Product ID:DEFEND-327
MSDS Date:09/29/1995
FSC:6850
NIIN:00N071398
MSDS Number: CBNSP

CALGON CORP

PITTSBURGH, PA 15230-1346
US

Emergency Phone: 412-494-8000

Info Phone: 412-494-8000

Preparer: P J MALONEY

Cage: 86035

CALGON CORP

1346 PITTSBURGH, PA 15230-1346 US

Telephone: 412-494-8000

Cage: 86035

1050

CAS: 110-91-8

RTECS: QD6475000

Fraction By Weight: <25%

OSHA PEL 20 PPM, S

ACGIH TLV: 20 PPM, S

ETHANOL, 2-(DIETHYLAMINO)-; (2-DIETHYLAMINOETHANOL (DEAE))

CAS: 100-37-8

RTECS: KK5075000

Fraction By Weight: <20%

OSHA PEL 10 PPM, S

ACGIH TLV: 2 PPM, S

OF MOUTH, THROAT, ESOPHAGUS & STOM. DEAE PRDCES

RTECS: 9999999ZZ

& BRONCH IRRIT W/COUGHING & SORE THROAT. SEV OVEREXP

RTECS: 9999999ZZ

RPTD INHAL OF MORPHOLINE CAN RSLT IN LUNG INJURY. IN

RTECS: 9999999ZZ

LIVER NECROSIS & RENAL TUBULAR DEGENERATION AT CONCS

RTECS: 9999999ZZ

RESP & MUC MEMB IRRIT, COUGHING, WHEEZING,

RTECS: 9999999ZZ

EXPOS HAVE CAUSED BRONCHOPNEUMONIA IN RATS.

RTECS: 9999999ZZ

RATS & GPGS HAVE SHOWN EVIDENCE OF INTENSE IRRIT OF

RTECS: 9999999ZZ

INCRG LIVER & KIDNEY INJURY W/INCRG DOSES. SKIN,

RTECS: 9999999ZZ

APPLICATION OF MORPHOLINE TO RABBITS. RPTD EXPOS OF

RTECS: 9999999ZZ

LARGELY CENTERED ABOUT BRONCHI & BRONCHIOLES, &

RTECS: 9999999ZZ

CONGESTION. LONG-TERM FEEDING STUDIES IN RATS &

RTECS: 9999999ZZ

TESTICULAR ATROPHY IN SOME RATS AT ALL DOSES GIVEN.

RTECS: 9999999ZZ

AT 5000 PPM & 10,000 PPM. SOME CEREBELLAR

RTECS: 9999999ZZ

WERE EXPOSED TO DEAE VAPS 6 HRS/DAY, 5 DAYS/WK, FOR

RTECS: 9999999ZZ

STUDY RSLTD IN NO ADVERSE EFT CONC OF 10 PPM &

RTECS: 9999999ZZ

TO 500 PPM OF DEAE FOR 6 HRS/DAY EXHIBITED TREMORS

RTECS: 9999999ZZ

THIS INDICATES POSS CNS INVOLVEMENT. SIGNS OF EYE &

RTECS: 9999999ZZ

EXHIBITED CORNEAL OPACITIES. TWENTY PERCENT OF

RTECS: 9999999ZZ

SIGNIFICANT WT LOSSES & AT NECROPSY, SEV EFTS ON

RTECS: 9999999ZZ

SEEK MED AID IMMED. NEVER GIVE ANYTHING BY

RTECS: 9999999ZZ

NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: EXPECTED TO CAUSE SEV
IRRIT ON CONT & POSS PERM INJURY. AT LOW CONCS IN AIR, MORPHOLINE
VAPS HAVE CAUSED TRANSIENT CORNEAL EDEMA & TEMPORARY FOGGY VISION
W/HALOS AROUND LIGHTS IN WORKERS EXPOSED FOR MANY HRS. THESE SYMPS
APPEAR AFTER WORK & DISAPPEAR BY NEXT DAY. SKIN: DIRECT CONT WITH
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MORPHOLINE MAY CAUSE SKIN BURNS. VAPS
MAY ALSO BE IRRIT TO SKIN. MORPHOLINE IS TOX BY SKIN ABSORPTION BY
OSHA DEFINITION & SIGNS OF ACUTE TOX FROM SKIN ABSORPTION ARE
SIMILAR TO THOSE SEEN F ROM INGEST. SYMPS INCLUDE INACTIVITY,
TREMORS, TEARING & SALIVATION. CONT W/MORPHOLINE MAY CAUSE ALLERGIC
SKIN (SUP DAT)
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY,
LIVER, KIDNEY OR SKIN DISEASES MAY BE AT INCREASED RISK FROM
EXPOSURE TO MORPHOLINE.

First Aid:EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. SEEK
MED AID IMMED. SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MIN WHILE REMOVING CONTAM CLTHG & SHOES. SEEK MED AID IMMED. WASH
CLTHG BEFORE REUSE. VICTIMS W/MAJOR SKIN CONTSHOULD BE MAINTAINED
UNDER MED OBSERVATION FOR AT LEAST 24 HRS DUE TO POSS OF DELAYED
RXN. INGEST: DO NOT INDUCE VOMIT. GIVE LGE QTYS OF WATER. (ING 22)

Flash Point:163F,73C
Lower Limits:SEE ING 1
Upper Limits:SEE ING 1
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . EXERCISE CAUTION WHEN FIGHTING ANY CHEM
FIRE. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:PRODUCT EMITS TOXIC GASES UNDER FIRE
CONDITIONS. PRODUCT VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION & FLASH BACK.

Spill Release Procedures:VENTILATE AREA OF SPILL. REMOVE ALL SOURCES OF
IGNITION. WEARING APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT,
CONTAIN SPILL, COLLECT ONTO INERT ABSORBENT AND PLACE INTO SUITABLE
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN OR
CLOTHING. AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM HEAT AND FLAME.
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A
COOL, DRY, WELL-VENTILATED LOCATION. SEPARATE FROM OXIDIZING
MATERIALS AND ACIDS.

Respiratory Protection:IF AIRBORNE CONCENTRATIONS EXCEED PUBLISHED
EXPOSURE LIMITS, USE A NIOSH/MSHA APPROVED RESPIRATOR IN ACCORDANCE
WITH OSHA RESPIRATORY PROTECTION REQUIREMENTS (29 CFR 1910.134).
Ventilation:LOC EXHAUST VENT MAY BE REQUIRED IN ADDITION TO GEN ROOM
VENT TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH: 11.8-11.9. EFTS OF OVEREXP: RXN IN SENSITIVE, EXPOSED PERS. DEAE IS
A SEV SKIN IRRIT & IT HAS BEEN REPORTED TO CAUSE SKIN SENSIT
(INDUCTION OF ALLERGY) IN GUINEA PIGS TESTS. PRLNG/WIDESPREAD SKIN
CONT W/THIS PROD MAY RSLT IN ABSORPTIONOF HARMFUL AMTS OF MATL.
INGEST: MAY CAUSE SEV IRRIT/BURNS OF MUC MEMB (ING 3)

Vapor Pres:21 @ 20C
Vapor Density:3-4
Spec Gravity:1.0185-1.0195
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, PALE YELLOW LIQUID, WITH AMINE ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG ACIDS, COPPER ALLOYS, ZINC GALVANIZED IRON.
Stability Condition to Avoid:KEEP AWAY FROM HEAT AND FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.

Waste Disposal Methods:DISCARDED PRODUCT, AS SOLD, WOULD NOT BE
CONSIDERED A RCRA HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.