Product ID:SKYDROL 500B-4 FIRE RESISTANT HYDRAULIC FLUID
MSDS Date:07/17/1995
FSC:9150
NIIN:00-134-8785
MSDS Number: CBSXT

MONSANTO CO

800 N LINDBERGH BLVD
SAINT LOUIS, MO 63167
US

Emergency Phone: 314-694-6661, CHEMTREC 800-424-9300

Info Phone: 314-694-6661

Cage: 76541

MONSANTO COMPANY

SAINT LOUIS, MO 63167 US

Telephone: 314-694-6661 OR 800-332-3111

Cage: 76541

TRIBUTYL PHOSPHATE

CAS: 126-73-8

RTECS: TC7700000

OSHA PEL 5 MG/M3

ACGIH TLV: 0.2 PPM; 9596

DIBUTYL PHENYL PHOSPHATE

CAS: 2528-36-1

RTECS: TB9626600

LD50 LC50 Mixture:ORAL LD50(RAT): 2,200 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT WITH THIS PRODUCT HAS BEEN
REPORTED TO PRODUCE SEVERE EYE PAIN WITHOUT EYE DAMAGE. PRODUCT
REMOVES OIL FROM THE SKIN CAUSING DRYING AND CRACKING FOLLOWING
REPEATED AND PROLONGED CONTACT. E XPOSURE TO AEROSOLIZED FLUID OR
VAPORS ARE PRODUCED AT HIGH TEMPERATURES HAS BEEN REPORTED TO CAUSE
IRRITATION.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE PAIN, SKIN DRYING, CRACKING, NOSE/THROAT
IRRITATION, COUGHING, WHEEZING, NAUSEA, HEADACHE, URINARY BLADDER
DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL
ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION.

Flash Point Method:COC
Flash Point:320F,160C
Autoignition Temp:Autoignition Temp Text:750F
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY(FOG), FOAM, DRY CHEMICAL, CARBON
DIOXIDE
Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS EXPOSED TO PRODUCTS
OF COMBUSTION SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.
EQUIPMENT SHOULD BE THOROUGHLY DECONTAMINATED.
Unusual Fire/Explosion Hazard:PRODUCTS OF DECOMPOSITION INCLUDE
HAZARDOUS CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF PHOSPHORUS.

Spill Release Procedures:CONTAINS LARGE SPILLS WITH DIKES AND TRANSFER
THE MATERIAL TO APPROPRIATE CONTAINERS FOR RECLAMATION OR DISPOSAL.
ABSORB REMAINING MATERIAL OR SMALL SPILLS WITH AN INERT MATERIAL
AND THEN PLACE IN A C HEMCIAL WASTE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE
VENTILATION. KEEP CONTAINER CLOSED.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. EMPTIED CONTAINER
RETAINS VAPOR AND PRODUCT RESIDUE. OBSERVE ALL LABELLED SAFEGUARDS
UNTIL CONTAINER IS DESTROYED. DO NOT REUSE THIS CONTAINER.

Respiratory Protection:USE NIOSH/MSHA APPROVE RESPIRATORY PROTECTION
EQUIPMENT WHEN AIRBORNE EXPOSURE IS EXCESSIVE.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION AS
REQUIRED TO MAINTAIN EXPOSURE LEVELS.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
LAUNDER CONTAMINATED CLOTHING AND CLEAN PROTECTIVE EQUIPMENT BEFORE
REUSE.

HCC:V6
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:1.052-1.060
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, PURPLE OILY LIQUID, NO ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXTREME TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF PHORPHORUS, CARBON MONOXIDE,
SOOT.

Waste Disposal Methods:PRODUCT MEETS THE CRITERIA FOR A SYNTHETIC USED
OIL UNDER US EPA STANDARDS FOR THE MANAGEMENT OF USED OIL (40 CFR
279). CONTACT LOCAL, STAE AND FEDERAL AUTHORITIES TO DETERMINE
CORRECT DISPOSAL PROCE DURES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.