Product ID:MARINE ANTIFREEZE -50 DEGREE
MSDS Date:05/01/1995
FSC:6850
NIIN:00N071561
MSDS Number: CBPBT

NOBLE CO

614 MONROE ST
GRAND HAVEN, MI 49417-1065
US

Emergency Phone: 616-842-7844

Info Phone: 616-842-7844

Cage: JO357

THE NOBLE CO

GRAND HAVEN, MI 49417-1065 US

Telephone: 616-842-7844

Cage: 54756

1,2-PROPANEDIOL; (PROPYLENE GLYCOL)

CAS: 57-55-6

RTECS: TY2000000

OSHA PEL N/K

ACGIH TLV: N/K

POTASSIUM PHOSPHATE; DIBASIC

CAS: 7758-11-4

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

COOLING. AVOID FROTHING/STEAM EXPLOSION. BURNING LIQ

RTECS: 9999999ZZ

PRACTICAL TO EXTINGUISH FIRE BY WATER DILUTION. NOTE

RTECS: 9999999ZZ

TRAVEL LONG DISTANCES ALONG GROUND BEFORE

RTECS: 9999999ZZ

MAY BE COMBUSTIBLE AT TEMPERATURES BELOW NORMAL FLASH

RTECS: 9999999ZZ

ASSURE EMISSIONS COMPLY W/APPLIC REGS.

RTECS: 9999999ZZ

POISONING PLANT BIOMASS. ASSURE EFFLUENT COMPLIES

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE MINOR EYE
IRRITATION. CHRONIC:NONE LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD . EYES:IMMEDIATELY RINSE W/CLEAN WATER
FOR AT LEAST 15 MINUTES. RETRACT EYELIDS OFTEN. OBTAIN EMERGENCY
MEDICAL ATTENTION IF PAIN, BLINKING, TEARS, OR REDNESS PERSIST.

Flash Point Method:TCC
Flash Point:211F,99C
Lower Limits:2.0%
Upper Limits:13.0%
Extinguishing Media:DRY CHEMICAL, WATERSPRAY, WATER FOG, CO*2, OR
ALCOHOL TYPE FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . DO
NOT ENTER FIRE AREA W/OUT PROPER PROT. SEE SECTION - DECOMP PRODS
POSS. FIGHT FIRE FROM DISTANCE/ (SUPDAT)
Unusual Fire/Explosion Hazard:HEAT FROM FIRE CAN GENERATE FLAMM VAP.
WHEN MIXED W/AIR & EXPOS TO IGNIT SOURCE, VAPS CAN BURN IN
OPEN/EXPLODE IF CONFINED. VAPS MAY BE HVR/AIR. MAY (ING 6)

Spill Release Procedures:SLIPPERY-SPREAD GRANULAR COVER.
IMPOUND/RECOVER LG LAND SPILL; SOAK UP SM SPILL ON WATER, MATL SOL.
CONTAIN/MINIMIZE DISPERSION/COLLECT. HIGHLY BIODEGRADABLE-CAN
STIMULATE ALGAE GROWTH WHEN NOT PROPER LY INHIBITED. RPT PER
REGULATORY REQUIREMENTS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN TIGHTLY CLSD CNTNRS. STORE
AWAY FROM HEAT/MOISTURE/STRONG OXIDIZING AGENTS. MATL CAN ATTACK
SOME FORMS OF PLASTICS.
Other Precautions:WHEN NORM HNDLG REQS HEATING, DO NOT HEAT >50F BELOW
FLASH POINT UNLESS IN CLSD SYS AWAY FROM AIR. HANDLE EMPTY CNTNRS
WITH CARE/RESIDUE CAN BURN IF HEATED. DRAIN ANY NEC RESIDUE TO
SEWER CAREFULLY TO PVNT UPSET TO SEWAGE TREATMENT.

Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION EQUIPMENT IS
RECOMMENDED UNDER ANTICIPATED CONDITIONS OF NORMAL USE WITH
ADEQUATE VENTILATION. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN (FP N).
Ventilation:AT ELEVATED TEMPERATURES, SPECIAL VENTILATION MAY BE
REQUIRED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
SPEC GRAV:1.03 @ 20C/4C (68F/32.9F). VAP DENS:2.6 (AIR=1.0 @ 60-90F).
FL PT:211F,99C FOR PURE PROPYLENE GLYCOL (PG). THE BL-50 MIX WILL
BE CONSIDERABLY HIGHER. FIRE FIGHT PROC:PROTECTED LOCATION. HEAT
MAY BUILD PRESS/RUPTURE CLSD CNTNRS. SPREADING FIRE, INCREASING
RISK OF BURNS/INJURIES. USE WATER APRAY/FOG FOR (ING 4)

Boiling Pt:B.P. Text:214F,101C
Vapor Pres:19 @ 70F
Vapor Density:SUPDAT
Spec Gravity:SUPDAT
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:COMPLETE
Appearance and Odor:FD&C RED #40 DYE, SLIGHTLY VISCOUS, RELATIVELY
ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:INCOMPLETE COMBUST MAY PRDCE CARBON
MONOXIDE & OTHER HARMFUL GASES/VAPORS, INCLUDING OXIDES OF
PHOSPHOROUS & POTASSIUM.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS .
CONTAMD PROD/SOIL/WATER SHOULD BE CONSIDERED DANGEROUS DUE TO
POTNTL FOR ENVIR HARM. LANDFILL SOLIDS AT PERMITTED SITES. USE
REGISTERED TRANSPORTERS. B URN CONCENTRATED LIQS. AVOID
FLAMEOUTS.(ING 8)

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of Defense. The United States of America in no manner whatsoever,
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assume responsibility for the suitability of this information to their
particular situation.