Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
MSDS Date:11/21/1994
FSC:6830
NIIN:00N069304
MSDS Number: CDMTV

MATHESON GAS PRODUCTS

30 SEAVIEW DR
SECAUCUS, NJ 07096
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 201-867-4100

Cage: 0NPS5

MATHESON GAS PRODUCTS INC

1587 SECACUS, NJ 07094-1882 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: 0NPS5

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL

MAY BE ATTACKED;

RTECS: 9999999ZZ

OF HEART & SUBSEQUENTLY MAY CAUSE SUDDEN

RTECS: 9999999ZZ

EMOTIONAL STRESS. DOGS EXPOSED TO 11,000-13,000 PPM

RTECS: 9999999ZZ

TREMORS. ALL SYMPS WERE REVERSIBLE W/IN 15 MIN. IN

RTECS: 9999999ZZ

THAT INCL TACHYCARDIA, MYOCARDIAL DEPRESS, &

RTECS: 9999999ZZ

MAY

RTECS: 9999999ZZ

TO RABBIT EYES IS REPORTED TO HAVE PRDCED ONLY MILD

RTECS: 9999999ZZ

ONE HUMAN

RTECS: 9999999ZZ

WHILE UNDER ANESTH. THIS PRDCED IMMED BUT TRANSIENT

RTECS: 9999999ZZ

IRRIT & DIARR FOR 3 DAYS THEREAFTER. IF SUFFICIENT

RTECS: 9999999ZZ

IN ACUTE INHAL. INGEST OF HYDROCARBONS IS ASSOC

RTECS: 9999999ZZ

HUMAN EXPOS FOR 2 WKS AT CONCS OF APPROX 500 & 100

RTECS: 9999999ZZ

DECREMENT IN PERFORMANCE OF COMPLEX MENTAL TASKS.

RTECS: 9999999ZZ

DEGENERATIVE FATTY INFILTRATION ON LIVER.

RTECS: 9999999ZZ

OCCLUDED CONT OF 5 G/KG W/RABBIT SKIN FOR 5

RTECS: 9999999ZZ

CONSPICUOUS ENLARGEMENT OF LIVER CELLS.

RTECS: 9999999ZZ

TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR

RTECS: 9999999ZZ

BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES

RTECS: 9999999ZZ

LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (AT

RTECS: 9999999ZZ

OCCURS, KEEP HEAD LOWER THAN HIPS TO HELP PVNT

RTECS: 9999999ZZ

NO SPECIFIC ANTIDOTE. TREAT

RTECS: 9999999ZZ

(GAS MASK) W/CHIN-STYLE/FRONT/BACK-MOUNTED ORG

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:TARGET EFTS:CNS DEPRESS; SIMPLE
ASPHY. POIS MAY ALSO AFFECT LIVER & KIDNEYS. STIMULANTS SUCH AS
EPINEPHRINE MAY INDUCE VENTRICULAR FIBRILLATION.
INHAL:NARCOTIC/SIMPLE ASPHY. 4500 PPM IMMED DANGE ROUS TO
LIFE/HLTH. MAY CAUSE MILD IRRITOF MUC MEMB OF UPPER RESP TRACT. MAY
BE ANESTH & CAUSE CNS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DEPRESS W/DROW & ARRHYS. HUMANS
EXPOSED TO 2500-4500 PPM FOR 30-100 MIN SHOWED SIGNIFICANT
IMPAIRMENT OF MANUAL DEXTERITY & VIGILANCE, LOSS OF CONC,
SOMNOLENCE & HEAVINESS IN HEAD, WHICH DISA PPEARED 15 MIN AFTER
EXPOS ENDED. SIMPLE ASPHY MAY OCCUR AT HIGH CONCS. OVEREXP COULD
RSLT IN EPINEPHRINE SENSIT (ING 3)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN
DISORDERS, IMPAIRED CARDIVASCULAR FUNCTION, PARTICULARLY CARDIAC
ARRHYTHMIAS/IMPAIRED RESPIRATORY FUNCTION.

First Aid:INHAL: REMOVE TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC.
KEEP PERS WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET
MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH
W/SOAP/MIL D DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF
CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. EYES: WASH
IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS LIFTING UPPER & LOWER
(ING 20)

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . MOVE CONTRS FROM FIRE AREA IF YOU CAN DO IT W/OUT
RISK. DO NOT SCATTER SPILLED MATL WITH (SUP DAT)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND
PHOSGENE .

Spill Release Procedures:STOP LEAK IF YOU CAN DO IT WITHOUT RISK. FOR
SMALL SPILLS, TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND
PLACE INTO CLEAN, DRY CONTAINERS FOR LATER DISPOSAL. KEEP
UNNECESSARY PEOPLE AWAY. ISOLATE HAZARD AREA AND DENY ENTRY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
STOR THIS SUBSTANCE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP
IN TIGHTLY CLSD CONTR.
Other Precautions:STORE IN A COOL, DRY, VENTILATED AREA. NO SMOKING IN
AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING,
OPEN FLAMES, OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE
THE FORMATION OF H CL AND/OR PHOSGENE .

Respiratory Protection:THE SPECIFIC RESP SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIMS OF
RESP & BE APPRVD BY NIOSH. FOR A LIST OF SPECIFIC RESPIRATOR TYPES,
CONTACT NEHC .
Ventilation:PROVIDE GENERAL DILUTION VENTILATION TO MEET PUBLISHED
EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT RPTD/PRLNG
CONT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: HIGH-PRESS WATER STREAMS. DIKE FIRE-CTL WATER FOR
LATER DISP. USE AGENTS SUITABLE FOR TYPE OF SURROUNDING FIRE. AVOID
BRTHG HAZ VAPS, KEEP UPWIND. MATLS TO AVOID: FORMS SHOCK-SENSITIV E
MIX. BARIUM (POWDERED)/LITHIUM (POWDERED): FORMS EXPLO MIX.
MAGNESIUM ALLOY: DECOMP POSS. (ING 2)

Boiling Pt:B.P. Text:118F,48C
Vapor Pres:284 @ 20C
Vapor Density:6.47
Spec Gravity:1.5635
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.017% @ 25C
Appearance and Odor:CLEAR, COLORLESS, VOLATILE LIQUID WITH A SLIGHT
ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI METALS/BERYLLIUM/CALCIUM/MAGNESIUM/ZINC: VIOLENT RXN POSS.
ALUMINUM (POWDERED)/TITANIUM (POWDERED): (SUP DAT)
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY.
AVOID CONTACT WITH STRONG OXIDIZERS, EXCESSIVE HEAT, SPARKS, OR
OPEN FLAME.
Hazardous Decomposition Products:THERMAL DECOMP PRODS MAY INCL TOX &
CORR FUMES OF CHLORIDES & FLUORIDES, & TOX OXIDES OF CARBON. HCL,
PHOSGENE .

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.