Product ID:840 3347 EA-5 FIRST AND SECOND STOP BATH AND REPLENISHER
MSDS Date:12/17/1997
FSC:6750
NIIN:01-412-6605
MSDS Number: CDGYN

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

ACETIC ACID (CERCLA)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 65-70%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 20-25%

SODIUM ACETATE

CAS: 127-09-3

RTECS: AJ4300010

Fraction By Weight: 5-10%

LD50 LC50 Mixture:ORAL LD50 (RAT): 0.5-5.0 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPOR EXTREMRELY
IRRITATING. EYE CONTACT CAUSES SEVERE BURNS. VAPOR EXTREMELY
IRRITATING TO EYES. SKIN CONTACT CAUSES SEVERE BURNS. MAY BE FATAL
OR HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL
TRACT IF SWALLOWED.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:RESPIRATORY TRACT IRRITAION, EYE IRRITATION,
EYE BURNS, SKIN BURNS, GI TRACT BURNS. ACUTE OVEREXPOSURE TO
EXTREMELY HIGH AIRBORNE CONCENTRATIONS OF RESPIRATORY IRRITANTS HAS
BEEN ASSOCIATED WITH DEVEL OPMENT OF AN ASTHMA-LIKE REACTIVE
AIRWAYS SYNDROME (RADS) IN SUSCEPTIBLE INDIVIDUALS. SUCH
CONCENTRATIONS NOT LIKELY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DO NOT INDUCE VOMITING. GIVE A GLASS OF WATER. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR
POISON CONTROL ASAP.

Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NO FLASHPOINT IN STANDARD APPARATUS DUE
TO FLAME QUENCHING; HOWEVER, COMBUSTIBLE VAPORS MAY BE PRESENT IN
VESSELS OF ADEQUATE SIZE ABOVE 49C (120F).

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. FLUSH TO SEWER
IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL
WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER
FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE VAPOR AT CONCENTRATIONS
GREATER THAN THE EXPOSURE LIMITS. DO NOT GET IN EYES, ON SKIN, CON
SLOTHING. USE ONLY WITH ADEQUATE VENTILATION
Other Precautions:KEEP AWAY FROM HEAT AND FLAME. KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE ORGANIC VAPOR
CARTRIDGE. IF RESPIRATO RS USED, A PROGRAM SHOULD BE INSTITUTED.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS OR GOGGLES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.

HCC:C2
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.11
pH:3.0
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, STRONG VINEGAR ODOR
Percent Volatiles by Volume:90 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, AMINES, BASES, METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.

Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
< 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.