Product ID:IMRON 5000 POLYURETHANE ENAMELS, 511H
MSDS Date:01/01/1995
FSC:8010
NIIN:00N073983
MSDS Number: CCPZB

E I DUPONT DE NEMOURS & CO

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Cage: 0ERJ7

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

NONE @ 20C

CAS: 42767-92-0

OSHA PEL N/K

ACGIH TLV: N/K

NONE @ 20C

CAS: 42767-92-0

OSHA PEL N/K

ACGIH TLV: N/K

8

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM; 200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NONE @ 20C

CAS: 18454-12-1

RTECS: OF9800000

Fraction By Weight: 56%

OSHA PEL N/K

ACGIH TLV: N/K

2.2 @ 20C

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

OSHA PEL N/K

ACGIH TLV: N/K

25 @ 20C

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACTIVITY IN ANIMALS HAS BEEN INCONCLUSIVE. HAS BEEN

RTECS: 9999999ZZ

OVEREXP TO LEAD MAY CAUSE

RTECS: 9999999ZZ

REPRO SYS INCLUDING EMBRYOTOX EFTS. SYMPS MAY INCL

RTECS: 9999999ZZ

SEE OSHA LEAD STD 29CFR 1910.1025. FOR EXPOS LONGER

RTECS: 9999999ZZ

LIMIT (IN G/M3)=400/HRS WORKED IN DAY. THESE CHEMS

RTECS: 9999999ZZ

INGEST

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CAUSED INCRD LIVER & KIDNEY WTS. PROPYLENE GLYCOL

RTECS: 9999999ZZ

RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY

RTECS: 9999999ZZ

ANIMALS. RECURRENT OVEREXP MAY RSLT IN LIVER &

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SPILL & ALLOW TO SIT 10 MIN, MINIMUM. TYPICAL

RTECS: 9999999ZZ

80% WATER, 0-10% AMMONIA, 2-5% DETERGENT, BALANCE

RTECS: 9999999ZZ

AFTER 48 HRS, CNTNR MAY BE SEALED & DISPOSED OF.

RTECS: 9999999ZZ

PROBS OR PRIOR RXN TO ISOCYANATE SHOULD NOT

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IN PAINTING AREA. FOLLOW RESP MFR'S DIRECTIONS FOR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:LEAD APPEARS ON THE NAVY LIST OF OCCUP
CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO .
INGEST:GI DISTRESS. INHAL:MAY CAUSE NOSE & THROAT IRRIT. RPTD &
PRLNGD OVEREXP TO SOLVS MAY LEAD TO PERM BRAIN & NERVS SYS DMG.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:LEAD CHROMATE: IARC MONOGRAPHS ON EVAL
OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990:GROUP 1. NTP
7TH (SUPDAT)
Effects of Overexposure:HLTH HAZ: EYE WATERING, HDCH, NAUS, DIZZ & LOSS
OF COORDINATION ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. EXPOS TO
ISOCYANATES MAY CAUSE RESP SENSIT; MAY BE PERM & MAY BE DELAYED FOR
SEVERAL HRS AFTER EXPOS. RPTD OVEREXP TO ISOCYANATES MAY CAUSE
DECR IN LUNG FUNC; MAY BE PERM. PERS W/BRTHG PROBS OR PRIOR RXN TO
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: IN THE UNLIKELY EVENT OF INGEST, CALL MD IMMED & HAVE
NAMES OF INGREDS AVAIL. INHAL: IF AFFECTED BY INHAL OF VAPOR OR
SPRAY MIST, REMOVE TO FRESH AIR. IF BREATHING DFCLTY PERSITS OR
OCCURS LAT ER, CONSULT MD. EYES: IN CASE OF EYE CONTACT, IMMED
FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN; CALL MD. SKIN: IN CASE
OF SKIN CONTACT, WASH W/SOAP & WATER. IF IRRIT OCCURS, CONTACT MD.

Flash Point Method:CC
Flash Point:100F,38C
Lower Limits:0.9%
Upper Limits:23.0%
Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS
FLAM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE
MISTS/SPRAYS MAY BE FLAM AT TEMPS BELOW THE FLASH POINT.

Spill Release Procedures:DO NOT BREATHE VAPS. DO NOT GET IN EYES/ON
SKIN. WEAR NIOSH APPRVD POS PRESS, SUPPLIED AIR VAP/PARTICULATE
RESP (TC-19C), EYE PROT, GLOVES & PROT MATL. REMOVE SOURCES OF
IGNIT. ABSORB W/INERT MATL. VE NT AREA. POUR LIQ DECONTAMINATE SOLN
OVER (ING 18)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE LABEL PRECS. KEEP AWAY FROM
HEAT, SPKS & FLAME. CLOSE CNTNR AFTER EACH USE. GROUND CNTNRS WHEN
POURING. DO NOT STORE ABOVE 120F.
Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
SMOKING. DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING WITHOUT
A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.

Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR NIOSH APPRVD POS
PRESS, SUPPLIED AIR RESP (TC-19C) WHILE MIXING ACTIVATOR W/ANY
PAINT OR CLEAR ENAMEL, DURING APPLICATN & UNTIL ALL VAPS & SPRAY
MISTS ARE EXHAUSTED. PE RS W/HISTORY OF LUNG/BRTHG (ING 21)
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
COVERALLS ARE RECOMMENDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: ANNUAL REPORT ON CARCINS, 1994: KNOWN TO BE CARCIN.
EFTS OF OVEREXP: ISOCYANATES MUST NOT BE EXPOSED TO VAP/SPRAY MIST
OF PROD. EYE: MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNGD LIQ CN TCT
MAY CAUSE IRRIT W/DISCOMFORT & DERM. BUTYL ACETATE: MAY CAUSE
ABNORM LIVER FUNC. TESTS FOR EMBRYOTOXIC (ING 9)

Boiling Pt:B.P. Text:>135F,>57C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.980
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:7-100

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE, OXIDES OF LISTED HEAVY METALS.

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.