Product ID:WHITE RAPDRY WATER ST CA, 2342A9
MSDS Date:12/07/1993
FSC:8010
NIIN:00N072291
MSDS Number: CDTNP

MORTON INTERNATIONAL

1021 N MISSION RD
LOS ANGELES, CA 90033
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 213-225-4154

Cage: 7D283

MORTON INTERNATIONAL

LOS ANGELES, CA 90033 US

Telephone: 213-225-4154

Cage: 7D283

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CALCIUM CARBONATE (MARBLE) (LIMESTONE)

CAS: 1317-65-3

RTECS: EV9580000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1.34 LB/GAL

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

ANTICIPATED TO BE CARCINOGEN.

RTECS: 9999999ZZ

250 MG/M3 LEVEL ARE NOT RELEVANT TO

RTECS: 9999999ZZ

MEMB DUE TO MECH ACTION, CHRONIC EXPOS MAY AFFECT

RTECS: 9999999ZZ

PRLNGD & RPTD EXPOS TO ETHYL ALCOHOL HAVE RSLTD IN

RTECS: 9999999ZZ

& TERATOGENICITY, TRANSIENT MUTAGENIC EFTS HAS BEEN

RTECS: 9999999ZZ

THERAPY SHOULD BE AWARE ETHYL ALCOHOL IN PROD IS HAZ

RTECS: 9999999ZZ

DISULFIRAM RXN MAY FOLLOW INGEST OF SM AMTS OF

RTECS: 9999999ZZ

METHANOL-EXCESS HUMAN EXPOS TO METHANOL MAY LEAD

RTECS: 9999999ZZ

INCL BLNDNESS/DEATH, METABOLIC ACIDOSIS, CNS & OPTIC

RTECS: 9999999ZZ

& KIDNEY DAMAGE.

RTECS: 9999999ZZ

REMOVE TO FRESH AIR. IF NOT

RTECS: 9999999ZZ

DFCLTY PERSISTS, OR OCCURS LATER, CONSULT PHYSICIAN.

RTECS: 9999999ZZ

CNTNR FOR DISP. APPROP SFTY MEASURES & PROT

RTECS: 9999999ZZ

OTHER BODIES OF WATER. COMPLY W/ALL APPLIC GOVT REGS

RTECS: 9999999ZZ

AUTHORIZED FACILITY, OR (3) TREAT AT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:GI DISTRESS.
SKIN:RPTD/PRLNGD LIQ CONT MAY CAUSE IRRIT W/DISCOMFORT & DERM. MAY
ALSO CAUSE ALLERGIC SKIN RXN. CAN BE ABSORBED THRU SKIN IN HARMFUL
AMTS. INHAL:MAY CAUSE NOSE & THROAT IRRI T. MAY CAUSE NERV SYS
DEPRESS CHARACT BY FOLLOWING PROGRESSIVE STEPS:HEADACHE, DIZZ,
NAUS, STAGG GAIT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT
ON CARCINS, (ING 8)
Effects of Overexposure:HLTH HAZ:CONFUSN, UNCON. CHRONIC:TITANIUM
DIOXIDE-NO KNOWN HAZ W/NORMAL INDUST USE. IN LIFE-TIME INHAL TEST,
LUNG CANCERS WERE FOUND IN SOME RATS EXPOS TO 250 MG/M3 RESPIRABLE
TITANIUM DUST. ANALYSIS OF TITANIUM DIOXIDE CONCS IN RAT'S LUNGS
SHOWED LUNG CLEARANCE MECHANISM WAS OVERWHELMED & THAT RSLT @
MASSIVE (ING 9)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:GI DISTRESS. CALL PHYS IMMED & HAVE NAME OF INGREDS
AVAIL. SKIN:IMMED FLUSH AFFECTED AREA W/WATER FOR @ LST 15 MINS. OF
LG EXPOS, USE EMER SHOWER. REMOVE CONTAMD CLTHG & SHOES. CLEANSE
W/SOAP & WATER, INCL HAIR & UNDER FINGER NAILS.GET IMMED MED ATTN.
WASH CONTAMD CLTHG SEPARATELY BEFORE REUSE. EYE:IMMED FLUSH
W/PLENTY OF WATER FOR @ LST 15 MINS; CALL PHYS. IF IRRIT OCCURS,
CONT (ING 18)

Flash Point Method:SCC
Flash Point:106F,41C
Extinguishing Media:SM FIRES:FOAM, CARBON DIOXIDE, DRY CHEM/WATER
SPRAY. LG FIRES:FOAM, WATER SPRAY/FOG. "ALCOHOL" FOAM FOR POLAR
SOLVENTS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER FROM FOG NOZZ MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILDUP.
Unusual Fire/Explosion Hazard:VAPS MAY BE HVR/AIR & MAY TRAVEL
CONSIDERABLE DIST FROM MATL HNDLG POINT. VAPS CAN BE IGNITED BY
SPK, FLAME, CIGARETTE, ELEC MOTOR, STATIC DISCHARGE, (SUPDAT)

Spill Release Procedures:STOP DISCHARGE, IF IT CAN BE PERFORMED SAFELY,
& CNTN MATL. IF SUBSTANTIAL QTY IS SPILLED, RECOVER W/PUMP/VACUUM
TRUCK, EXPLO PROOF EQUIP SHOULD BE USED OF PROD IS FLAM/COMBUST.
OTHERWISE, USE SYNTHET IC ABSORB. PLACE CONTAMD MATL IN SUITBLE
(ING 20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA. DO NOT CUT, GRIND, WELD/DRILL NEAR THIS CNTNR.
Other Precautions:THIS CNTNR CAN BE HAZ WHEN EMPTY, BECAUSE IT CAN
RETAIN PROD RESIDUE. THEREFORE, DO NOT REUSE CNTNR FOR FOOD,
CLTHG/PRODS FOR HUMAN/ANIMAL CONSUMPTION/WHERE SKIN CONT MAY OCUR.
ALWAYS OBEY HAZ WARNING S & HNDL CNTNRS AS IF THEY WERE FULL.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST TO MAINTAIN VAPOR CONCENTRATION BELOW
THRESHOLD LIMIT VALUE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING BEFORE
REUSE. DISCARD SHOES IF SATURATED.
Supplemental Safety and Health
EXPLO HAZ:ENGINE, PILOT LIGHT, HOT SURF/OTHER IGNIT SOURCE. MAY
LIBERATE IRRIT/TOX VAPS DURING COMBUST/DECOMP. CNDTNS TO
AVOID:POTASSIUM, SODIUM, ZINC. AVOID CHROMIC ANHYDRIDE, LEAD
PERCHLORATE/PERCHL ORIC ACID. TITANIUM DIOXIDE:THERM DECOMPRODS MAY
INCL:HAZARDOUS FUMES OF TITANIUM DIOXIDE.

Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT KNOWN
Appearance and Odor:OPAQUE LIQUID WITH AROMATIC SOLVENT ODOR.
Percent Volatiles by Volume:47.14

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPKS, & OPEN FLAME. TITANIUM
DIOXIDE:ALUMINUM, CALCIUM; VIOLENT RXN W/INCANDESCENCE, LITHIUM
MAGNESIUM, (SUPDAT)
Hazardous Decomposition Products:MAY LIBERATE SMOKE, SOOT, AND TOXIC
FUMES (CARBON MONOXIDE AND CARBON DIOXIDE).

Waste Disposal Methods:DISPOSE OF WASTE I/A/W LOC, STATE, & FED REGS.
OF METH OF DISP CURRENTLY AVAIL, IT IS REC THAT ALTERNATIVE BE
SELECTED ACCORD TO FOLLOWING ORDER OF PREFERANCE BASED UPON ENVIR
ACCEPTABILITY:(1) RECYCL E/REWORK IF @ ALL FEASIBLE. (2) INCIN
@(ING 22)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.