Product ID:4411
MSDS Date:07/15/1996
FSC:8010
NIIN:00D005608
MSDS Number: CCLHG

B&B CHEMICAL COMPANY,INC.

875 WEST 20TH. STREET,
HIALEAH, FL 33010
US

Emergency Phone: 305-888-5247/800-424-9300(CHEMTREC)

Info Phone: 305-888-5247

Cage: 21361

B & B TRITECH, INC.

HIALEAH, FL 33010-2310 US

Telephone: 305-888-5247

Cage: 21361

METHYLENE CHLORIDE (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: <72%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

AMMONIA (SARA 302/313) (CERCLA)

CAS: 7664-41-7

RTECS: BO0875000

Fraction By Weight: <5%

OSHA PEL 50 PPM

ACGIH TLV: 25 PPM/35 STEL; 9596

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

SODIUM CHROMATE (SARA 313) (CERCLA)

CAS: 7775-11-3

RTECS: GB2955000

Fraction By Weight: <1%

OSHA PEL C 0.1 MG (CRO3)/M3

ACGIH TLV: 0.05 MG(CR)/M3;A1;96

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <4%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 96

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TRADE SECRET COMPONENT/INGREDIENT A

Fraction By Weight: <8%

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:LUNG, EYE, SKIN, LIVER,
KIDNEY. ACUTE- EYE:CAUSES IRRITATION. SKIN:IRRITATION, DEFATTING.
PROLONGED SKIN CONTACT MAY RESULT IN BURNS & ABSORPTION. INHALE:MAY
CAUSE CNS DEPRESSION. NARCOT IC IN HIGH CONCENTRATIONS.
ORAL:HARMFULIF INGESTED. CHRONIC- LONG TERM OVEREXPOSURE MAY CAUSE
LIVER & KIDNEY DAMAGE.
Explanation of Carcinogenicity:METHYLENE CHLORIDE IS LISTED AS A
POTENTIAL HUMAN CARCINOGEN BY NTP, IARC AND ACGIH. CONTAINS SODIUM
CHROMATE.
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, HEADACHE,
DIZZINESS, SKIN DEFATTING AND BURNS, ELEVATED CARBOXYHEMOGLOBIN
LEVELS, WEAKNESS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY, CARDIOVASCULAR
OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THE SUBSTANCE.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.
EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
HOLD EYELIDS OPEN. WASH SKIN WITH SOAP & WATER. INHALED:REMOVE TO
FRESH AIR. PROVIDE CPR/OXYG EN IF NECESSARY. ORAL:DO NOT INDUCE
VOMITING. CALL PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.

Flash Point Method:COC
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:CARBON DIOXIDE, SAND, DRY CHEMICAL (ABC) OR FOAM.
USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. DANGEROUS TO EYES.
Unusual Fire/Explosion Hazard:THERE IS POSSIBILITY OF PRESSURE BUILDUP
IN CLOSED CONTAINERS. METHYLENE CHLORIDE FORMS FLAMMABLE MIXTURES
WITH MANY FLAMMABLE SOLVENTS. TOXIC AND ACIDIC VAPORS

Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA.
ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL. PLACE IN A
CONTAINER FOR CHEMICAL WASTE. WASH AREA WITH SOAPY WATER TO REMOVE
RESIDUE. COLLECT WATER RIN SES IN APPROPRIATE CONTAINER.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED PLACE
AWAY FROM OPEN FLAMES, INCOMPATIBLE MATERIALS. LOOSEN CLOSURE
CAUTIOUSLY.
Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH
OF CHILDREN. USE IN WELL VENTILATED AREA. FOR LABORATORY USE ONLY.

Respiratory Protection:IF THE TLV IS EXCEEDED, WEAR A NIOSH-APPROVED
FULL-FACED RESPIRATOR FOR CHLORINATED SOLVENTS OR ORGANIC VAPOR.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:FLUOROELASTOMER (VITON), PVA
Eye Protection:CHEMICAL SPLASH GOGGLES/SAFETY GLASSES
Other Protective Equipment:PROTECTIVE CLOTHING AS NEEDED TO PREVENT
PROLONGED/REPEATED SKIN CONTACT, EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:100F,38C
Vapor Density:>1
Spec Gravity:1.1
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:PARTIAL
Appearance and Odor:YELLOW, VISCOUS LIQUID - CHLORINATED SOLVENT ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. AVOID CONTACT WITH OPEN FLAMES, ELECTRICAL ARCS,
EXCESSIVE HEAT
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON MONOXIDE,
CARBON DIOXIDE, PHOSGENE AND CHLORINE MAY BE FORMED.

Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL REGULATIONS. CAN BE INCINERATED.
CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT R ESIDUE, FOLLOW LABEL WARNINGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.