Product ID:NIPOL 1312
MSDS Date:06/08/1992
FSC:9320
NIIN:00N055792
MSDS Number: CDTJG

ZEON CHEMICALS INC

1701 GOLF RD
ROLLING MEADOWS, IL 60008
US

Emergency Phone: 800-735-3388

Info Phone: 708-437-9770

Cage: 0J3F9

ZEON CHEMICALS L.P.

LOUISVILLE, KY 40211 US

Telephone: 800-735-3388/502-775-2000

Cage: 0J3F9

ACRYLONITRILE (SARA 302/313) (CERCLA) % WT; <20 PPM

CAS: 107-13-1

RTECS: AT5250000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: 2 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

<5

CAS: 106-99-0

RTECS: EI9275000

Fraction By Weight: <0.1%

OSHA PEL 1000 PPM

ACGIH TLV: 2 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

PHENOL, P-TERT-BUTYL; (P-T-BUTYL PHENOL)

CAS: 98-54-4

RTECS: SJ8925000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

ACRYLONITRILE BUTADIENE POLYMER

CAS: 9003-18-3

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

ALIPHATIC HYDROCARBS. CONSIDER COMBUST PRODS

RTECS: 9999999ZZ

RPTS OF DEPIGMENTATION OF SKIN (VITALIGO)

RTECS: 9999999ZZ

DECOMP/COMBUST PRODS CAUSES IRRIT OF RESP TRACT,

RTECS: 9999999ZZ

AS POTNTLY HAZ & TAKE MEASURES TO AVOID EXPOS. SEE

RTECS: 9999999ZZ

SUCH AS SPECIFIC FORMULATION & PROCESSING

RTECS: 9999999ZZ

VENTD CNDTNS & AVOID CONTINUED/PRLNGD BRTHG OF VAPS.

RTECS: 9999999ZZ

EATING/SMKNG/USING TOILET FACILITIES. PERFORM CLEAN

RTECS: 9999999ZZ

ELASTOMER MAY BE HELD AT PROCESS TEMPS FOR SHORT

RTECS: 9999999ZZ

EXPOS TO ELEVATED TEMP/EXCESS TIME RSLTS IN DECOMP.

RTECS: 9999999ZZ

OR DECOMP WILL OCCUR. STORE IN COOL, DRY PLACE AWAY

RTECS: 9999999ZZ

ABNORM CNDTNS SUCH AS EQUIP MALFUNC/USING

RTECS: 9999999ZZ

PROCESSING MAY CAUSE DECOMP. PROVIDE EMPLOYEES

RTECS: 9999999ZZ

SUPPLIED RESPS. COMPOUNDING INGREDS PURCHASED TO ADD

RTECS: 9999999ZZ

FOLLOW RECOMD PRECS OF INDIVIDUAL ADDITIVE

RTECS: 9999999ZZ

HEAT SUFFICIENT TO RSLT IN POLYMER BREAKDOWN

RTECS: 9999999ZZ

INHAL OF FUMES. LOCAL EXHAUST VENT SHOULD BE

RTECS: 9999999ZZ

NOT ADEQ TO AVOID EXPOS, PROVIDE W/SUITABLE

RTECS: 9999999ZZ

INHAL. VENT MUST BE ADEQ TO MAINTAIN AMBIENT

RTECS: 9999999ZZ

MAY BE FOUND IN PUBS SUCH AS INDUSTRIAL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:OVEREXP IS NOT EXPECTED AT AMBIENT
TEMPS. NO ADVERSE HLTH EFTS EXPECTED DURING NORM PROCESSING WHEN
POTNTL EXPOS ARE ELIM BY GOOD INDUS HYGIENE PRACT & WELL VENTD
CNDTNS. AT PROCESSING TEMPS, COMBINED INGREDS (ELASTOMER & OTHER
PROCESSING INGREDS) MAY EMIT FUMES & VAPS THAT CAUSE IRRIT TO RESP
TRACT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EYES &/OR SKIN. TYPICALLY, THESE EFTS
ARE REVERSIBLE UPON REMOVAL FROM EXPOS & NO LASTING EFTS EXPECTED.
MOST IMPORTANTLY, POTNTL FOR IRRIT DEPENDS ON EFTIVENESS OF EXHST
VENT PROVIDED TO PR OCESS AREA. PROD CNTNS TRACE AMT OF P-T-BUTYL
PHENL AS COMPONENT OF ANTIOXIDANT PACKAGE. ALTHOUGH RARE, THERE
ARE(ING 6)
Medical Cond Aggravated by Exposure:NONE KNOWN FOR PRODUCT AS
DELIVERED.

First Aid:IF IRRIT OCCURS/PERSISTS FROM ANY ROUTE OF EXPOS, REMOVE FROM
AREA. CALL MD. PROVIDE PROTECTION BEFORE ALLOWING REENTRY. EYES:
FLUSH EYES W/RUNNING WATER FOR @ LST 15 MIN WHILE HOLDING EYELIDS
OPEN. C ONSULT MD IF IRRIT PERSISTS. SKIN: REMOVE CONTAMD CLTHG.
WASH SKIN W/SOAP & WATER. NO EFTS REQ FIRST AIR EXPECTED. INHAL:
REMOVE TO FRESH AIR. CONSULT MD IMMED. INGEST: CALL MD IMMEDIATELY
.

Extinguishing Media:WATER/ABC DRY CHEM/PROTEIN TYPE AIR FOAMS.
ELASTOMERS CONSIDERED "ORDINARY COMBUSTS" (NFPA CLASS A). CO*2 IS
(SUPDAT)
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP PERS W/OUT
SUITABLE NIOSH APPRVD RESP PROT MUST LEAVE AREA TO PVNT SIGNIFICANT
EXPOS TO TOX COMBUST GASES FROM(SUPDAT)
Unusual Fire/Explosion Hazard:HYDROGEN CYANIDE GAS IS FORMED UPON
COMBUSTION. THIS REPRESENTS A HAZARD TO FIREFIGHTERS. SEE SECTION
ON STABILITY FOR ADDITIONAL INFO ON COMBUSTION PRODUCTS.

Spill Release Procedures:WEAR PROT EQUIP TO CNTN SPILL & RECOVER AS
MUCH AS POSS FOR REUSE. ABSORB REMAINDER W/INERT MATL. PLACE
RESIDUE IN CLSD CNTNR FOR DISP. WASH SPILL AREA W/SOAP & WATER. DO
NOT ALLOW PROD TO ENTER MUNIC IPAL SEWERS/WATERWAYS W/OUT
PERMISSION FROM AUTHS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DURING NORM PROC, VIRTUALLY ALL
ELASTOMERS WILL EMIT FUMES & VAPS WHEN HEATED TO PROCESSING TEMPS.
VAP CONC & COMPOSITION DEPENDS ON VARIABLES(ING 9)
Other Precautions:PROCESSING FUME CONDENSATES WHICH MAY INCL TOX
CONTAMINANTS, MAY BE COMBUST & SHOULD BE PERIODICALLY REMOVED FROM
EXHST HOODS, DUCTWORK & OTHER SURFS. WEAR PROT CLTHG, INCL RUB
GLOVES, DURING CLEANUP OPERATIONS TO PVNT SKIN CNTCT. (ING 15)

Respiratory Protection:AS SUPPLIED, RESP PROT IS NOT TYPICALLY REQD
DURING NORM USE & HNDLG OPERATIONS. ABNORM CNDTNS SUCH AS EQUIP
MANFUNC, IMPROPER EQUIP/PROCS OR HANDUP/STAGNATION DURING
PROCESSING MAY CAUSE DECOMP. IF G EN DILUTION/LOC EXHST VENT IS
(ING 21)
Ventilation:EFTIVE GEN & IF NEC, LOC EXHST VENT MUST ALWAYS BE PROVIDED
TO DRAW FUMES/VAPS AWAY FROM WORKERS TO PVNT ROUTINE(ING 22)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:DO NOT STORE OR CONSUME FOOD IN PROCESSING
AREAS. DO NOT USE PROCESSING EQUIPMENT TO HEAT FOOD.
Supplemental Safety and Health
% VOLAT(WT): <1% (WATER VAP). EXTING MEDIA:GEN NOT RECOMD FOR USE ON
CLASS A FIRES-LACK OF COOLING CAPACITY MAY RSLT IN REIGNIT. FIRE
FIGHT PROC:ANY SOURCE. IN ENCLSD/POORLY VENTD AREAS, WEAR NIOSH AP
PRVD SCBA DURING CLEANUP IMMED AFTER FIRE AS WELL AS DURING ATTACK
PHASE OF FIREFIGHT. MATL TO AVOID:W/THESE ELASTOMERS.

Spec Gravity:1.0 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER VISCOUS LIQUID WITH A CHARACTERISTIC ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFO AVAIL, BUT STRONG OXIDIZERS/REDUCING AGENTS, GEN NOT
COMPAT W/MANY ORG CMPDS, ARE NOT COMPAT (SUPDAT)
Stability Condition to Avoid:OVERHEATING.
Hazardous Decomposition Products:FUMES PRDCED WHEN HEATED TO DECOMP
TEMPS MAY CNTN:OXIDES OF CARBON, HYDROGEN CYANIDE & SM AMTS OF
AROMATIC & (ING 5)

Waste Disposal Methods:LANDFILL OR INCINERATION IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS. THESE PRODUCTS ARE NOT
DEFINED OR DESIGNATED AS HAZARDOUS BY CURRENT PROVISIONS OF THE
FEDERAL (EPA) RESOURCE CONSERVA TION AND RECOVER ACT (RCRA, 40 CFR
261).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.