Product ID:HAZE GRAY LATEX, D10167
MSDS Date:06/21/1990
FSC:8010
NIIN:00N073311
MSDS Number: CCNMP

PPG INDUSTRIES INC

250 KAPPA DR
PITTSBURGH, PA 15238
US

Emergency Phone: 304-843-1300

Info Phone: 412-963-5822

Cage: DO542

PPG INDUSTRIES INC. COATINGS & RESINS GP

9 ALLISON PARK, PA 15101

Telephone: 412-492-5555

Cage: DO542

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 2-5%

OSHA PEL N/K

ACGIH TLV: 0.1 MG/M3 RDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 5-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

WATER; (DEIONIZED WATER)

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 50-55%

OSHA PEL N/K

ACGIH TLV: N/K

2-2-PROPOXY ETHANOL; (DIETHYLENE GLYCOL MONOPROPYL ETHER)

CAS: 6881-94-3

Fraction By Weight: 2-5%

OSHA PEL N/K

ACGIH TLV: N/K

BENZYL ALCOHOL

CAS: 100-51-6

RTECS: DN3150000

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

PROPIONIC ACID, 2-METHYL-, MONOESTER WITH 2,2,4-

CAS: 25265-77-4

RTECS: UF6000000

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

FILM FORMERS, RESINS AND ADDITIVES

Fraction By Weight: 25-30%

OSHA PEL N/K

ACGIH TLV: N/K

APPLICATION OF PROD IS NOT EXPECTED TO

RTECS: 9999999ZZ

FOR HUMANS IS LIMITED. PROD CNTNS TITANIUM DIOXIDE.

RTECS: 9999999ZZ

IN LONG-TERM STUDY DEVELOPED LUNG TUMORS. STUDIES

RTECS: 9999999ZZ

INCRD RISK OF CANCER FROM EXPOS. POTNTL FOR INHAL

RTECS: 9999999ZZ

LIMITED. SINCE OVEREXPOSURES ARE NOT EXPECTED,

RTECS: 9999999ZZ

FOLLOWING USE OF THIS PROD, CNTCT POISON

RTECS: 9999999ZZ

INFO AVAILABLE. INGESTION. EXCESSIVE EXPOSURE TO

RTECS: 9999999ZZ

SUGGESTED EXPOS LIMITS, LEL BELOW STATED LIMIT & TO

RTECS: 9999999ZZ

SURFACES COATED W/THIS PRODUCT.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST:HARMFUL/FATAL IF SWALLOWED.
EYES:IRRIT. REDNESS, ITCH, BURNING SENSATION & VISUAL DISTURBS MAY
INDICATE EXCESS EYE CNTCT. SKIN:MAY CAUSE SLIGHT IRRIT. DRYNESS,
ITCH, CRACKING, BURNING, REDNESS & SWELL ARE CNDTNS ASSOC W/EXCESS
SKIN CNTCT. INHAL:VAP & SPRAY MIST MAY BE HARMFUL IF INHALED.
SANDING(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT
ON CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ: & GRINDING DUSTS MAY BE HARMFUL IF
INHALED. CHRONIC: PROD CNTNS A FORM OF CRYSTALLINE SILICA WHICH IS
ASSOC W/INCRD RISK OF CANCER IN LAB ANIMALS. LONG-TERM EXPOS TO
CRYSTALLINE SILICA MAY A LSO LEAD TO DISABLING INJURY KNOWN AS
SILICOSIS. THESE EFTS ARE ASSOC W/BRTHG EXCESS AMTS OF SILICA DUST.
(ING 8)
Medical Cond Aggravated by Exposure:NOT APPLICABLE.

First Aid:INGEST: IF SWALLOWED, DO NOT INDUCE VOMIT. EYES: IN CASE OF
EYE CNTCT, FLUSH EYES IMMED W/PLENTY OF WATER FOR AT LEAST 15 MIN.
SKIN: IN CASE OF SKIN CNTCT, FLUSH IMMED W/PLENTY OF WATER FOLLOWED
BY WA SHING W/SOAP & WATER. INHAL: IF AFFECTED BY INHAL OF
VAP/SPRAY MIST, REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER
SUPPORTIVE MEASURES AS REQD. OTHER: IF ANY OF FOLLOWING OCCUR
DURING OR (ING 13)

Flash Point Method:PMCC
Extinguishing Media:NFPA CLASS B EXTING(CO*2/DRY CHEM/UNIVERSAL AQ FILM
FORMING FOAM) DESIGNED TO EXTING NFPA CLASS IIIB COMBUST LIQ FIRES.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. WATER
SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD CNTNRS
TO PVNT PRESS BUILDUP & POSS (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
(DUE TO THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME
HEAT.

Spill Release Procedures:PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER
NIOSH APPRVD RESP & SKIN & EYE PROTECTION SHOULD BE PERMITTED IN
AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATL
W/SAWDUST, VERMICULITE OR OTHE R ABSORB MATL & PLACE INTO CNTNRS
FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA
CLASS IIIB COMBUST LIQS. PROTECT FROM FREEZING.
Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT
COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE
OTHER COMPONENT(S) BEFORE BLENDING AS THE RESULTING MIXTURE MAY
HAVE THE HAZARDS OF ALL OF ITS PARTS.

Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE A SUITABLE
NIOSH APPROVED RESPIRATOR.
Ventilation:PROVIDE GEN DILUTION OR LOC EXHST VENT IN VOL & PATTERN TO
KEEP CONC OF INGREDS LISTED BELOW THE LOWEST (ING 15)
Protective Gloves:NITRILE, NEOPRENE OR LATEX GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING AND
SHOES.
Supplemental Safety and Health
FIRE FIGHT PROC: AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. IF WATER
IS USED, FOG NOZZS ARE PREF. HAZ DECOMP PRODS: INCLUDING CARBON
MONOXIDE, ZINC OXIDE. EXPLAN OF CARCIN: 1994:ANTIC TO BE CARCIN.

Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:17.1
Vapor Density:HVR/AIR
Spec Gravity:1.11
Evaporation Rate & Reference:31 (BUOAC=100)
Solubility in Water:56.6%
Appearance and Odor:VISCOUS LIQUID W/ODOR CHARACTERISTIC OF CHEMICAL
FAMILY & ANY LISTED SOLVENTS.
Percent Volatiles by Volume:56

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE HAZ DECOMP PRODS WHEN
HEATED. WELDING/BRAZING/FLAME-CUTTING ON SURFS COATED W/PROD MAY
PRDCE FUMES (SUPDAT)

Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE, PROVINCIAL AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WAS TE MANAGEMENT FACILITY.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.