Product ID:DETA-ANCAMINE
MSDS Date:10/01/1992
FSC:8010
NIIN:00N056942
MSDS Number: CDNBJ

AIR PRODUCTS AND CHEMICALS INC

7201 HAMILTON BLVD
ALLENTOWN, PA 18195-1501
US

Emergency Phone: 800-523-9374

Info Phone: 800-345-3148

Cage: 00742

AIR PRODUCTS AND CHEMICALS INC

ALLENTOWN, PA 18195-1501 US

Telephone: 800-345-3148/ 800-752-1597

Cage: 00742

DIETHYLENETRIAMINE

CAS: 111-40-0

RTECS: IE1225000

Fraction By Weight: 100%

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM, S

COUGH, TIGHTNESS OF CHEST/SHORTNESS OF BREATH.

RTECS: 9999999ZZ

SHOULD BE DISCARDED. VICTIMS OF MAJOR CONT

RTECS: 9999999ZZ

MOVE PATIENT TO FRESH

RTECS: 9999999ZZ

RESP (MOUTH-TO-MOUTH). SUPP OXYG MAY BE INDICATED.

RTECS: 9999999ZZ

ADMIN

RTECS: 9999999ZZ

HIGHLY

RTECS: 9999999ZZ

AMMONIA GAS. CHEM PNEUM, PULM EDEMA, LARYNGEAL EDEMA

RTECS: 9999999ZZ

OCCUR FOLLOWING EXPOS. THERE IS NO SPECIFIED

RTECS: 9999999ZZ

TREATMENT, WHICH IS SIMILAR TO THAT FOR THERMAL

RTECS: 9999999ZZ

UP PERS MUST BE EQUIPPED W/NIOSH APPRVD SCBA &

RTECS: 9999999ZZ

SPILL POTNTL FOR CARBON MONOXIDE &/OR NITROUS OXIDES

RTECS: 9999999ZZ

PROD FROM ENTERING STREAMS/DRINKING WATER SUPPLIES.

RTECS: 9999999ZZ

CONTAMINATION SHOULD OCCUR.

RTECS: 9999999ZZ

BE USED DEPENDING ON QUALITY & QTY, OF

RTECS: 9999999ZZ

DISCHARGE WATER QUALITY STDS. DISP OF IN APPRVD

RTECS: 9999999ZZ

LONG TERM ENIRON HAZS, THUS LANDFILL DISP MUST BE

RTECS: 9999999ZZ

REMOVE CLTHG THAT BECOMES CONTAM. EXAMINE

RTECS: 9999999ZZ

OR CRACKS. LAUNDER OR DISCHARD CONTAMINATED

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1080 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:VAP IN LOW CONCS CAN CAUSE
LACRIM, CONJ & CORNEAL EDEMA. CORNEAL EDEMA MAY GIVE RISE TO "BLUE
HAZE"/"FOG" AROUND LIGHTS. EFT IS TRANSIENT & HAS NO KNOWN RESIDUAL
EFT. EYE/SKIN CONT:UNDILUTED PROD QUICKLY CAUSES SEV IRRIT, PAIN &
MAY CAUSE BURNS, NECROSIS & PERM INJURY. BURNS MAY CAUSE (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BLINDNESS. INHAL:VAPS CAUSE IRRIT OF
RESP TRACT & MAY CAUSE ADVERSE SYSTEMIC EFTS. RISK OF EXPOS UNDER
NORM WORKING CNDTNS IS WELL VENTED SPACE IS MIN. AEROSOL,
MISTS/FOGS SHOULD BE AVOIDED; MAY CAUSE HARM. INGEST:MALAISE,
DISCOMFORT, DEATH UNLESS TREATED PROMPTLY. CHRONIC:SKIN:PRIMARY
IRRIT, DERM, (SUPDAT)
Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY DISEASES (E.G.
BRONCHITIS, EMPHYSEMA). EYE DISEASE. SKIN DISORDERS & ALLERGIES.
ASTHMA.

First Aid:EYE:HOLD LIDS APART & IMMED FLUSH W/PLENTY OF WATER FOR AT
LST 15 MINS. CALL MD, PREF SPECIALIST. SKIN:REMOVE PROD & IMMED
FLUSH AFFECTED AREA W/WATER FOR AT LST 15 MINS. CALL MD. FOR MAJOR
BURNS, COV ER AFFECTED AREA W/STERILE DRESSING/CLEAN SHEETING &
TRANSPORT FOR MED CARE. DO NOT APPLY GREASES/OINTMENTS. CONTROL
SHOCK, IF PRESENT. LAUNDER CONTAM CLTHG PRIOR TO REUSE. CONTAM
LEATHER WEAR (ING 3)

Flash Point Method:PMCC
Flash Point:210F,99C
Extinguishing Media:IGNIT WILL GIVE RISE TO CLASS B FIRE. IN CASE OF
FIRE USE:WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEM, ALCOHOL
FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
RETAIN EXPENDED LIQS FROM FIRE FIGHTING FOR LATER DISP. WATER SPRAY
IS ALSO USEFUL IN COOLING FIRE-EXPOS(SUPDAT)
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID, CLASS IIIB. MAY
GENERATE TOXIC OR IRRITATING COMBUSTION PRODUCTS. SUDDEN REACTION &
FIRE MAY RESULT IF PRODUCT IS MIXED W/OXIDIZING AGENT.

Spill Release Procedures:VENT SPACE INVOLVED. SHUT OFF/REMOVE ALL IGNIT
SOURCES. CONSTRUCT DIKE TO PVNT SPREADING. PROT WORKERS W/WATER
SPRAY. COVER MINOR SPILLS W/SODIUM BILSULFITE TO NEUT & REDUCE
VAPS. SPRAY W/WATER. PLACE IN METAL CNTNRS FOR RECOVERY/DISP.
CLEAN-(ING 11)
Neutralizing Agent:SODIUM BISULFITE.

Handling and Storage Precautions:KEEP IN COOL, DRY, VENTED STOR & IN
CLSD CNTNRS. STORE IN STEEL CNTNRS PREF LOCATED OUTDOORS, ABOVE
GROUND & SURROUNDED BY DIKES TO CNTN SPILLS/LEAKS.
Other Precautions:CORR LIQ. KEEP AWAY FROM OXIDIZERS, HEAT/FLAMES.
AVOID CONT W/SKIN, EYES/CLTHG. AVOID BRTHG VAPS. EMPTY CNTNRS MAY
CNTN EXPLO VAPS. FLUSH EMPTY CNTNRS W/WATER TO REMOVE RESIDUAL
FLAMM LIQ & VAPS. ADHE RE TO WORK PRACTICE RULES (SUPP DATA)

Respiratory Protection:IN POORLY VENTED AREAS, NIOSH APPRVD CARTRIDGE
MASK FOR OXGN VAPS IS REC UNDER FOLLOWING CNDTNS:EMER SITUATIONS,
WHEN PROD VAP CONC IS >20 PPM FOR PERIOD >15 MINS, DURING REPAIR &
CLEANING OF EQUIP/DU RING TRANSFER/DISCHARGE OF PRODUCT.
Ventilation:ADEQUATE GENERAL & LOCAL EXHAUST. MAINTAIN AIR
CONCENTRATIONS IN WORK SPACES I/A/W STANDARDS OUTLINED IN MSDS.
Protective Gloves:NITRILE RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . APPROPRIATE PROTECTIVE CLOTHING, RUBBER APRON, RUBBER
BOOTS.
Work Hygienic Practices:CONT LENSES SHOULD NOT BE WORN. WASH AT END OF
EACH WORKSHIFT & BEFORE EATING, SMOKING/USING TOILET. PROMPTLY (ING
18)
Supplemental Safety and Health
PH(3% AQ SOLN):11.4. FIRE FIGHT PROC:TANKS & IN DISPERSING VAPS. OTHER
PREC:ESTABLISHED BY GOVT REGS (OSHA). DO NOT USE SODIUM
NITRITE/OTHER NITROSATING AGENTS IN FORMS CNTNG PROD.
CANCER-CAUSING NITR OSAMINES COULD BE FORMED. EYE PROT:FULLLGTH
FCSHLD . EFTS OF OVEREXP:DEFAT, RASH/CORR. INHAL:RESP EFTS, (ING 2)

Boiling Pt:B.P. Text:404F,207C
Melt/Freeze Pt:M.P/F.P Text:-38F,-39C
Vapor Pres:<0.1 @ 25C
Vapor Density:3.6
Spec Gravity:0.952 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:0.01 (BUTYL ACETATE=1)
Solubility in Water:COMPLETELY
Appearance and Odor:COLORLESS, MOBILE LIQUID; AMMONIACAL, IRRITATING
ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ACIDS, NITROUS ACIDS, NITRITES, NITROUS OXIDE. FOR
COMPLETE LISTING & MORE INFO, CONT NEHC .
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
AMMONIA, NITROGEN OXIDES, NITRIC ACID. FOR MORE SPECIFIC INFO,
CONTACT NEHC .

Waste Disposal Methods:COMPLY W/ALL FED, STATE & LOC REGS. INCIN IS
ACCEPT & PREF METH OF DISP. NITROGEN OXIDE EMISSION CONTROLS MAY BE
REQD TO MEET SPECIFICATIONS. CHEM &/OR BIOLOGICAL DEGRADATION IS
FEASIBLE. SUITAB LE INDUS/MUNICIPAL WASTE TREATMENT SYS CAN(ING 15)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.