNIT & FLASH BACK. FORMS EXPLO MIX
IN AIR. CNTNR EXPLO MAY OCCUR UNDER FIRE (SUPDAT)

Spill Release Procedures:EVAC AREA & KEEP PERS UPWIND. SHUT OFF ALL
SOURCES OF IGNIT. WEAR FULL PROT EQUIP SUCH AS, A BUTYL RUBB
CHEM-PROOF AIR SUIT, W/BRTHG AIR SUPPLIED. SHUT OFF LEAK IF THERE
IS NO RISK. USE NONSPK TOOLS. VENTILATE AREA & WASH SPILL SITE
AFTER (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY CLSD. KEEP AWAY FROM
HEAT, SPKS, & OPEN FLAME. PROTECT FROM MOISTURE. CYL TEMP SHOULD
NOT EXCEED 125F(52C). STORE & USE W/ADEQ VENT.
Other Precautions:CONTENTS UNDER PRESS. COOL TO 0C BEFORE OPENING. DO
NOT BREATHE GAS. DO NOT GET IN EYES, ON SKIN, ON CLTHG. AVOID
PRLNGD/RPTD EXPOS. CORR. TOX. LACHRYMATOR. READILY ABSORBED THRU
SKIN. FLAMM. CAUSES B URNS. TARGET ORGAN(S):LIVER, (SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG & (ING 4)
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXTING MEDIA:AWAY FROM FIRE IF THERE IS NO RISK. WATER MAY BE INEFTIVE
FOR COOLING, BUT MAY NOT EFT EXTINGUISHMENT. EXPLO HAZ:CONDITIONS.
MATLS TO AVOID:W/CELLULOSE NITRATE. INCOMPAT W/SILVER, MERCURY &
BRASS. PROTECT FROM MOISTURE. SPILL RELEASE:MATL PICKUP IS
COMPLETE. OTHER PRECS:KIDNEYS. DANGER:FLAMM, (ING 2)

Boiling Pt:B.P. Text:61.9F,16.6C
Melt/Freeze Pt:M.P/F.P Text:-114F,-81C
Vapor Pres:874 @ 20C
Vapor Density:1.56 @ 15C
Spec Gravity:0.689
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, TIN, NICKEL, COPPER, COPPER
ALLOYS, ZINC & ITS ALLOYS, ALUMINUM, INCOMPAT(SUDPAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.

Waste Disposal Methods:CAUTION:NO-RETURN CYLINDER. DO NOT REUSE. EMPTY
CYL WILL CNTN HAZ RESIDUE. FOLLOW PROPER DISPOSAL TECHNIQUES.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.