Product ID:TONER KIT 8/15 (150 GRAMS), 5397-30
MSDS Date:08/01/1995
FSC:6850
NIIN:00N074685
MSDS Number: CCSCK

RICOH CORP

5 DEDRICK PLACE
WEST CALDWELL, NJ 07006
US

Emergency Phone: 800-336-6737

Info Phone: 800-336-6737; 201-882-2000

Cage: RICOH

RICOH CORP

WEST CALDWELL, NJ 07006 US

Telephone: 201-882-2000

Cage: RICOH

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

IRON (III) OXIDE; (IRON OXIDE)

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: 50-60%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3 FUME (FE)

SOLVENT BLACK 7; (DYE)

CAS: 8005-02-5

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

STYRENE/ACRYLATE POLYMER; (STYRENE ACRYLIC POLYMER)

CAS: 25213-39-2

Fraction By Weight: 40-50%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES/INHAL:NOT APPLIC.
SKIN:IRRIT (RABBIT) - MILDLY IRRITATING. INGEST:>5 G/KG BODYWEIGHT.
CHRONIC:IN A XEROX SPONSORED CHRONIC INHAL STUDY IN RATS USING A
SPECIAL TEST TONER, THERE WERE NO LUNG CHANGES AT ALL IN LOWEST
EXPOS LEVEL (1 MG/M3), MOST RELEVANT LEVEL TO POTNTL HUMAN EXPOS. A
VERY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 65, PG 24-27, 1995:GROUP 2B.
Effects of Overexposure:HLTH HAZ:SLIGHT DEGREE OF FIBROSIS WAS NOTED IN
25% OF ANIMALS AT MIDDLE EXPOS LEVEL (4 MG/M3) WHILE A SLIGHT
DEGREE OF FIBROSIS WAS OBSERVED AT HIGHEST EXPOS LEVEL (16 MG/M3)
IN ALL ANIMALS. THESE FI NDINGS ARE ATTRIBUTED TO "LUNG
OVERLOADING", A GENERIC RESPONSE TO EXCESSIVE AMTS OF ANY DUST
RETAINED IN LUNGS (SUPDAT)
Medical Cond Aggravated by Exposure:WILL NOT OCCUR.

First Aid:EYES:TRY TO REMOVE OR FLUSH OUT W/EYE DROPS FOR AT LEAST 15
MINUTES. IF UNSUCCESSFUL, GET MEDICAL ATTENTION. SKIN:WASH
THOROUGHLY W/SOAP & WATER. INHAL:REMOVE FROM EXPOSURE.
INGEST:DILUTE STOMACH CONT ENTS W/SEVERAL GLASSES OF WATER.

Extinguishing Media:FOAM, WATER SPRAY, DRY CHEMICALS OR CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NO SPECIAL FIRE-FIGHTING PROCEDURE IS NECESSARY.
Unusual Fire/Explosion Hazard:WILL NOT OCCUR.

Spill Release Procedures:IF SPILLED, SWEEP UP USING APPRVD TONER VACUUM
CLEANER W/0.5 MICRON FILTER SUCH AS ATRIX AAA TONER VACUUM (RICOH
EDP CODE 342MIU). USE OF VACUUM CLEANER NOT RATED FOR TONER
PARTICULATE COULD BE POTNTL FIRE HAZ &/OR RSLT IN PERSONAL
INJURY.(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP OUT
OF REACH OF CHILDREN. MINIMIZE BREATHING DUST.
Other Precautions:IN ORDER TO AVOID RISK OF POWDER ENTERING EYES, DO
NOT HANDLE IN WINDY AREAS. MINIMIZE INHALATION OF DUST.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE NEEDED UNDER NORMAL CONDITIONS OF USE.
Ventilation:LOCAL EXHAUST:NONE NEEDED UNDER NORMAL CONDITIONS OF USE.
MECHANICAL (GENERAL):ADEQUATE VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . NONE NEEDED UNDER NORMAL CONDITIONS OF USE.
Work Hygienic Practices:CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE
BREAKS & MEALS, & AT THE END OF WORK PERIODS.
Supplemental Safety and Health
EFTS OF OVEREXP:FOR PRLNG INTERVAL. SPECIAL TEST TONER WAS TEN TIMES
MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER TO COMPLY W/EPA
TESTING PROTOCOL & WOULD NOT FUNCTION PROPERLY IN XEROGRAPHIC
EQUIP. SPILL PROC:REMOVE RESIDUE W/SOAP & WATER. WASTE DISP
METH:PROPER METHOD OF DISPOSAL.

Spec Gravity:1.99
Solubility in Water:NEGLIGIBLE; <0.1%
Appearance and Odor:BLACK POWDER; NO ODOR.

Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CARBON MONOXIDE & OTHER DECOMPOSITION
PRODUCTS IN THE CASE OF INCOMPLETE COMBUSTION.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . USED
TONER SHOULD BE DISP OF IN ENVIRONMENTALLY SAFE MANNER & I/A/W GOVT
REGS. DO NOT INCIN. DISP REGS VARY FROM LOCALITY TO LOCALITY,
THEREFORE, CONSU LT YOUR LOC OFFICE OF THE EPA TO DETERMINE(SUPDAT)

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particular situation.