Product ID:SOLUTION S0771 N-2 TITRANT
MSDS Date:08/03/1989
FSC:6550
NIIN:01-385-2803
MSDS Number: CBRBN

NALCO CHEMICAL CO

ONE NALCO CENTER
NAPERVILLE, IL 60563-1198
US

Emergency Phone: 708-920-1510

Info Phone: 708-920-1510

Preparer: RICKY STACKHOUSE

Cage: 89524

ONDEO NALCO COMPANY

NAPERVILLE, IL 60563-1198 US

Telephone: (630) 305-1000

Cage: 89524

SULFURIC ACID (SARA 302/313) (CERCLA)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 20-40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

GASTRIC LAVAGE. MEASURES AGAINST CIRCULATORY

RTECS: 9999999ZZ

TREAT PLANT WHICH HAS A PH CTL SYS IN

RTECS: 9999999ZZ

PLASTIC, & PLACED IN GARBAGE COLLECTION CONTAINER.

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES/SKIN: CORROSIVE, WITH
POSSIBLE PERMANENT DAMAGE DEPENDING ON THE LENGTH OF EXPOSURE AND
ON THE FIRST AID ACTION GIVEN. INGESTION: CAN BE HARMFUL DUE TO
ACIDIC NATURE.
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONO ON EVAL OF
CARCIN RISK OF CHEMICALS TO MAN, VOL 54, PG 41, 1992: GROUP 1.
ANIMAL: PULM IRRIT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.

First Aid:EYES: IMMED FLUSH FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS
OPEN. CALL MD AT ONCE. SKIN: IMMED FLUSH W/WATER FOR AT LEAST 15
MIN. CALL MD. INGEST: DO NOT INDUCE VOMIT. GIVE WATER. CALL MD.
INHAL: REMO VE TO FRESH AIR. TREAT SYMPS. CALL MD. NOTE TO MD: NO
SPEC ANTIDOTE IS KNOWN. BASED ON INDIVIDUAL RXNS OF PATIENT, MD'S
JUDGMENT SHOULD BE USED TO CTL SYMPS & CLINICAL CNDTN. CAUTION:
(SUP DAT)

Flash Point:NONE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EVOLVE SO*X UNDER FIRE CONDITIONS.

Spill Release Procedures:SMALL LIQUID SPILLS: COVER SPILL WITH SODIUM
BICARBONATE OR SODA ASH/LIME MIXTURE. MIX AND ADD WATER TO FORM A
SLURRY. FLUSH DOWN DRAIN WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. USE WITH
ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:IF IT POSSIBLE TO GENERATE SIGNIFICANT LEVELS OF
VAPORS OR MISTS, A NIOSH APPROVED OR EQUIVALENT ACID RESPIRATOR IS
RECOMMENDED.
Ventilation:GENERAL VENT IS RECOMMENDED. ADDITIONALLY, LOCAL EXHAUST
VENT IS REC WHERE VAPORS, MISTS/AEROSOLS MAY BE RELEASED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 5)
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID: CALCIUM HYDROXIDE (LIME), CYANIDES, SULFIDES,
HYPOCHLORITES, CHLORITES) WHICH CAN GENERATE HEAT
W/SPLATTERING/BOILING & RELEASE OF TOX FUMES. FIRST AID PROC: IF
UNCON, HAVING TROUBLE B RTHG/IN CONVULSIONS, DO NOT INDUCE
VOMIT/GIVE WATER. NOTE TO MD: PROBABLE MUCOSAL DMG MAY
CONTRAINDICATE USE OF (ING 2)

pH:<1
Solubility in Water:COMPLETELY
Appearance and Odor:CLEAR ORANGE LIQUID, WITH NO ODOR

Stability Indicator/Materials to Avoid:YES
AVOID ALKALINE MATLS (E.G., AMMONIA & ITS SOLNS, CARBONATES, SODIUM
HYDROXIDE (CAUSTIC), POTASSIUM HYDROXIDE, (SUP DAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN THE EVENT OF COMBUSTION, SO*X MAY
BE FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE PROTECTIVE
EQUIPMENT.

Waste Disposal Methods:IF THIS PROD BECOMES A WASTE, IT MEETS THE
CRITERIA OF HAZ WASTE AS DEFINED UNDER RCRA 40 CFR 261. HAZ WASTE
D002. ACID SOLNS SHOULD BE NEUT BEFORE BEING DISCHARGED TO SANITARY
SEWER. ALTERNATIVELY, A N ACID SOLN MAY BE DISP INTO WASTE (ING3)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.