Product ID:EXTERIOR SEMI-GLOSS, 78-45
MSDS Date:01/20/1995
FSC:8010
NIIN:00N034408
MSDS Number: CCWGZ

PPG INDUSTRIES INC

4325 ROSANNA DR
ALLISON PARK, PA 15101
US

Emergency Phone: 304-843-1300

Info Phone: 412-492-5555

Cage: 47695

PPG INDUSTRIES INC

PITTSBURGH, PA 15272 US

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: 47695

NOSE & THROAT. SAFE HNDLG OF THIS PROD REQS THAT ALL

RTECS: 9999999ZZ

ZINC OXIDE (SARA 313) (CERCLA)

CAS: 1314-13-2

RTECS: ZH4810000

Fraction By Weight: 1-<5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 20-<30%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

4-ISOTHIAZOLIN-3-ONE, 2-OCTYL-; (OCTYLISOTHIAZOLONE)

CAS: 26530-20-1

RTECS: NX8156900

Fraction By Weight: 0.1-<1%

OSHA PEL N/K

ACGIH TLV: N/K

2-PROPANOL,1-(2-BUTOXY-1-METHYLETHOXY)-; (DIPROPYLENE

CAS: 29911-28-2

RTECS: UA8200000

Fraction By Weight: 1-<5%

OSHA PEL N/K

ACGIH TLV: N/K

SILICA GEL; (SILICA)

CAS: 112945-52-5

RTECS: VV7310000

Fraction By Weight: 1-<5%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

OF IGNIT & FLASH BACK. DO NOT SMOKE WHILE USING

RTECS: 9999999ZZ

CLSD CNTNRS MAY EXPLODE WHEN OVERHEATED. DO NOT APPLY

RTECS: 9999999ZZ

IN CONTACT W/EXTREME HEAT.

RTECS: 9999999ZZ

OVEREXP OCCUR DURING/FOLLOWING USE OF PROD,

RTECS: 9999999ZZ

OF IMPERMEABLE MATL. NO SPECIFIC

RTECS: 9999999ZZ

FOR THIS PROD. RECS FOR SKIN PROT ARE BASED ON

RTECS: 9999999ZZ

IMMERSION, CONTACT MFR OF PROTECTIVE CLOTHING FOR

RTECS: 9999999ZZ

LOWER MOLECULAR WEIGHT POLYMER FRACTIONS;

RTECS: 9999999ZZ

LIMITED TO, FLAME CUTTING, BRAZING & WELDING.

RTECS: 9999999ZZ

CONT MAY CAUSE ALLERGIC SKIN RASH. VAP &/OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:HARMFUL IF SWALLOWED. EYE
CONT:CAUSES IRRIT. SKIN CONT:MAY CAUSE SLIGHT IRRIT. PRLNG/RPTD
CONT MAY CAUSE ALLERGIC RXN. INHAL:VAP &/OR SPRAY MIST MAY BE
HARMFUL IF INHALED. VAP IRRITS EYES , NOSE & THROAT. CHRONIC:AVOID
LONG-TERM & RPTD CONT. THIS PROD CONTAINS TITANIUM DIOXIDE. ANIMALS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:INHALING MASSIVE QTYS OF TITANIUM
DIOXIDE DUST IN LONG-TERM STUDY DEVELOPED LUNG TUMORS. STUDIES
W/HUMANS INVOLVED IN MFR OF THIS PIGMENT INDICATE NO INCR RISK OF
CANCER FROM EXPOS. POTNTL F OR INHAL OF TITANIUM DIOXIDE DUSTS
FROMCOATINGS IS VERY LTD. SINCE OVEREXPS ARE NOT EXPECTED, THERE IS
NO (SUPP DATA)

First Aid:INGEST:DO NOT INDUCE VOMIT. GENTLY WIPE OUT INSIDE MOUTH TO
REMOVE ANY RESIDUAL MATL. EYE:REMOVE CONT LENSES & FLUSH IMMED
W/GENTLE STREAM OF LUKEWARM WATER FOR AT LST 15 MINS. SKIN:FLUSH
IMMED W/PLEN TY OF WATER FOR AT LST 15 MINS FOLLOWEDBY WASHING
W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER
SUPPORT MEASURES AS REQD. OTHER:IF INGEST, ANY TYPE OF
OVEREXP/SYMPS OF (ING 9)

Extinguishing Media:USE EXTINGUISHERS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. WATER SPRAY MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & POSS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP THIS PROD AWAY FROM HEAT, SPKS,
FLAME & OTHER SOURCES OF IGNIT (I.E., PILOT LIGHTS, ELEC MOTORS,
STATIC ELEC). INVISIBLE VAPS CAN TRAVEL TO SOURCE (ING 6)

Spill Release Procedures:PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER
NIOSH APPRVD RESP, SKIN & EYE PROT SHOULD BE PERMITTED IN AREA.
REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAND,
VERMICULITE/OTHER NONCOMBUST ABS ORB MATL & PLACE IN CLEAN, EMPTY
CNTNRS(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE >120F (48C). VAPS MAY
COLLECT IN LOW AREAS. CNTNRS SHOULD BE GROUNDED WHEN POURING. AVOID
FREE FALL OF LIQS IN EXCESS OF A FEW INCHES.
Other Precautions:IF THIS MATL IS PART OF MULTIPLE COMPONENT SYS, READ
MSDS FOR OTHER COMPONENTS(S) BEFORE BLENDING AS RESULTING MIXT MAY
HAVE HAZS OF ALL OF ITS PARTS. HARMFUL IF SWALLOWED. MAY CAUSE
SLIGHT SKIN IRRIT . CAUSES EYE IRRIT. PRLNG/RPTD (ING 15)

Respiratory Protection:WHERE VENT IS INADEQ, USE NIOSH APPRVD(TC-23C-)
AIR PURIFYING/AIR SUPPLIED(TC-19C-) RESP. READ RESP MFR'S
INSTRUCTIONS & LITERATURE CAREFULLY TO DETERM TYPE OF AIRBORNE
CONTAMS AGAINST WHICH RESP IS E FTIVE & HOW IT IS TO BE PROPERLY
FITTED.
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO
KEEP CONCS OF INGS BELOW LOWEST SUGGESTED EXPOS LIMS, (SUPDAT)
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR PROT CLTHG TO PVNT SKIN CONT. APRON SHOULD BE CONSTRUCTED (ING
10)
Work Hygienic Practices:CLEAN CONTAMINATED CLOTHING & BOOTS.
Supplemental Safety and Health
FIRE FIGHT PROC:AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. IS WATER IS
USED, FOG NOZZ ARE PREF. EFTS OF OVEREXP:SIGNIFICANT HAZ FOR MAN.
SPILL PROC:FOR DISP. ONLY SPILLED MATL & ABSORB SHOULD BE PLAC ED
IN THIS CNTNR. VENT:LEL BELOW STATEDLIM & TO REMOVE DECOMP PRODS
DURING WELDING/FLAME CUTTING.

Boiling Pt:B.P. Text:>205F,>96C
Vapor Pres:17.4
Vapor Density:HVR/AIR
Spec Gravity:1.267
Evaporation Rate & Reference:34 (BUOAC=100)
Solubility in Water:51.8%
Appearance and Odor:VISCOUS LIQUID W/ODOR CHARACTERISTIC OF SOLVENTS
LISTED IN INGREDIENTS SECTION.
Percent Volatiles by Volume:66.14

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE FOLLOWING HAZ DECOMP PRODS
WHEN EXPOS TO EXTREME HEAT:OXIDES OF ZINC; CARBON MONOXIDE; CARBON
DIOXIDE;(ING 13)

Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF I/A/W
FEDERAL, STATE, PROVINCIAL & LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WASTE MANAGEMENT F ACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.