Product ID:SS-25/19
MSDS Date:02/06/1990
FSC:6850
NIIN:01-031-1747
MSDS Number: CCBFV

NATIONAL CHEMSEARCH DIV OF NCH CORP

IRVING, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 214-438-1381

Preparer: KELLY RAHN

Cage: DO481

NCH CORP

152170 IRVING, TX 75015-2170 US

Telephone: 972-438-0563

Cage: 20913

LIGROINE; (ALIPHATIC PETROLEUM DISTILLATE)

CAS: 8032-32-4

RTECS: OI6180000

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

ETHYLENE, TETRACHLORO-; (PERCHLOROETHYLENE) (SARA 313)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 40%

OSHA PEL 100 PPM, Z-2

ACGIH TLV: 25 PPM/100 STEL, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYLENE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 20%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PPM VIA INHAL 6 HRS PER DAY, 5 DAYS PER WK FOR 1 YR.

RTECS: 9999999ZZ

MONTH & STUDIES INDICATE NO STATISTICALLY SIGNIFICANT

RTECS: 9999999ZZ

QUESTION, SINCE EXPOS LASTED FOR ONLY 2 YR. 3RD STUDY

RTECS: 9999999ZZ

PPM & RATS TO 200 & 400 PPM FOR 6 HRS PER DAY, 5 DAYS

RTECS: 9999999ZZ

OBSERVED IN MICE. IN RATS AN INCR IN RARE KIDNEY

RTECS: 9999999ZZ

HAD INCR INCIDENCE OF MONONUCLEAR CELL LEUK. IARC

RTECS: 9999999ZZ

CARCIN. EPIDEMIOLOGIC STUDIES HAVE BEEN INCONCLUSIVE

RTECS: 9999999ZZ

HUMANS. PERIPHERAL NEUROPATHY HAS BEEN CITED AS SYMP

RTECS: 9999999ZZ

FOUND TO BE EMBRYOTOXIC & HAS CAUSED DELAYS IN

RTECS: 9999999ZZ

TERATOGENIC (BIRTH DEFECT) EFTS IN EXPERIMENTAL

RTECS: 9999999ZZ

LISTED BY CA PROP 65 AS CARCINS. CHLOROCARBON MATLS

RTECS: 9999999ZZ

LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.

RTECS: 9999999ZZ

EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS

RTECS: 9999999ZZ

HIPS TO PVNT ASPIR OF LIQ INTO LUNGS. GET

RTECS: 9999999ZZ

RETAINED AS WELL AS TOX OF PROD, GASTRIC LAVAGE

RTECS: 9999999ZZ

TO PVNT PULM ASPIR. IF COMATOSE, CUFFED ENDOTRACHEAL

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 3
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CAN LEAD TO CNS DEPRESS, HDCH,
DIZZ. NAUS & LOSS OF CONSCIOUSNESS. WILL DEFAT SKIN & CAUSE IRRIT
CAUSING TEARING & REDNESS. CHRONIC:CNS DEPRESS OF SYS, KIDNEY DMG,
DERM & POSSIBLY CANCER. SYSTEM IC & OTHER EFTS:PERCHLOROETHYLENE
HAS CAUSED LIVER & KIDNEY TOX EFTS IN CHRONICALLY OVEREXPOSED (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONO SUPP, VOL
7, PG 194, 1987:GROUP 2B. NTP 7 TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO (SUPDAT)
Effects of Overexposure:HLTH HAZ:EXPERIMENTAL ANIMALS. CARCIN:3 STUDIES
HAVE BEEN CONDUCTED TO ASSESS CARCIN POTNTL OF PERCHLOROETHYLENE IN
LAB ANIMALS. IN 1 STUDY, RATS & MICE WERE EXPOS BY GAVAGE
(FORCE-FED) @ LEV OF 500 & 1000 MG/KG/DAY. INCR INCIDENCE OF LIVER
TUMORS WERE OBSERVED IN MICE. RSLTS OF RAT STUDY WERE INCONCLUSIVE
DUE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR & TREAT SYMPTOMATICALLY. GIVE OXYG IF
BRTHG IS DFCLT. GIVE ARTF RESP IF BRTHG STOPS. GET MED HELP.
EYE:FLUSH W/WATER FOR @ LEAST 15 MINS, HOLDING EYELIDS OPEN
OCCASNLY FOR MAX BENEFIT. SEE PHYS IF IRRIT PERSISTS. SKIN:WASH
W/SOAP & WATER. APPLY EMOLLIENT RICH CREAM. SEE PHYS IF IRRIT
PERSISTS. INGEST:DO NOT INDUCE EVEN IF VOMIT OCCURS. IF IT OCCURS,
KEEP HEAD BELOW (ING 14)

Flash Point Method:COC
Flash Point:180F,82C
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . UNDER CERTAIN CONDITIONS PHOSGENE CAN BE
FORMED. (TEMPERATURES IN EXCESS OF 1000F).

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. PVNT FROM
ENTERING SEWER/WATER SOURCES. VENTILATE ENCLOSED SPACE. WEAR RESP.
CLEAN UP (ANY ELECTRIC CLEANING EQUIP MUST BE EXPLO PROOF) OR SOAK
UP W/SAND, COTTON WASTE OR OTHER ABSORBANT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:INDOOR:STOR TEMP:120F MAX, -50F MIN.
FOLLOW LBL DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF
REACH OF CHILDREN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:NO RESP IS NEEDED IN NORM USE. IN EMER
SITUATIONS, HOWEVER THE FOLLOWING ARE REC:NIOSH/MSHA APPRVD
500PPM:CCROVF/GMOV/SAF/SCRAB. 1000 PPM:NIOSH/MSHA APPRVD
CCROVF/GMOV/SAF/SCBAF. ESCAPE:NIOSH/MSHA APP RVD GMOV/SCBA.
Ventilation:LOCAL EXHAUST SHOULD BE EMPLOYED TO KEEP AIR QTY @ OR EQUAL
TO MAXIMUM ALLOWED CONCENTRATION.
Protective Gloves:VITON, PVA, OR EQUIVALENT.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:HEADGEAR & APRON WHEN SPRAYING. ANSI APPRVD
EMER EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:BE CARCIN. ANIMAL:LUNG, LIV, SALIVARY, MAMMARY GLAND
(TUMORS). TETACHLOROETHYLENE:IARC MONO, SUPP VOL 7, PG 355,
1987:GROUP 2A. NTP 7TH ANN RPT ON CARCIN, 1994:ANTIC TO BE CARCIN.
ANI MAL:BLOOD, LIVER. EFTS OF OVEREXP:TO EXCESS IN ANIMAL DEATHS.
SECOND STUDY INVOLVED RATS EXPOS TO CONC UP TO 600(ING 4)

Boiling Pt:B.P. Text:113F,45C
Vapor Pres:60
Vapor Density:1
Spec Gravity:1.030 (H*2O=1)
Evaporation Rate & Reference:0.10 (BU AC =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NON-VISCOUS TRANSPARENT WATER WHITE, CHLORINATED
SOLVENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, ACIDS, SELECTED AMINES, & ALUMINUM (WHEN IN PRESENCE
OF WATER & CLOSE CONT UNDER PRESSURE).
Stability Condition to Avoid:OPEN FLAMES.
Hazardous Decomposition Products:HCL & PHOSGENE . CAN @ DECOMP TEMP
RELEASE CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE &
PHOSGENE.

Waste Disposal Methods:WASTE LIQUIDS SHOULD BE SENT TO LICENSED
RECLAIMER/INCINERATED @ LICENSED INCIN. DISPOSE OF IN ACCORDANCE
WITH ALL FEDERAL, STATE AND LOCAL POLLUTION REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.